Confined space effects driving to heterogenization of solutions at the interfaces

go back to reference Brennan, J.K., Bandosz, T.J., Thomson, K.T., Gubbins, K.E.: Water in porous carbons. Colloids Surf. A, Physicochem. Eng. Asp. 187–188, 539–568 (2001) CrossRef Brennan, J.K., Bandosz, T.J., Thomson, K.T., Gubbins, K.E.: Water in porous carbons. Colloids Surf. A, Physicochem. Eng. Asp. 187–188, 539–568 (2001) CrossRef

go back to reference Chaplin, M.: Water structure and science (2011). http://www.lsbu.ac.uk/water/ Chaplin, M.: Water structure and science (2011). http://​www.​lsbu.​ac.​uk/​water/​

go back to reference Derjaguin, B.V., Churaev, N.V., Muller, V.M.: Surface Forces. Consultants Bureau, New York (1987) CrossRef Derjaguin, B.V., Churaev, N.V., Muller, V.M.: Surface Forces. Consultants Bureau, New York (1987) CrossRef

go back to reference Derjaguin, B.V., Ovcharenko, F.D., Churaev, N.V. (eds.): Water in Disperse Systems. Khimiya, Moscow (1989) Derjaguin, B.V., Ovcharenko, F.D., Churaev, N.V. (eds.): Water in Disperse Systems. Khimiya, Moscow (1989)

go back to reference Drago, R.S.: Physical Methods in Chemistry. Saunders, Philadelphia (1977) Drago, R.S.: Physical Methods in Chemistry. Saunders, Philadelphia (1977)

go back to reference Emsley, J.W., Feenej, J., Sutcliffe, L.H.: High Resolution Nuclear Magnetic Resonance Spectroscopy. Pergamon, Oxford (1965) Emsley, J.W., Feenej, J., Sutcliffe, L.H.: High Resolution Nuclear Magnetic Resonance Spectroscopy. Pergamon, Oxford (1965)

go back to reference Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Montgomery, J.A., Vreven, T. Jr., Kudin, K.N., Burant, J.C., Millam, J.M., Iyengar, S.S., Tomasi, J., Barone, V., Mennucci, B., Cossi, M., Scalmani, G., Rega, N., Petersson, G.A., Nakatsuji, H., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Klene, M., Li, X., Knox, J.E., Hratchian, H.P., Cross, J.B., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R.E., Yazyev, O., Austin, A.J., Cammi, R., Pomelli, C., Ochterski, J.W., Ayala, P.Y., Morokuma, K., Voth, G.A., Salvador, P., Dannenberg, J.J., Zakrzewski, V.G., Dapprich, S., Daniels, A.D., Strain, M.C., Farkas, O., Malick, D.K., Rabuck, A.D., Raghavachari, K., Foresman, J.B., Ortiz, J.V., Cui, Q., Baboul, A.G., Clifford, S., Cioslowski, J., Stefanov, B.B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Martin, R.L., Fox, D.J., Keith, T., Al-Laham, M.A., Peng, C.Y., Nanayakkara, A., Challacombe, M., Gill, P.M.W., Johnson, B., Chen, W., Wong, M.W., Gonzalez, C., Pople, J.A.: Gaussian 03 Revision E.01. Gaussian, Inc., Wallingford, CT (2004) Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Montgomery, J.A., Vreven, T. Jr., Kudin, K.N., Burant, J.C., Millam, J.M., Iyengar, S.S., Tomasi, J., Barone, V., Mennucci, B., Cossi, M., Scalmani, G., Rega, N., Petersson, G.A., Nakatsuji, H., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Klene, M., Li, X., Knox, J.E., Hratchian, H.P., Cross, J.B., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R.E., Yazyev, O., Austin, A.J., Cammi, R., Pomelli, C., Ochterski, J.W., Ayala, P.Y., Morokuma, K., Voth, G.A., Salvador, P., Dannenberg, J.J., Zakrzewski, V.G., Dapprich, S., Daniels, A.D., Strain, M.C., Farkas, O., Malick, D.K., Rabuck, A.D., Raghavachari, K., Foresman, J.B., Ortiz, J.V., Cui, Q., Baboul, A.G., Clifford, S., Cioslowski, J., Stefanov, B.B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Martin, R.L., Fox, D.J., Keith, T., Al-Laham, M.A., Peng, C.Y., Nanayakkara, A., Challacombe, M., Gill, P.M.W., Johnson, B., Chen, W., Wong, M.W., Gonzalez, C., Pople, J.A.: Gaussian 03 Revision E.01. Gaussian, Inc., Wallingford, CT (2004)

