Skip to main content
Top
Published in: Journal of Polymer Research 6/2020

01-06-2020 | REVIEW PAPER

Development history and synthesis of super-absorbent polymers: a review

Authors: Xiaofang Ma, Guohua Wen

Published in: Journal of Polymer Research | Issue 6/2020

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Super-absorbent polymers (SAPs) refer to a three-dimensional network polymer, water-swellable, water-insoluble, organic or inorganic material that can absorb thousands of times its own weight of distilled water. It is widely used in various fields, such as: agricultural, biomedical, daily physiological products, separation technology and wastewater treatment. In the review, the development history of superabsorbent polymers since 1961 is described, and the polymerization methods of superabsorbent polymers and the wide-ranging use of this type of polymers in life are described in detail. The article introduces four basic polymerization methods, bulk polymerization, solution polymerization, suspension polymerization and radiation polymerization from the preparation methods and types. Not only the detailed methods of polymerization but also their respective advantages and disadvantages are introduced. In recent years, new progress has been made in polymerization methods, for example, in-situ polymerization to obtain an onion-like multilayer tube cellulose hydrogel. The hydrogel has super-absorbent properties, and the water swelling mechanism is briefly introduced. Finally, the latest advances in super-absorbent polymers are pointed out.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Yu X, Wang Z, Liu J, Mei H, Yong D, Li J (2019) Preparation, swelling behaviors and fertilizer-release properties of sodium humate modified superabsorbent resin. Materials Today Communications 19:124–130 Yu X, Wang Z, Liu J, Mei H, Yong D, Li J (2019) Preparation, swelling behaviors and fertilizer-release properties of sodium humate modified superabsorbent resin. Materials Today Communications 19:124–130
2.
go back to reference Feng K, Song LJ, Li R et al (2016) Absorbed Pb2+ and Cd2+ ions in water by cross-linked starch Xanthate. Mater Protec 49:177–180 Feng K, Song LJ, Li R et al (2016) Absorbed Pb2+ and Cd2+ ions in water by cross-linked starch Xanthate. Mater Protec 49:177–180
3.
go back to reference He G, Ke W, Chen X, Kong Y, Zheng H, Yin Y, Cai W (2017) Preparation and properties of quaternary ammonium chitosan-g-poly (acrylic acid-co-acrylamide) superabsorbent hydrogels. React Funct Polym 111:14–21 He G, Ke W, Chen X, Kong Y, Zheng H, Yin Y, Cai W (2017) Preparation and properties of quaternary ammonium chitosan-g-poly (acrylic acid-co-acrylamide) superabsorbent hydrogels. React Funct Polym 111:14–21
4.
go back to reference Mishra B, Upadhyay M, Reddy Adena S et al (2017) Hydrogels: an introduction to a controlled drug delivery device, synthesis and application in drug delivery and tissue engineering. Austin J Biomed Eng 4:1037 Mishra B, Upadhyay M, Reddy Adena S et al (2017) Hydrogels: an introduction to a controlled drug delivery device, synthesis and application in drug delivery and tissue engineering. Austin J Biomed Eng 4:1037
5.
go back to reference Sun D, Liu WY, Tang AM et al (2019) A new PEGDA/CNF aerogel-wet hydrogel scaffold fabricated by a two-step method. Soft Matter 15(40):8092–8810PubMed Sun D, Liu WY, Tang AM et al (2019) A new PEGDA/CNF aerogel-wet hydrogel scaffold fabricated by a two-step method. Soft Matter 15(40):8092–8810PubMed
6.
go back to reference Li Z, Gunn J, Chen MH, Cooper A, Zhang M (2008) On-site alginate gelation for enhanced cell proliferation and uniform distribution in porous scaffolds. J Biomed Mater Res A 86(2):552–559PubMed Li Z, Gunn J, Chen MH, Cooper A, Zhang M (2008) On-site alginate gelation for enhanced cell proliferation and uniform distribution in porous scaffolds. J Biomed Mater Res A 86(2):552–559PubMed
7.
