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Published in: Journal of Nanoparticle Research 12/2012

01-12-2012 | Research Paper

CuO/Ta2O5 core/shell nanoparticles synthesized in immersed arc-discharge: production conditions and dielectric response

Authors: P. K. Karahaliou, P. Svarnas, S. N. Georga, N. I. Xanthopoulos, D. Delaportas, C. A. Krontiras, I. Alexandrou

Published in: Journal of Nanoparticle Research | Issue 12/2012

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Abstract

We reported recently on a novel nanostructured material produced by the arc-discharge in water method, and extended studies were realized to identify the nature of this material, i.e., CuO/Ta2O5 core/shell crystalline nanoparticles (NPs). As a continuation of this investigation on the possibility of complex NP synthesis using immersed arc-discharge, the production conditions of the CuO/Ta2O5 NPs are herein presented in detail and the electrical properties of the nanopowder are examined comprehensively. The discharge is thus probed in situ by electrical measurements, optical emission spectroscopy and high speed imaging, and the electrical behavior of the NPs is considered by means of broadband dielectric spectroscopy. This combined study provides an integrated characterization of this new material, unveils its potential applications, and makes available suggestions on the process control.

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Literature
go back to reference Ashkarran AA (2011) Metal and metal oxides nanostructures prepared by electrical arc discharge method in liquids. J Clust Sci 22:233–266CrossRef Ashkarran AA (2011) Metal and metal oxides nanostructures prepared by electrical arc discharge method in liquids. J Clust Sci 22:233–266CrossRef
go back to reference Bhushan B (2004) Introduction to nanotechnology. In: Bhushan B (ed) Handbook of nanotechnology. Springer, Heidelberg, pp 1–6CrossRef Bhushan B (2004) Introduction to nanotechnology. In: Bhushan B (ed) Handbook of nanotechnology. Springer, Heidelberg, pp 1–6CrossRef
go back to reference Böttcher CJF, Bordewijk P (1978) Theory of electric polarization. Elsevier, Amsterdam Böttcher CJF, Bordewijk P (1978) Theory of electric polarization. Elsevier, Amsterdam
go back to reference Delaportas D, Svarnas P, Alexandrou I, Siokou A, Black K, Bradley JW (2009) γ-Al2O3 nanoparticle production by arc-discharge in water: in situ discharge characterization and nanoparticle investigation. J Phys D 42(24):5204 11 ppCrossRef Delaportas D, Svarnas P, Alexandrou I, Siokou A, Black K, Bradley JW (2009) γ-Al2O3 nanoparticle production by arc-discharge in water: in situ discharge characterization and nanoparticle investigation. J Phys D 42(24):5204 11 ppCrossRef
go back to reference Delaportas D, Svarnas P, Alexandrou I (2010) Ta2O5 crystalline nanoparticle synthesis by DC anodic arc in water. J Electrochem Soc 157(6):K138–K143CrossRef Delaportas D, Svarnas P, Alexandrou I (2010) Ta2O5 crystalline nanoparticle synthesis by DC anodic arc in water. J Electrochem Soc 157(6):K138–K143CrossRef
go back to reference Delaportas D, Svarnas P, Alexandrou I, Hall S (2011a) Plasma of arc discharge in water for the formation of diverse nanostructures dependent on the anode material. IEEE Trans Plasma Sci 39(11):2628–2629CrossRef Delaportas D, Svarnas P, Alexandrou I, Hall S (2011a) Plasma of arc discharge in water for the formation of diverse nanostructures dependent on the anode material. IEEE Trans Plasma Sci 39(11):2628–2629CrossRef
go back to reference Delaportas D, Svarnas P, Alexandrou I, Georga SN, Krontiras CA, Xanthopoulos NI, Siokou A, Chalker PR (2011b) CuO/Ta2O5 core/shell nanoparticles produced by arc-discharge in water. Mater Lett 65:2337–2340CrossRef Delaportas D, Svarnas P, Alexandrou I, Georga SN, Krontiras CA, Xanthopoulos NI, Siokou A, Chalker PR (2011b) CuO/Ta2O5 core/shell nanoparticles produced by arc-discharge in water. Mater Lett 65:2337–2340CrossRef