go back to reference Glushko, V.P. (ed.): Handbook of Thermodynamic Properties of Individual Substances. Nauka, Moscow (1978) (in Russian) Glushko, V.P. (ed.): Handbook of Thermodynamic Properties of Individual Substances. Nauka, Moscow (1978) (in Russian)

go back to reference Gregg, S.J., Sing, K.S.W.: Adsorption, Surface Area and Porosity. Academic Press, London (1982) Gregg, S.J., Sing, K.S.W.: Adsorption, Surface Area and Porosity. Academic Press, London (1982)

go back to reference Gun’ko, V.M., Mikhalovsky, S.V.: Evaluation of slitlike porosity of carbon adsorbents. Carbon 42, 843–849 (2004) CrossRef Gun’ko, V.M., Mikhalovsky, S.V.: Evaluation of slitlike porosity of carbon adsorbents. Carbon 42, 843–849 (2004) CrossRef

go back to reference Gun’ko, V.M., Turov, V.V.: Nuclear Magnetic Resonance Studies of Interfacial Phenomena. Taylor & Francis, San Diego (2013, in press) CrossRef Gun’ko, V.M., Turov, V.V.: Nuclear Magnetic Resonance Studies of Interfacial Phenomena. Taylor & Francis, San Diego (2013, in press) CrossRef

go back to reference Gun’ko, V.M., Turov, V.V., Bogatyrev, V.M., Zarko, V.I., Leboda, R., Goncharuk, E.V., Novza, A.A., Turov, A.V., Chuiko, A.A.: Unusual properties of water at hydrophilic/hydrophobic interfaces. Adv. Colloid Interface Sci. 118, 125–172 (2005) Gun’ko, V.M., Turov, V.V., Bogatyrev, V.M., Zarko, V.I., Leboda, R., Goncharuk, E.V., Novza, A.A., Turov, A.V., Chuiko, A.A.: Unusual properties of water at hydrophilic/hydrophobic interfaces. Adv. Colloid Interface Sci. 118, 125–172 (2005)

go back to reference Gun’ko, V.M., Turov, V.V., Gorbik, P.P.: Water at the Interfaces, Naukova Dumka, Kiev (2009) (in Russian) Gun’ko, V.M., Turov, V.V., Gorbik, P.P.: Water at the Interfaces, Naukova Dumka, Kiev (2009) (in Russian)

go back to reference Gun’ko, V.M., Morozova, L.P., Turova, A.A., Turov, A.V., Gaishun, V.E., Bogatyrev, V.M., Turov, V.V.: Hydrated phosphorus oxyacids alone and adsorbed on nanosilica. J. Colloid Interface Sci. 368, 263–272 (2012a) CrossRef Gun’ko, V.M., Morozova, L.P., Turova, A.A., Turov, A.V., Gaishun, V.E., Bogatyrev, V.M., Turov, V.V.: Hydrated phosphorus oxyacids alone and adsorbed on nanosilica. J. Colloid Interface Sci. 368, 263–272 (2012a) CrossRef

go back to reference Gun’ko, V.M., Turov, V.V., Whitby, R.L.D., Prykhod’ko, G.P., Turov, A.V., Mikhalovsky, S.V.: Interactions of single and multi-layer graphene oxides with water, methane, organic solvents and HCl studied by 1H NMR method. Carbon (2012b, submitted for publication) Gun’ko, V.M., Turov, V.V., Whitby, R.L.D., Prykhod’ko, G.P., Turov, A.V., Mikhalovsky, S.V.: Interactions of single and multi-layer graphene oxides with water, methane, organic solvents and HCl studied by ¹H NMR method. Carbon (2012b, submitted for publication)

go back to reference Hess, W.T.: Hydrogen peroxide. In: Kirk-Othmer Encyclopedia of Chemical Technology, 4th edn., vol. 13, pp. 961–995. Wiley, New York (1995) Hess, W.T.: Hydrogen peroxide. In: Kirk-Othmer Encyclopedia of Chemical Technology, 4th edn., vol. 13, pp. 961–995. Wiley, New York (1995)

