Skip to main content
Top

2019 | OriginalPaper | Chapter

7. Comprehensive Utilization of Carbide Slag

Authors : Fenglan Han, Laner Wu

Published in: Industrial Solid Waste Recycling in Western China

Publisher: Springer Singapore

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Carbide slag (acetylene sludge) is the industrial residue, which is discharged when the hydrolysis of calcium carbide is undertaken to prepare acetylene. The slag mainly consists of Ca(OH)2. If the carbide slag is stacked on the spot, it may pollute water resources near the stacking field. Additionally, the drying of carbide slag generates dust, which pollutes the atmosphere. Therefore, cleaner production and sustainable use of resources are difficult and focus on research in China. At present, the comprehensive utilization of carbide slag includes several methods. One of the methods involving large consumption of carbide slag is the production of cement. Second, the application of carbide slag as a desulfurizer in wet flue gas desulfurization system can also treat wastes. Moreover, carbide slag is used to produce ordinary chemical products and prepare nanocalcium carbonate.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Yao EL, Wang XQ (2013) Development and tendency predict of comprehensive utilization of carbide slag of chlor-alkali industry. Chin Chlor-Alkali (2): 40–42. Yao EL, Wang XQ (2013) Development and tendency predict of comprehensive utilization of carbide slag of chlor-alkali industry. Chin Chlor-Alkali (2): 40–42.
2.
go back to reference Tao L, Zhang ZH (2016) Current situation and development trend of PVC industry in China. Polyvinyl Chloride 44(7): 1–4. Tao L, Zhang ZH (2016) Current situation and development trend of PVC industry in China. Polyvinyl Chloride 44(7): 1–4.
3.
go back to reference Li Y, Liu H, Sun R et al (2012) Thermal analysis of cyclic carbonation behavior of CaO derived from carbide slag at high temperature. J Therm Anal Calorim 110: 685–694.CrossRef Li Y, Liu H, Sun R et al (2012) Thermal analysis of cyclic carbonation behavior of CaO derived from carbide slag at high temperature. J Therm Anal Calorim 110: 685–694.CrossRef
4.
go back to reference Cao JX, Liu F, Lin Q et al (2008) Effect of calcination temperature on mineral composition of carbide slag, lime activity and synthesized xonotlite. Key Eng Mater 368: 1545–1547.CrossRef Cao JX, Liu F, Lin Q et al (2008) Effect of calcination temperature on mineral composition of carbide slag, lime activity and synthesized xonotlite. Key Eng Mater 368: 1545–1547.CrossRef
5.
go back to reference Liang B, Han FL (2016) Crystal transformation of calcium carbonate micro-particles prepared from carbide slags. Inorg Chem Ind 48(10): 65–69. Liang B, Han FL (2016) Crystal transformation of calcium carbonate micro-particles prepared from carbide slags. Inorg Chem Ind 48(10): 65–69.
6.
go back to reference Li HZ (2010) Characteristic of carbide slag of acetylene by drying process and its influence. China Chlor-Alkali (6): 15–17. Li HZ (2010) Characteristic of carbide slag of acetylene by drying process and its influence. China Chlor-Alkali (6): 15–17.
7.
go back to reference Mater J (2002) Cementing material from calcium carbide residue-rice husk ash. Am Soc Civ Eng 15(5): 470–476. Mater J (2002) Cementing material from calcium carbide residue-rice husk ash. Am Soc Civ Eng 15(5): 470–476.
8.
go back to reference Horpibulsuk S, Phetchuay C, Chinkulkijniwat (2011) Soil stabilization by calcium carbide residue and fly ash. J Mater Civ Eng 24(2): 184–193. Horpibulsuk S, Phetchuay C, Chinkulkijniwat (2011) Soil stabilization by calcium carbide residue and fly ash. J Mater Civ Eng 24(2): 184–193.
9.
go back to reference Jaturapitakkul C, Roongreung B (2003) Cementing material from calcium carbide residue-rice husk ash. J Mater Civ Eng 15(5): 470–475.CrossRef Jaturapitakkul C, Roongreung B (2003) Cementing material from calcium carbide residue-rice husk ash. J Mater Civ Eng 15(5): 470–475.CrossRef
10.
go back to reference Krammart P, Tangtermsirikul S (2004) Properties of cement made by partially replacing cement raw materials with municipal solid waste ashes and calcium carbide waste. Constr Build Mater 18: 579–583.CrossRef Krammart P, Tangtermsirikul S (2004) Properties of cement made by partially replacing cement raw materials with municipal solid waste ashes and calcium carbide waste. Constr Build Mater 18: 579–583.CrossRef