go back to reference Fontanella JJ, Wintersgill MC, Edmondson CA, Lomax JF (2009) Water-associated dielectric relaxation in oxide nanoparticles. J Phys D 42:042003CrossRef Fontanella JJ, Wintersgill MC, Edmondson CA, Lomax JF (2009) Water-associated dielectric relaxation in oxide nanoparticles. J Phys D 42:042003CrossRef
go back to reference Gutsch A, Krämer M, Michael G, Mühlenweg H, Pridöhl M, Zimmermann G (2002) Gas-phase production of nanoparticles. Kona 20:24–37 Gutsch A, Krämer M, Michael G, Mühlenweg H, Pridöhl M, Zimmermann G (2002) Gas-phase production of nanoparticles. Kona 20:24–37
go back to reference Kontos GA, Soulintzis AL, Karahaliou PK, Psarras GC, Georga SN, Krontiras CA, Pisanias MN (2007) Electrical relaxation dynamics in TiO(2)—polymer matrix composites. Express Polym Lett 1:781–789CrossRef Kontos GA, Soulintzis AL, Karahaliou PK, Psarras GC, Georga SN, Krontiras CA, Pisanias MN (2007) Electrical relaxation dynamics in TiO(2)—polymer matrix composites. Express Polym Lett 1:781–789CrossRef
go back to reference Kremer F, Schönhals A (2003) Analysis of dielectric spectra. In: Kremer F, Schönhals A (eds) Broadband dielectric spectroscopy. Springer, HeidelbergCrossRef Kremer F, Schönhals A (2003) Analysis of dielectric spectra. In: Kremer F, Schönhals A (eds) Broadband dielectric spectroscopy. Springer, HeidelbergCrossRef
go back to reference Lin Y, Jiang L, Zhao R, Liu G, Nan C-W (2005) Preparation of core/shell structured NiO-based ceramics and their dielectric properties. J Phys D 38:1615CrossRef Lin Y, Jiang L, Zhao R, Liu G, Nan C-W (2005) Preparation of core/shell structured NiO-based ceramics and their dielectric properties. J Phys D 38:1615CrossRef
go back to reference Mpoukouvalas K, Wang J, Wegner G (2010) Conductivity of poly(pyrrole)-poly(styrene sulfonate) core-shell nanoparticles analyzed by impedance spectroscopy: effect of alkali counter ions. Chem Phys Chem 11:139–148CrossRef Mpoukouvalas K, Wang J, Wegner G (2010) Conductivity of poly(pyrrole)-poly(styrene sulfonate) core-shell nanoparticles analyzed by impedance spectroscopy: effect of alkali counter ions. Chem Phys Chem 11:139–148CrossRef
go back to reference Nasser E (1971) Fundamentals of gaseous ionization and plasma electronics. Wiley-Interscience, New York, p 189 Nasser E (1971) Fundamentals of gaseous ionization and plasma electronics. Wiley-Interscience, New York, p 189
go back to reference Neagu E, Pissis P, Apekis L (2000) Electrical conductivity effects in polyethylene terephthalate films. J Appl Phys 87:2914CrossRef Neagu E, Pissis P, Apekis L (2000) Electrical conductivity effects in polyethylene terephthalate films. J Appl Phys 87:2914CrossRef
go back to reference Patel HK, Martin SW (1992) Fast ionic conduction in Na2S + B2S3 glasses: compositional contributions to nonexponentiality in conductivity relaxation in the extreme low-alkali-metal limit. Phys Rev B 45:10292CrossRef Patel HK, Martin SW (1992) Fast ionic conduction in Na2S + B2S3 glasses: compositional contributions to nonexponentiality in conductivity relaxation in the extreme low-alkali-metal limit. Phys Rev B 45:10292CrossRef
go back to reference Pissis P, Anagnostopoulou-Konsta A, Apekis L, Daoukaki-Diamanti D, Christodoulides C (1991) Dielectric effects of water in water-containing systems. J Non Cryst Solids 131–133:1174–1181CrossRef Pissis P, Anagnostopoulou-Konsta A, Apekis L, Daoukaki-Diamanti D, Christodoulides C (1991) Dielectric effects of water in water-containing systems. J Non Cryst Solids 131–133:1174–1181CrossRef
