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2012 | OriginalPaper | Chapter

4. Crystal Structure

Author : Dr. Walter Borchardt-Ott

Published in: Crystallography

Publisher: Springer Berlin Heidelberg

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Abstract

In order to progress from a lattice to a crystal, the points of the lattice must be occupied by atoms, ions or molecules. Because the points are all identical, the collections of objects occupying them must also be identical. In general, crystals are not built up so simply as the crystal of α -polonium in Fig. 3.1!
Let us consider the construction of a crystal by means of a hypothetical example. Figure 4.1a shows a lattice with a rectangular unit cell projected on the a, b-plane. We now place the molecule ABC in the unit cell of the lattice in such a way that A lies at the origin and B and C within the chosen cell (Fig. 4.1b).
The coordinates are yet another triple: x,y,z, where 0 ≤ x,y,z < 1 for all positions within the unit cell.

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Footnotes
1
The Ångström unit (Å): 1 Å = 10–8 cm = 0.1 nm. If a row of spheres with a radius of 1 Å is made, these will be 50,000,000 of them per centimeter! https://static-content.springer.com/image/chp%3A10.1007%2F978-3-642-16452-1_4/MediaObjects/1370_3_En_4_Figd_HTML.gif
 
Metadata
Title
Crystal Structure
Author
Dr. Walter Borchardt-Ott
Copyright Year
2012
Publisher
Springer Berlin Heidelberg
DOI
https://doi.org/10.1007/978-3-642-16452-1_4