go back to reference Israelachvili, J.N., Wennerstrom, H.: Hydration or steric forces between amphiphilic surfaces? Langmuir 6, 873–876 (1990) CrossRef Israelachvili, J.N., Wennerstrom, H.: Hydration or steric forces between amphiphilic surfaces? Langmuir 6, 873–876 (1990) CrossRef

go back to reference Jieli, M., Aida, M.: Classification of OH bonds and infrared spectra of the topology-distinct protonated water clusters H3O+(H2O) n−1 (n≤7). J. Phys. Chem. A 113, 1586–1594 (2009) CrossRef Jieli, M., Aida, M.: Classification of OH bonds and infrared spectra of the topology-distinct protonated water clusters H₃O⁺(H₂O) _n−1 (n≤7). J. Phys. Chem. A 113, 1586–1594 (2009) CrossRef

go back to reference Jones, C.W.: Applications of Hydrogen Peroxide and Derivatives. Royal Chem. Soc., Cambridge (1999) Jones, C.W.: Applications of Hydrogen Peroxide and Derivatives. Royal Chem. Soc., Cambridge (1999)

go back to reference Leninsky, M.I., Mazanko, A.F., Novikov, I.N.: Hydrogen Chloride and Hydrochloric Acid. Khimiya, Moscow (1985) Leninsky, M.I., Mazanko, A.F., Novikov, I.N.: Hydrogen Chloride and Hydrochloric Acid. Khimiya, Moscow (1985)

go back to reference March, J.: Advanced Organic Chemistry, 4th edn. Wiley, New York (1992) March, J.: Advanced Organic Chemistry, 4th edn. Wiley, New York (1992)

go back to reference Mitchell, J., Webber, J.B.W., Strange, J.H.: Nuclear magnetic resonance cryoporometry. Phys. Rep. 461, 1–36 (2008) CrossRef Mitchell, J., Webber, J.B.W., Strange, J.H.: Nuclear magnetic resonance cryoporometry. Phys. Rep. 461, 1–36 (2008) CrossRef

go back to reference Murakhtina, T., Heuft, J., Meijer, E.J., Sebastiani, D.: First principles and experimental 1H NMR signatures of solvated ions: the case of HCl(aq). Chem. Phys. Chem. 7, 2578–2584 (2006) CrossRef Murakhtina, T., Heuft, J., Meijer, E.J., Sebastiani, D.: First principles and experimental ¹H NMR signatures of solvated ions: the case of HCl(aq). Chem. Phys. Chem. 7, 2578–2584 (2006) CrossRef

go back to reference Nekrasov, B.V.: Fundamentals of General Chemistry. Khimya, Moscow (1973) Nekrasov, B.V.: Fundamentals of General Chemistry. Khimya, Moscow (1973)

go back to reference Petrov, O.V., Furó, I.: NMR cryoporometry: principles, applications and potential. Prog. Nucl. Magn. Reson. Spectrosc. 54, 97–122 (2009) CrossRef Petrov, O.V., Furó, I.: NMR cryoporometry: principles, applications and potential. Prog. Nucl. Magn. Reson. Spectrosc. 54, 97–122 (2009) CrossRef

go back to reference Pople, J.A., Schneider, W.G., Bernstein, H.J.: High-Resolution Nuclear Magnetic Resonance. McGraw-Hill, New York (1959) Pople, J.A., Schneider, W.G., Bernstein, H.J.: High-Resolution Nuclear Magnetic Resonance. McGraw-Hill, New York (1959)

go back to reference Schuster, M., Kreuer, K.-D., Steininger, H., Maier, J.: Proton conductivity and diffusion study of molten phosphonic acid H3PO3. Solid State Ion. 179, 523–528 (2008) CrossRef Schuster, M., Kreuer, K.-D., Steininger, H., Maier, J.: Proton conductivity and diffusion study of molten phosphonic acid H₃PO₃. Solid State Ion. 179, 523–528 (2008) CrossRef