go back to reference Singh D, Huh PH, Kim SC (2016) Hyperbranched poly(glycidol)/poly(ethylene oxide) crosslinked hydrogel for tissue engineering scaffold using e-beams. J Biomed Mater Res A 104(1):48–56PubMed Singh D, Huh PH, Kim SC (2016) Hyperbranched poly(glycidol)/poly(ethylene oxide) crosslinked hydrogel for tissue engineering scaffold using e-beams. J Biomed Mater Res A 104(1):48–56PubMed
9.
go back to reference Farahani BV, Ghasemzadeh H, Afraz S (2016) Thermodynamic studies of insulin loading into a glucose responsive hydrogel based on chitosan-polyacrylamide-polyethylene glycol. J Chin Chem Soc 63(5):438–444 Farahani BV, Ghasemzadeh H, Afraz S (2016) Thermodynamic studies of insulin loading into a glucose responsive hydrogel based on chitosan-polyacrylamide-polyethylene glycol. J Chin Chem Soc 63(5):438–444
10.
go back to reference Kapadia CH, Tian S, Perry JL, Luft JC, DeSimone JM (2016) Reduction sensitive PEG hydrogels for Codelivery of antigen and adjuvant to induce potent CTLs. Mol Pharm 13(10):3381–3394PubMedPubMedCentral Kapadia CH, Tian S, Perry JL, Luft JC, DeSimone JM (2016) Reduction sensitive PEG hydrogels for Codelivery of antigen and adjuvant to induce potent CTLs. Mol Pharm 13(10):3381–3394PubMedPubMedCentral
11.
go back to reference Lim S, Jung GA, Muckom RJ, Glover DJ, Clark DS (2019) Engineering bioorthogonal protein–polymer hybrid hydrogel as a functional protein immobilization platform. Chem Commun 55(6):806–809 Lim S, Jung GA, Muckom RJ, Glover DJ, Clark DS (2019) Engineering bioorthogonal protein–polymer hybrid hydrogel as a functional protein immobilization platform. Chem Commun 55(6):806–809
12.
go back to reference Pontremoli C, Boffito M, Fiorilli S, Laurano R, Torchio A, Bari A, Tonda-Turo C, Ciardelli G, Vitale-Brovarone C (2018) Hybrid injectable platforms for the in situ delivery of therapeutic ions from mesoporous glasses. Chem Eng J 340:103–113 Pontremoli C, Boffito M, Fiorilli S, Laurano R, Torchio A, Bari A, Tonda-Turo C, Ciardelli G, Vitale-Brovarone C (2018) Hybrid injectable platforms for the in situ delivery of therapeutic ions from mesoporous glasses. Chem Eng J 340:103–113
13.
go back to reference Wei YB, Zeng Q, Wang M, Huang JZ et al (2019) Near-infrared light-responsive electrochemical protein imprinting biosensor based on a shape memory conducting hydrogel. Biosens Bioelectron 131:156–162PubMed Wei YB, Zeng Q, Wang M, Huang JZ et al (2019) Near-infrared light-responsive electrochemical protein imprinting biosensor based on a shape memory conducting hydrogel. Biosens Bioelectron 131:156–162PubMed
14.
go back to reference Singh A, Vaishagya KK, Verma R et al (2019) Temperature/pH-triggered PNIPAM-based smart Nanogel system loaded with Anastrozole delivery for application in Cancer chemotherapy. AAPS PharmSciTech 20:213PubMed Singh A, Vaishagya KK, Verma R et al (2019) Temperature/pH-triggered PNIPAM-based smart Nanogel system loaded with Anastrozole delivery for application in Cancer chemotherapy. AAPS PharmSciTech 20:213PubMed
15.
go back to reference Zhang J, Zhao T, Sun B et al (2018) Effects of biofertilizers and super absorbent polymers on plant growth and soil fertility in the arid mining area of Inner Mongolia, China. J.Mt. (15):1920–1935 Zhang J, Zhao T, Sun B et al (2018) Effects of biofertilizers and super absorbent polymers on plant growth and soil fertility in the arid mining area of Inner Mongolia, China. J.Mt. (15):1920–1935
16.