go back to reference Psarras GC (2010) Conductivity and dielectric characterization of polymer nanocomposites. In: Tjong SC, Mai Y-W (eds) Physical properties and applications of polymer nanocomposites. Woodhead Publishing Limited, Oxford Psarras GC (2010) Conductivity and dielectric characterization of polymer nanocomposites. In: Tjong SC, Mai Y-W (eds) Physical properties and applications of polymer nanocomposites. Woodhead Publishing Limited, Oxford
go back to reference Psarras GC, Gatos KG, Karahaliou PK, Georga SN, Krontiras CA, Karger-Kocsis J (2007) Relaxation phenomena in rubber/layered silicate nanocomposites. Express Polym Lett 1:837–845CrossRef Psarras GC, Gatos KG, Karahaliou PK, Georga SN, Krontiras CA, Karger-Kocsis J (2007) Relaxation phenomena in rubber/layered silicate nanocomposites. Express Polym Lett 1:837–845CrossRef
go back to reference Psarras GC, Siengchin S, Karahaliou PK, Georga SN, Krontiras CA, Karger-Kocsis J (2011) Dielectric relaxation phenomena and dynamics in polyoxymethylene/polyurethane/alumina hybrid nanocomposites. Polym Int 60:1715–1721CrossRef Psarras GC, Siengchin S, Karahaliou PK, Georga SN, Krontiras CA, Karger-Kocsis J (2011) Dielectric relaxation phenomena and dynamics in polyoxymethylene/polyurethane/alumina hybrid nanocomposites. Polym Int 60:1715–1721CrossRef
go back to reference Raiser YuP (1997) Gas discharge physics. Springer, Berlin, p 245 Raiser YuP (1997) Gas discharge physics. Springer, Berlin, p 245
go back to reference Shukla D, Mehra A (2006) Modeling shell formation in core-shell nanocrystals in reverse micelle systems. Langmuir 22(23):9500–9506CrossRef Shukla D, Mehra A (2006) Modeling shell formation in core-shell nanocrystals in reverse micelle systems. Langmuir 22(23):9500–9506CrossRef
go back to reference Spanoudaki A, Albela B, Bonneviot L, Peyrard M (2005) The dynamics of water in nanoporous silica studied by dielectric spectroscopy. Eur Phys J E 17:21–27CrossRef Spanoudaki A, Albela B, Bonneviot L, Peyrard M (2005) The dynamics of water in nanoporous silica studied by dielectric spectroscopy. Eur Phys J E 17:21–27CrossRef
go back to reference Tsangaris GM, Psarras GC, Kouloumbi N (1998) Electric modulus and interfacial polarization in composite polymeric systems. J Mater Sci 33:2027–2037CrossRef Tsangaris GM, Psarras GC, Kouloumbi N (1998) Electric modulus and interfacial polarization in composite polymeric systems. J Mater Sci 33:2027–2037CrossRef
go back to reference Vassilikou-Dova A, Kalogeras IM (2009) Dielectric analysis (DEA). In: Menczel JD, Bruce PR (eds) Thermal analysis of polymers, fundamentals and applications. Wiley, Hoboken Vassilikou-Dova A, Kalogeras IM (2009) Dielectric analysis (DEA). In: Menczel JD, Bruce PR (eds) Thermal analysis of polymers, fundamentals and applications. Wiley, Hoboken
go back to reference Xu P, Zhang X (2011) Investigation of MWS polarization and dc conductivity in polyamide 610 using dielectric relaxation spectroscopy. Eur Polym J 47:1031–1038CrossRef Xu P, Zhang X (2011) Investigation of MWS polarization and dc conductivity in polyamide 610 using dielectric relaxation spectroscopy. Eur Polym J 47:1031–1038CrossRef
go back to reference Zhang C, Stevens GC (2008) The dielectric response of polar and non-polar nanodielectrics. IEEE Trans Dielectr Electr Insul 15:606–617CrossRef Zhang C, Stevens GC (2008) The dielectric response of polar and non-polar nanodielectrics. IEEE Trans Dielectr Electr Insul 15:606–617CrossRef
Metadata
Title
CuO/Ta2O5 core/shell nanoparticles synthesized in immersed arc-discharge: production conditions and dielectric response
Authors
P. K. Karahaliou
P. Svarnas
S. N. Georga
N. I. Xanthopoulos
D. Delaportas
C. A. Krontiras
I. Alexandrou
Publication date
01-12-2012
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 12/2012
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-012-1297-3

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