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Polymer Science, Series A
Published in: Polymer Science, Series A 6/2023

01-12-2023 | SOLUTIONS

Complexes Based on Polyvinyl Alcohol and a Copolymer of Sodium Salts of Styrenesulfonic and Maleic Acids

Authors: E. A. Litmanovich, O. A. Pyshkina, D. E. Ochenkov, S. A. Pantsernaya, R. V. Grossman, V. E. Savchenkova, M. V. Zhilkin, V. G. Sergeyev

Published in: Polymer Science, Series A | Issue 6/2023

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Abstract

For the first time, the interaction of polyvinyl alcohol and a copolymer of sodium salts of styrenesulfonic and maleic acids in aqueous solutions has been studied using the techniques of static and dynamic light scattering and capillary viscometry. It has been shown that hydrogen-bonded complexes are formed between them, with compaction of polyvinyl alcohol coils occurring in dilute solutions and additional structuring of the solution in semidilute solutions. The activation parameters (enthalpy and entropy) of viscous flow have been assessed, confirming the formation of the complexes. The concentration regimes of solutions of polyvinyl alcohol, the copolymer, and the complexes have been studied. It has been shown that the semidilute entanglement-free regime disappears in solutions of the complexes.
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next article Hydrodynamic and Conformational Behavior of N-Vinylformamide–Sodium 4-Styrenesulfonate Copolymers in Aqueous Solutions

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Metadata
Title
Complexes Based on Polyvinyl Alcohol and a Copolymer of Sodium Salts of Styrenesulfonic and Maleic Acids
Authors
E. A. Litmanovich
O. A. Pyshkina
D. E. Ochenkov
S. A. Pantsernaya
R. V. Grossman
V. E. Savchenkova
M. V. Zhilkin
V. G. Sergeyev
Publication date
01-12-2023
Publisher
Pleiades Publishing
Published in
Polymer Science, Series A / Issue 6/2023
Print ISSN: 0965-545X
Electronic ISSN: 1555-6107
DOI
https://doi.org/10.1134/S0965545X23600588

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