11.
go back to reference Abo-El-Enein SA, Hashem FS, Amin MS et al (2016) Physicochemical characteristics of cementitious building materials derived from industrial solid wastes. Constr Build Mater 126: 983–990.CrossRef Abo-El-Enein SA, Hashem FS, Amin MS et al (2016) Physicochemical characteristics of cementitious building materials derived from industrial solid wastes. Constr Build Mater 126: 983–990.CrossRef
12.
go back to reference He LB (2011) Practice of producing low alkali clinker for railway with 100% carbide slag instead of limestone. Cem Guide N Epoch (2): 47–49. He LB (2011) Practice of producing low alkali clinker for railway with 100% carbide slag instead of limestone. Cem Guide N Epoch (2): 47–49.
13.
go back to reference Liu QW (2008) Application of calcium carbide slag instead of limestone in cement production. Dev Guide Build Mater (6): 78–80. Liu QW (2008) Application of calcium carbide slag instead of limestone in cement production. Dev Guide Build Mater (6): 78–80.
14.
go back to reference Ye DZ, Zhang L, Huang TS (2004) Experimental study of the effect of calcium carbide sludge used as the admixture of cement on the properties and structure of the cement. J Fuzhou Univ (Nat Sci) 32(1): 43–46. Ye DZ, Zhang L, Huang TS (2004) Experimental study of the effect of calcium carbide sludge used as the admixture of cement on the properties and structure of the cement. J Fuzhou Univ (Nat Sci) 32(1): 43–46.
15.
go back to reference Qiu SH, Yuan G, Lin XJ (2004) Study on substitution of modified calcium carbide sludge for gypsum to grind Portland. Cement (3): 3–5. Qiu SH, Yuan G, Lin XJ (2004) Study on substitution of modified calcium carbide sludge for gypsum to grind Portland. Cement (3): 3–5.
16.
go back to reference Li L, Bi JD, Bai YW et al (2013) Study on calcination and clinkerization differences between raw meal with carbide slag proportion and ordinary raw meal. Cem Guide N Epoch (3): 18–21. Li L, Bi JD, Bai YW et al (2013) Study on calcination and clinkerization differences between raw meal with carbide slag proportion and ordinary raw meal. Cem Guide N Epoch (3): 18–21.
17.
go back to reference Li HZ (2012) Production of cement with 100% dry discharged carbide slag instead of limestone. Cem Eng (5): 77–78. Li HZ (2012) Production of cement with 100% dry discharged carbide slag instead of limestone. Cem Eng (5): 77–78.
18.
go back to reference Jiang WG (2016) Production of high sulfate resistant Portland clinker with 100% carbide slag. Cement (6): 18–19. Jiang WG (2016) Production of high sulfate resistant Portland clinker with 100% carbide slag. Cement (6): 18–19.
19.
go back to reference He LB (2011) The proportioning scheme and quality control of 100% carbide slag instead of limestone for production of low alkali clinker. Sichuan Cem (3): 42–43. He LB (2011) The proportioning scheme and quality control of 100% carbide slag instead of limestone for production of low alkali clinker. Sichuan Cem (3): 42–43.
20.
go back to reference Hou XQ, Li HZ, Yu J et al (2007) The production of cement clinker by dry process with 100% carbide slag instead of natural calcareous materials. China Patent CN 1887765A, 3 Jan 2007. Hou XQ, Li HZ, Yu J et al (2007) The production of cement clinker by dry process with 100% carbide slag instead of natural calcareous materials. China Patent CN 1887765A, 3 Jan 2007.
21.
go back to reference Chen CL, Li SY (2013) Production of green low carbon cement from calcium carbide slag. Shihezi Sci Technol (3): 25–28. Chen CL, Li SY (2013) Production of green low carbon cement from calcium carbide slag. Shihezi Sci Technol (3): 25–28.
22.
go back to reference Jin SY, Zhao J, Bian GY (2014) The advances in application of flue gas desulfurization technologies in foreign countries. Sino-Global Energy 19(3): 89–95. Jin SY, Zhao J, Bian GY (2014) The advances in application of flue gas desulfurization technologies in foreign countries. Sino-Global Energy 19(3): 89–95.
23.
go back to reference Zhu QQ (2006) The desulfurization process with carbide slag in CFB boiler. Dissertation, Lanzhou University of Technology. Zhu QQ (2006) The desulfurization process with carbide slag in CFB boiler. Dissertation, Lanzhou University of Technology.
24.