go back to reference Fang L, Zhao Y, Tan T (2016) Preparation and water absorbent behavior of superabsorbent Polyaspartic acid resin. J Polym Res 13:145–152 Fang L, Zhao Y, Tan T (2016) Preparation and water absorbent behavior of superabsorbent Polyaspartic acid resin. J Polym Res 13:145–152
17.
go back to reference Zhang Y, Wang L, Li X, He P (2011) Salt-resistant superabsorbents from inverse-suspension polymerization of PEG methacrylate, acryamide and partially neutralized acrylic acid. J Polym Res 18:157–161 Zhang Y, Wang L, Li X, He P (2011) Salt-resistant superabsorbents from inverse-suspension polymerization of PEG methacrylate, acryamide and partially neutralized acrylic acid. J Polym Res 18:157–161
18.
go back to reference Liu X, Luan S, Li W (2019) Utilization of waste hemicelluloses lye for superabsorbent hydrogel synthesis. Int J Biol Macromol 132:954–962PubMed Liu X, Luan S, Li W (2019) Utilization of waste hemicelluloses lye for superabsorbent hydrogel synthesis. Int J Biol Macromol 132:954–962PubMed
19.
go back to reference Shi W, Dumont MJ, Ly EB (2014) Synthesis and properties of canola protein-based superabsorbent hydrogels. Eur Polym J 54:172–180 Shi W, Dumont MJ, Ly EB (2014) Synthesis and properties of canola protein-based superabsorbent hydrogels. Eur Polym J 54:172–180
20.
go back to reference Liu ZS, Rempel GL (1997) Preparation of superabsorbent polymers by crosslinking acrylic acid and acrylamide copolymers. J Appl Polym Sci 64(7):1345–1353 Liu ZS, Rempel GL (1997) Preparation of superabsorbent polymers by crosslinking acrylic acid and acrylamide copolymers. J Appl Polym Sci 64(7):1345–1353
21.
go back to reference Chen Y, Zhang Y, Wang F, Meng W, Yang X, Li P, Jiang J, Tan H, Zheng Y (2016) Preparation of porous carboxymethyl chitosan grafted poly (acrylic acid) superabsorbent by solvent precipitation and its application as a hemostatic wound dressing. Mater Sci Eng 63:18–29 Chen Y, Zhang Y, Wang F, Meng W, Yang X, Li P, Jiang J, Tan H, Zheng Y (2016) Preparation of porous carboxymethyl chitosan grafted poly (acrylic acid) superabsorbent by solvent precipitation and its application as a hemostatic wound dressing. Mater Sci Eng 63:18–29
22.
go back to reference Fang S, Wang G, Xing R, Chen X, Liu S, Qin Y, Li K, Wang X, Li R, Li P (2019) Synthesis of superabsorbent polymers based on chitosan derivative graft acrylic acid-co-acrylamide and its property testing. Int J Biol Macromol 132:575–584PubMed Fang S, Wang G, Xing R, Chen X, Liu S, Qin Y, Li K, Wang X, Li R, Li P (2019) Synthesis of superabsorbent polymers based on chitosan derivative graft acrylic acid-co-acrylamide and its property testing. Int J Biol Macromol 132:575–584PubMed
23.
go back to reference Li YL, Ke AR, Lin SB, Ouyang N (2011) Synthesis and properties of superabsorbent hygroscopic materials based on polyacrylamide and poly(2-acrylamido-2-methyl propyl sulfonic acid) co-polymer. Int J Polym Mater 60(14):1164–1177 Li YL, Ke AR, Lin SB, Ouyang N (2011) Synthesis and properties of superabsorbent hygroscopic materials based on polyacrylamide and poly(2-acrylamido-2-methyl propyl sulfonic acid) co-polymer. Int J Polym Mater 60(14):1164–1177
24.
go back to reference Kabir SMF, Sikdar PP, Haque B, Bhuiyan MAR, Ali A, Islam MN (2018) Cellulose-based hydrogel materials: chemistry, properties and their prospective applications. Progress in Biomaterials 7(3):153–174PubMedPubMedCentral Kabir SMF, Sikdar PP, Haque B, Bhuiyan MAR, Ali A, Islam MN (2018) Cellulose-based hydrogel materials: chemistry, properties and their prospective applications. Progress in Biomaterials 7(3):153–174PubMedPubMedCentral
25.
