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Journal of Polymer Research
Published in: Journal of Polymer Research 2/2016

01-02-2016 | Original Paper

Cyclodextrin-grafted thiacalix [4]arene netty polymer based on the click chemistry: preparation and efficient adsorption for organic dyes

Authors: Suichang Chen, Hongyu Guo, Fafu Yang, Xingdong Di

Published in: Journal of Polymer Research | Issue 2/2016

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Abstract

By reacting cyclodextrin-grafted thiacalix [4]arene derivative 9 containing three alkynyl groups with bis-azido compound 6, the first example of cyclodextrin-grafted thiacalix [4]arene netty polymer 10 was designed and prepared by the click chemistry in yield of 76 %. Its structure was confirmed by elemental analysis, 1H NMR spectrum, FTIR spectrum and XRD curve. The M n of polymer 10 was 48,677, indicating average approximately 22 units of compound 9 in each polymer molecule. Its SEM image showed porous and loose morphology. Adsorption experiments of polymer 10 indicated that it possessed excellent adsorption capacities for both cationic and anionic dyes [Orange G sodium salt (OG), Brilliant ponceau 5R (BP), Victoria blue B (VB), Crystal violet (CV), Neutral red (NR) and Methylene blue (MB)]. The highest adsorption capacities for VB, CV, NR and MB were 5.821, 6.825, 6.135 and 5.381 mmol/g, respectively. Adsorption kinetics and isotherms analysis suggested that all the adsorption processes were exothermic and spontaneous. The adsorption processes obeyed pseudo second-order model and the Langmuir isotherm equation. The adsorption abilities of polymer 10 at pH values 3–11 were keep stable between 1.5–4 mmol/g. The adsorption abilities for anionic dyes decreased with the increase of pH values but opposite phenomena for cationic dyes. Polymer 10 showed good reused adsorption property after desorption in five times’ cycles.
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Metadata
Title
Cyclodextrin-grafted thiacalix [4]arene netty polymer based on the click chemistry: preparation and efficient adsorption for organic dyes
Authors
Suichang Chen
Hongyu Guo
Fafu Yang
Xingdong Di
Publication date
01-02-2016
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 2/2016
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-016-0920-x

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