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Journal of Engineering Thermophysics

Published in:

01-02-2020

Combustion of Sludge-Lignin in Water-Oxygen Mixture

Authors: O. N. Fedyaeva, A. A. Vostrikov, D. O. Artamonov, A. V. Shishkin, M. Ya. Sokol

Published in: Journal of Engineering Thermophysics | Issue 1/2020

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Abstract

The paper presents the results of investigation of the products of oxidation of sludge-lignin (waste from the Baikal pulp and paper mill) in H\(_{2}\)O/O\(_{2}\) mixture in the autoclave and semi-flow modes at uniform heating of the reactor up to 750 K. The time dependencies of the reactor wall temperature and the power of ohmic heaters imply that the oxidation starts at 440 K and the maximum oxidation rate is realized at 583-643 K. Mass spectrometry measurements of the composition of the volatile products yielded the temperature dependency of the degree of removal of carbon occurring in CO and CO\(_{2}\) from sludge-lignin. Using physical and chemical methods of analysis it was shown that Al\(_{2}\)O\(_{3}\) (AlOOH in the autoclave mode), Fe\(_{2}\)O\(_{3}\), SiO\(_{2}\), AlPO\(_{4}\), and CaSO\(_{4}\) were major components of the residue after the sludge-lignin conversion. Formation of HCl and H\(_{2}\)SO\(_{4}\) in the course of oxidation of chlorine- and sulfur-containing organic compounds was found to cause corrosion of stainless steel.

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Title: Combustion of Sludge-Lignin in Water-Oxygen Mixture
Authors: O. N. Fedyaeva
A. A. Vostrikov
D. O. Artamonov
A. V. Shishkin
M. Ya. Sokol
Publication date: 01-02-2020
Publisher: Pleiades Publishing
Published in: Journal of Engineering Thermophysics / Issue 1/2020
Print ISSN: 1810-2328
Electronic ISSN: 1990-5432
DOI: https://doi.org/10.1134/S1810232820010038

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