go back to reference Hu ZH, Wen GH, Jin M et al (2014). Mater Protec S1:112–114 Hu ZH, Wen GH, Jin M et al (2014). Mater Protec S1:112–114
26.
go back to reference Lee JW, Kim SY, Kim SS, Lee YM, Lee KH, Kim SJ (1999) Synthesis and characteristics of interpenetrating polymer network hydrogel composed of chitosan and poly(acrylic acid). J Appl Polym Sci 73(1):113–120 Lee JW, Kim SY, Kim SS, Lee YM, Lee KH, Kim SJ (1999) Synthesis and characteristics of interpenetrating polymer network hydrogel composed of chitosan and poly(acrylic acid). J Appl Polym Sci 73(1):113–120
27.
go back to reference Yang Y, Xie Y, Pang L, Li M, Song X, Wen J, Zhao H (2013) Preparation of reduced Graphene oxide/poly(acrylamide) Nanocomposite and its adsorption of Pb(II) and methylene blue. Langmuir 29(34):10727–10736PubMed Yang Y, Xie Y, Pang L, Li M, Song X, Wen J, Zhao H (2013) Preparation of reduced Graphene oxide/poly(acrylamide) Nanocomposite and its adsorption of Pb(II) and methylene blue. Langmuir 29(34):10727–10736PubMed
28.
go back to reference Fanta GF, Burr RC, Russell CR, Rist CE (1966) Graft copolymers of starch. I. Copolymerization of gelatinized wheat starch with acrylonitrile. Fractionation of copolymer and effect of solvent on copolymer composition. J Appl Polym Sci 10(6):929–937 Fanta GF, Burr RC, Russell CR, Rist CE (1966) Graft copolymers of starch. I. Copolymerization of gelatinized wheat starch with acrylonitrile. Fractionation of copolymer and effect of solvent on copolymer composition. J Appl Polym Sci 10(6):929–937
29.
go back to reference Fanta GF, Burr RC, Russell CR et al (1966) Graft copolymers of starch. II. Copolymerization of gelatinized wheat starch with acrylonitrile: influence of reaction conditions on copolymer composition. J Polym Sci Pol Phys 4(10):765–769 Fanta GF, Burr RC, Russell CR et al (1966) Graft copolymers of starch. II. Copolymerization of gelatinized wheat starch with acrylonitrile: influence of reaction conditions on copolymer composition. J Polym Sci Pol Phys 4(10):765–769
30.
go back to reference Fanta GF, Burr RC, Russell CR, Rist CE (1967) Graft copolymers of starch. III. Copolymerization of gelatinized wheat starch with acrylonitrile. Influence of chain modifiers on copolymer composition. J Appl Polym Sci 11(3):457–463 Fanta GF, Burr RC, Russell CR, Rist CE (1967) Graft copolymers of starch. III. Copolymerization of gelatinized wheat starch with acrylonitrile. Influence of chain modifiers on copolymer composition. J Appl Polym Sci 11(3):457–463
31.
go back to reference Zohuriaan-Mehr MJ, Kabiri K (2008) Superabsorbent polymer materials: a review. Iran Polym J 17(6):451 Zohuriaan-Mehr MJ, Kabiri K (2008) Superabsorbent polymer materials: a review. Iran Polym J 17(6):451
32.
go back to reference Lin RX, Wang JW (2000) Recent trends in hydrogels based on Starchgraft-acrylic acid: a review. Chinese Polym Bull 2(1):85–93 Lin RX, Wang JW (2000) Recent trends in hydrogels based on Starchgraft-acrylic acid: a review. Chinese Polym Bull 2(1):85–93
33.
go back to reference Zou X X. Super-absorbent polymer. Chinese Chemical Industry Press, 1991 Zou X X. Super-absorbent polymer. Chinese Chemical Industry Press, 1991
34.