go back to reference Stephenson, N.A., Bell, A.T.: Quantitative analysis of hydrogen peroxide by 1H NMR spectroscopy. Anal. Bioanal. Chem. 381, 1289–1293 (2005) CrossRef Stephenson, N.A., Bell, A.T.: Quantitative analysis of hydrogen peroxide by ¹H NMR spectroscopy. Anal. Bioanal. Chem. 381, 1289–1293 (2005) CrossRef

go back to reference Stewart, J.J.P.: MOPAC2012. Stewart Computational Chemistry, Colorado Springs, CO, USA. http://openmopac.net/MOPAC2012.html (2012) Stewart, J.J.P.: MOPAC2012. Stewart Computational Chemistry, Colorado Springs, CO, USA. http://​openmopac.​net/​MOPAC2012.​html (2012)

go back to reference Strange, J.H., Rahman, M., Smith, E.G.: Characterization of porous solids by NMR. Phys. Rev. Lett. 71, 3589–3591 (1993) CrossRef Strange, J.H., Rahman, M., Smith, E.G.: Characterization of porous solids by NMR. Phys. Rev. Lett. 71, 3589–3591 (1993) CrossRef

go back to reference Tolstoy, P.M., Smirnov, S.N., Shenderovich, I.G., Golubev, N.S., Denisov, G.S., Limbacha, H.-H.: NMR studies of solid state—solvent and H/D isotope effects on hydrogen bond geometries of 1:1 complexes of collidine with carboxylic acids. J. Mol. Struct. 700, 19–27 (2004) CrossRef Tolstoy, P.M., Smirnov, S.N., Shenderovich, I.G., Golubev, N.S., Denisov, G.S., Limbacha, H.-H.: NMR studies of solid state—solvent and H/D isotope effects on hydrogen bond geometries of 1:1 complexes of collidine with carboxylic acids. J. Mol. Struct. 700, 19–27 (2004) CrossRef

go back to reference Turov, V.V., Gun’ko, V.M.: Clustered Water and Ways of Its Applications. Naukova Dumka, Kiev (2011) Turov, V.V., Gun’ko, V.M.: Clustered Water and Ways of Its Applications. Naukova Dumka, Kiev (2011)

go back to reference Turov, V.V., Gun’ko, V.M., Zarko, V.I., Bogatyr’ov, V.M., Dudnik, V.V., Chuiko, A.A.: Water adsorption at pyrogenic silica surfaces modified by phosphorus compounds. Langmuir 12, 3503–3510 (1996) CrossRef Turov, V.V., Gun’ko, V.M., Zarko, V.I., Bogatyr’ov, V.M., Dudnik, V.V., Chuiko, A.A.: Water adsorption at pyrogenic silica surfaces modified by phosphorus compounds. Langmuir 12, 3503–3510 (1996) CrossRef

go back to reference Turov, V.V., Gun’ko, V.M., Gaishun, V.E., Kosenok, Y.A., Golovan, A.P.: Application of NMR spectroscopy to determine the thermodynamic characteristics of water bound to OX-50 nanosilica. J. Appl. Spectrosc. 77, 588–594 (2010) CrossRef Turov, V.V., Gun’ko, V.M., Gaishun, V.E., Kosenok, Y.A., Golovan, A.P.: Application of NMR spectroscopy to determine the thermodynamic characteristics of water bound to OX-50 nanosilica. J. Appl. Spectrosc. 77, 588–594 (2010) CrossRef

go back to reference Turov, V.V., Gun’ko, V.M., Turova, A.A., Morozova, L.P., Voronin, E.F.: Interfacial behavior of concentrated HCl solution and water clustered at a surface of nanosilica in weakly polar solvents media. Colloids Surf. A, Physicochem. Eng. Asp. 390, 48–55 (2011) CrossRef Turov, V.V., Gun’ko, V.M., Turova, A.A., Morozova, L.P., Voronin, E.F.: Interfacial behavior of concentrated HCl solution and water clustered at a surface of nanosilica in weakly polar solvents media. Colloids Surf. A, Physicochem. Eng. Asp. 390, 48–55 (2011) CrossRef

go back to reference Zhang, S.: Direct detection of hydrogen peroxide via 1H CEST-MRI. Proc. Int. Soc. Magn. Reson. Med. 15, 3461 (2007) Zhang, S.: Direct detection of hydrogen peroxide via ¹H CEST-MRI. Proc. Int. Soc. Magn. Reson. Med. 15, 3461 (2007)