go back to reference Lin XF, Zhang J, Yin YS et al (2014) Discussion on techniques of gas desulfurization and denitration. Energy Environ Prot 28(1): 1–4. Lin XF, Zhang J, Yin YS et al (2014) Discussion on techniques of gas desulfurization and denitration. Energy Environ Prot 28(1): 1–4.
25.
go back to reference Zhu SY (2001) Environment and industry gas cleaning technology. Chemical Industry Press, Beijing. Zhu SY (2001) Environment and industry gas cleaning technology. Chemical Industry Press, Beijing.
26.
go back to reference Hu MY, Liu BW, Wang LD et al (2003) Effect of boiler operation on wet desulfuration system. J N Chin Electr Power Univ (Nat Sci Ed) 30(4): 97–99. Hu MY, Liu BW, Wang LD et al (2003) Effect of boiler operation on wet desulfuration system. J N Chin Electr Power Univ (Nat Sci Ed) 30(4): 97–99.
27.
go back to reference Zhong Q (2002) Flue gas desulfurization and denitrification technology and engineering example (First Edition). Chemical Industry Press, Beijing. Zhong Q (2002) Flue gas desulfurization and denitrification technology and engineering example (First Edition). Chemical Industry Press, Beijing.
28.
go back to reference Yan XR (2011) Technical analysis on use of carbide slag as desulphurizing agent in wet FGD system. Huadian Technol 33(9): 81–84. Yan XR (2011) Technical analysis on use of carbide slag as desulphurizing agent in wet FGD system. Huadian Technol 33(9): 81–84.
29.
go back to reference Shih SM, Lin JP, Shiau GY (2000) Dissolution rates of limestones of different sources. J hazard mater (B79): 159–171.CrossRef Shih SM, Lin JP, Shiau GY (2000) Dissolution rates of limestones of different sources. J hazard mater (B79): 159–171.CrossRef
30.
go back to reference Dong Y, Zhou QL, Hui SE et al (2006) Dissolution characteristics of carbide slag during wet flue gas desulfurization. J Power Eng 26(6): 884–887. Dong Y, Zhou QL, Hui SE et al (2006) Dissolution characteristics of carbide slag during wet flue gas desulfurization. J Power Eng 26(6): 884–887.
31.
go back to reference Lv HJ (2011) Application analysis of flue gas desulfurization with carbide slag-gypsum. Power Syst Eng 27(1): 41–42. Lv HJ (2011) Application analysis of flue gas desulfurization with carbide slag-gypsum. Power Syst Eng 27(1): 41–42.
32.
go back to reference Sun CY, Zhang P (2012) The application of acetylene sludge in WFGD in the thermal power plant. J Chongqing Electr Power Coll 17(5): 91–94. Sun CY, Zhang P (2012) The application of acetylene sludge in WFGD in the thermal power plant. J Chongqing Electr Power Coll 17(5): 91–94.
33.
go back to reference Yin CL, Yang YY, Lv YL et al (2013) Effects of impurities of carbide slag on the oxidation of calcium sulfite and dewatering performance of gypsum slurry. Environ Eng 31(2): 109–114. Yin CL, Yang YY, Lv YL et al (2013) Effects of impurities of carbide slag on the oxidation of calcium sulfite and dewatering performance of gypsum slurry. Environ Eng 31(2): 109–114.
34.
go back to reference Chuang XH, Xu XS (2012) Discussion on problems existed in carbide slag wet FGD system. Electr Power Technol Environ Prot 28(2): 42–44. Chuang XH, Xu XS (2012) Discussion on problems existed in carbide slag wet FGD system. Electr Power Technol Environ Prot 28(2): 42–44.
35.
go back to reference Xu HJ, Li HR, Sun SJ et al (2015) Effects of organic acid additives on enhancement of carbide slag flue gas desulfurization. J China Soc Power Eng 35(8): 659–665. Xu HJ, Li HR, Sun SJ et al (2015) Effects of organic acid additives on enhancement of carbide slag flue gas desulfurization. J China Soc Power Eng 35(8): 659–665.
36.
go back to reference Gao WY, Ma TC (2003) Study on autoclaved brick made of the water-granulated slag of fly ash and carbide slag. N Wall Mater Constr (8): 35–36. Gao WY, Ma TC (2003) Study on autoclaved brick made of the water-granulated slag of fly ash and carbide slag. N Wall Mater Constr (8): 35–36.
37.
go back to reference Wu QW, Shi LY, Zhang ZY (2002) Preparation of nanometer calcium carbonate particles by calcium carbide residue. J Shanghai Univ (Nat Sci Ed) 8(3): 247–250. Wu QW, Shi LY, Zhang ZY (2002) Preparation of nanometer calcium carbonate particles by calcium carbide residue. J Shanghai Univ (Nat Sci Ed) 8(3): 247–250.
Metadata
Title
Comprehensive Utilization of Carbide Slag
Authors
Fenglan Han
Laner Wu
Copyright Year
2019
Publisher
Springer Singapore
DOI
https://doi.org/10.1007/978-981-13-8086-0_7