go back to reference Ramazani-Harandi MJ, Zohuriaan-Mehr MJ, Yousefi AA, Ershad-Langroudi A, Kabiri K (2006) Rheological determination of the swollen gel strength of superabsorbent polymer hydrogels. Polym Test 25(4):470–474 Ramazani-Harandi MJ, Zohuriaan-Mehr MJ, Yousefi AA, Ershad-Langroudi A, Kabiri K (2006) Rheological determination of the swollen gel strength of superabsorbent polymer hydrogels. Polym Test 25(4):470–474
35.
go back to reference Kazanskii K S, Dubrovskii S A. Chemistry and physics of “agricultural” hydrogels. Springer Berlin Heidelberg, 1992, 97–133 Kazanskii K S, Dubrovskii S A. Chemistry and physics of “agricultural” hydrogels. Springer Berlin Heidelberg, 1992, 97–133
36.
go back to reference Bouranis DL, Theodoropoulos AG (1995) Designing synthetic polymers as soil conditioners. Commun Soil Sci Plan 26(9–10):1455–1480 Bouranis DL, Theodoropoulos AG (1995) Designing synthetic polymers as soil conditioners. Commun Soil Sci Plan 26(9–10):1455–1480
37.
go back to reference Dutkiewicz JK (2002) Superabsorbent materials from shellfish waste—a review. J Biomed Mater Res 63(3):373–381PubMed Dutkiewicz JK (2002) Superabsorbent materials from shellfish waste—a review. J Biomed Mater Res 63(3):373–381PubMed
38.
go back to reference Ichikawa T, Nakajima T. Polymeric materials encyclopedia, [P] 1996, 3, 8051–8059 Ichikawa T, Nakajima T. Polymeric materials encyclopedia, [P] 1996, 3, 8051–8059
39.
go back to reference Athawale VD, Lele V (2001) Recent trends in hydrogels based on Starchgraft-acrylic acid: a review. Starch-Starke 3:7–13 Athawale VD, Lele V (2001) Recent trends in hydrogels based on Starchgraft-acrylic acid: a review. Starch-Starke 3:7–13
40.
go back to reference Buchholz FL (1994) Recent advances in superabsorbent polyacrylates. Trends Polym Sci 2:277–281 Buchholz FL (1994) Recent advances in superabsorbent polyacrylates. Trends Polym Sci 2:277–281
41.
go back to reference Dayal U, Mehta SK, Choudhary MS et al (1999) Synthesis of acrylic Superabsorbents. Rev Macromol Chem Phys 39(3):507–525 Dayal U, Mehta SK, Choudhary MS et al (1999) Synthesis of acrylic Superabsorbents. Rev Macromol Chem Phys 39(3):507–525
42.
go back to reference Po R (1994) Water-absorbent polymers: a patent survey. J Macromol Sci C: Polym Rev 34(4):607–662 Po R (1994) Water-absorbent polymers: a patent survey. J Macromol Sci C: Polym Rev 34(4):607–662
43.
go back to reference Chin Y R, Al Dayel A. No. 85–1-2, Stanford Research Institute, SRI International, 1985 Chin Y R, Al Dayel A. No. 85–1-2, Stanford Research Institute, SRI International, 1985
44.
go back to reference Buchholz F L, Graham A T. Modern superabsorbent polymer technology. John! Wiley & Sons, Inc, 605 Third Ave, New York, NY 10016, USA, 1998. 279 Buchholz F L, Graham A T. Modern superabsorbent polymer technology. John! Wiley & Sons, Inc, 605 Third Ave, New York, NY 10016, USA, 1998. 279
45.
go back to reference Absorbent polymer technology. Elsevier, 2012 Absorbent polymer technology. Elsevier, 2012
46.
go back to reference Wu J H, Lin J M, Wei Y L. High water absorbent and water retaining material. 2005 Wu J H, Lin J M, Wei Y L. High water absorbent and water retaining material. 2005
47.
go back to reference Chatterjee, Pronoy K, Bhupender S. Elsevier, 2002, 13 Chatterjee, Pronoy K, Bhupender S. Elsevier, 2002, 13
48.
go back to reference Dhodarkar R, Borde P, Nandy T (2009) Super absorbent polymers in environmental remediation. Global Nest J 11(2):223–234 Dhodarkar R, Borde P, Nandy T (2009) Super absorbent polymers in environmental remediation. Global Nest J 11(2):223–234
49.
go back to reference Ma JZ, Li XL, B Y (2015) Advances in cellulose-based superabsorbent hydrogels. RSC Adv 5:59745–59757 Ma JZ, Li XL, B Y (2015) Advances in cellulose-based superabsorbent hydrogels. RSC Adv 5:59745–59757
50.
go back to reference Laftah WA, Hashim S, Ibrahim AN (2011) Polymer Hydrogels: A Review. Polym-Plast Technol 50(14):1475–1486 Laftah WA, Hashim S, Ibrahim AN (2011) Polymer Hydrogels: A Review. Polym-Plast Technol 50(14):1475–1486
51.
go back to reference Jayaramudu T, Li Y, Ko HU et al (2016) Poly(acrylic acid)-poly(vinyl alcohol) hydrogels for reconfigurable lens actuators. Int J Precis Eng and Man 3(4):375–379 Jayaramudu T, Li Y, Ko HU et al (2016) Poly(acrylic acid)-poly(vinyl alcohol) hydrogels for reconfigurable lens actuators. Int J Precis Eng and Man 3(4):375–379
52.
go back to reference Rabat NE, Hashim S, Majid RA, Rabat NE, Hashim S, Majid RA (2014) Effect of oil palm empty fruit bunch-grafted-poly(acrylic acid-co-acrylamide) hydrogel preparations on plant growth performance. Key Eng Mater 594:236–239 Rabat NE, Hashim S, Majid RA, Rabat NE, Hashim S, Majid RA (2014) Effect of oil palm empty fruit bunch-grafted-poly(acrylic acid-co-acrylamide) hydrogel preparations on plant growth performance. Key Eng Mater 594:236–239
53.
go back to reference Zou W, Liu X, Yu L, Qiao D, Chen L, Liu H, Zhang N (2013) Synthesis and characterization of biodegradable starch-polyacrylamide graft copolymers using starches with different microstructures. J Polym Environ 21(2):359–365 Zou W, Liu X, Yu L, Qiao D, Chen L, Liu H, Zhang N (2013) Synthesis and characterization of biodegradable starch-polyacrylamide graft copolymers using starches with different microstructures. J Polym Environ 21(2):359–365
54.
go back to reference Liu H, Yu M, Ma H, Wang Z, Li L, Li J (2014) Pre-irradiation induced emulsion co-graft polymerization of acrylonitrile and acrylic acid onto a polyethylene nonwoven fabric. Radiat Phys Chem 94:129–132 Liu H, Yu M, Ma H, Wang Z, Li L, Li J (2014) Pre-irradiation induced emulsion co-graft polymerization of acrylonitrile and acrylic acid onto a polyethylene nonwoven fabric. Radiat Phys Chem 94:129–132
55.
go back to reference Soto D, Urdaneta J, Fernández-García M (2016) Heavy metal (Cd2+, Ni2+, Pb2+ and Ni2+) adsorption in aqueous solutions by oxidized starches. J Polym Environ 24(4):343–355 Soto D, Urdaneta J, Fernández-García M (2016) Heavy metal (Cd2+, Ni2+, Pb2+ and Ni2+) adsorption in aqueous solutions by oxidized starches. J Polym Environ 24(4):343–355
56.
go back to reference Ding X, Li L, Liu P, Zhang J, Zhou NL, Lu S, Wei SH, Shen J (2009) The preparation and properties of dextrin-graft-acrylic acid/montmorillonite superabsorbent nanocomposite. Polym Compos 30(7):976–981 Ding X, Li L, Liu P, Zhang J, Zhou NL, Lu S, Wei SH, Shen J (2009) The preparation and properties of dextrin-graft-acrylic acid/montmorillonite superabsorbent nanocomposite. Polym Compos 30(7):976–981
57.
go back to reference Parvathy PC, Jyothi A (2014) Rheological and thermal properties of saponified cassava starch-\r g\r -poly(acrylamide) superabsorbent polymers varying in grafting parameters and absorbency. J Appl Polym Sci 131(11):40368–40378 Parvathy PC, Jyothi A (2014) Rheological and thermal properties of saponified cassava starch-\r g\r -poly(acrylamide) superabsorbent polymers varying in grafting parameters and absorbency. J Appl Polym Sci 131(11):40368–40378
58.
go back to reference Kong W, Li Q, Liu J, Li X, Zhao L, Su Y, Yue Q, Gao B (2016) Adsorption behavior and mechanism of heavy metal ions by chicken feather protein-based semi-interpenetrating polymer networks super absorbent resin. RSC Adv 6(86):83234–83243 Kong W, Li Q, Liu J, Li X, Zhao L, Su Y, Yue Q, Gao B (2016) Adsorption behavior and mechanism of heavy metal ions by chicken feather protein-based semi-interpenetrating polymer networks super absorbent resin. RSC Adv 6(86):83234–83243
59.
go back to reference He M, Zhao Y, Duan J et al (1872-1878) Fast contact of solid–liquid Interface created high strength multi-layered cellulose hydrogels with controllable size. ACS Appl Mater Inter 2014:6(3) He M, Zhao Y, Duan J et al (1872-1878) Fast contact of solid–liquid Interface created high strength multi-layered cellulose hydrogels with controllable size. ACS Appl Mater Inter 2014:6(3)
60.
go back to reference Halake KS, Lee J (2014) Superporous thermo-responsive hydrogels by combination of cellulose fibers and aligned micropores. Carbohydr Polym 105:184–192PubMed Halake KS, Lee J (2014) Superporous thermo-responsive hydrogels by combination of cellulose fibers and aligned micropores. Carbohydr Polym 105:184–192PubMed
61.
go back to reference Ge G, Zhang Y, Shao J, Wang W, Si W, Huang W, Dong X (2018) Stretchable, transparent, and self-patterned hydrogel-based pressure sensor for human motions detection. Adv Funct Mater 28(32):1802576 Ge G, Zhang Y, Shao J, Wang W, Si W, Huang W, Dong X (2018) Stretchable, transparent, and self-patterned hydrogel-based pressure sensor for human motions detection. Adv Funct Mater 28(32):1802576
62.
go back to reference Hoffman JD (1964) Theoretical aspects of polymer crystallization with chain folds: bulk polymers. Polym Eng Sci 4(4):315–362 Hoffman JD (1964) Theoretical aspects of polymer crystallization with chain folds: bulk polymers. Polym Eng Sci 4(4):315–362
63.
go back to reference Wang J, Wu W (2005) Swelling behaviors, tensile properties and thermodynamic studies of water sorption of 2-hydroxyethyl methacrylate/epoxy methacrylate copolymeric hydrogels. Eur Polym J 41(5):1143–1151 Wang J, Wu W (2005) Swelling behaviors, tensile properties and thermodynamic studies of water sorption of 2-hydroxyethyl methacrylate/epoxy methacrylate copolymeric hydrogels. Eur Polym J 41(5):1143–1151
64.
go back to reference Floroiu RM, Davis AP, Torrents A (2001) Cadmium adsorption on aluminum oxide in the presence of Polyacrylic acid. Environ Sci Technol 35(2):348–353PubMed Floroiu RM, Davis AP, Torrents A (2001) Cadmium adsorption on aluminum oxide in the presence of Polyacrylic acid. Environ Sci Technol 35(2):348–353PubMed
65.
go back to reference Montavon G, Rabung T, Geckeis H, Grambow B (2004) Interaction of Eu(III)/cm(III) with alumina-bound poly(acrylic acid): sorption, desorption, and spectroscopic studies. Environ Sci Technol 38(16):4312–4318PubMed Montavon G, Rabung T, Geckeis H, Grambow B (2004) Interaction of Eu(III)/cm(III) with alumina-bound poly(acrylic acid): sorption, desorption, and spectroscopic studies. Environ Sci Technol 38(16):4312–4318PubMed
66.
go back to reference Kamoun EA, Menzel H (2010) Crosslinking behavior of dextran modified with hydroxyethyl methacrylate upon irradiation with visible light-effect of concentration, coinitiator type, and solvent. J Appl Polym Sci 117(6):0 Kamoun EA, Menzel H (2010) Crosslinking behavior of dextran modified with hydroxyethyl methacrylate upon irradiation with visible light-effect of concentration, coinitiator type, and solvent. J Appl Polym Sci 117(6):0
67.
go back to reference Yamagami M, Kamitakahara H, Yoshinaga A, Takano T (2018) Thermo-reversible supramolecular hydrogels of trehalose-type diblock methylcellulose analogues. Carbohydr Polym 183:110–122PubMed Yamagami M, Kamitakahara H, Yoshinaga A, Takano T (2018) Thermo-reversible supramolecular hydrogels of trehalose-type diblock methylcellulose analogues. Carbohydr Polym 183:110–122PubMed
68.
go back to reference Shin BM, Kim JH, Chung DJ (2013) Synthesis of pH-responsive and adhesive super-absorbent hydrogel through bulk polymerization. Macromol Res 21(5):582–587 Shin BM, Kim JH, Chung DJ (2013) Synthesis of pH-responsive and adhesive super-absorbent hydrogel through bulk polymerization. Macromol Res 21(5):582–587
69.
go back to reference Sun S, Mao LB, Lei Z, Yu SH, Cölfen H (2016) Hydrogels from amorphous calcium carbonate and Polyacrylic acid: bio-inspired materials for mineral plastics. Angew Chem Int Edit 55(39):11765–11769 Sun S, Mao LB, Lei Z, Yu SH, Cölfen H (2016) Hydrogels from amorphous calcium carbonate and Polyacrylic acid: bio-inspired materials for mineral plastics. Angew Chem Int Edit 55(39):11765–11769
70.
go back to reference Lee WF, Wu RJ (1996) Superabsorbent polymeric materials. I. Swelling behaviors of crosslinked poly(sodium acrylate-co-hydroxyethyl methacrylate) in aqueous salt solution. J Appl Polym Sci 62(7):1099–1114 Lee WF, Wu RJ (1996) Superabsorbent polymeric materials. I. Swelling behaviors of crosslinked poly(sodium acrylate-co-hydroxyethyl methacrylate) in aqueous salt solution. J Appl Polym Sci 62(7):1099–1114
71.
go back to reference Morita S, Kitagawa K, Ozaki Y (2009) Vib. Hydrogen-bond structures in poly(2-hydroxyethyl methacrylate): infrared spectroscopy and quantum chemical calculations with model compounds. Spectrosc 51(1):28–33 Morita S, Kitagawa K, Ozaki Y (2009) Vib. Hydrogen-bond structures in poly(2-hydroxyethyl methacrylate): infrared spectroscopy and quantum chemical calculations with model compounds. Spectrosc 51(1):28–33
72.
go back to reference Katiyar R, Bag DS, Nigam I (2014) Synthesis and evaluation of swelling characteristics of fullerene (C60) containing cross-linked poly (2-hydroxyethyl methacrylate) hydrogels. Advanced Materials Letter 5:214–222 Katiyar R, Bag DS, Nigam I (2014) Synthesis and evaluation of swelling characteristics of fullerene (C60) containing cross-linked poly (2-hydroxyethyl methacrylate) hydrogels. Advanced Materials Letter 5:214–222
73.
go back to reference Wang Q, Zhang J, Wang A (2009) Preparation and characterization of a novel pH-sensitive chitosan-g-poly (acrylic acid)/attapulgite/sodium alginate composite hydrogel bead for controlled release of diclofenac sodium. Carbohydr Polym 78(4):731–737 Wang Q, Zhang J, Wang A (2009) Preparation and characterization of a novel pH-sensitive chitosan-g-poly (acrylic acid)/attapulgite/sodium alginate composite hydrogel bead for controlled release of diclofenac sodium. Carbohydr Polym 78(4):731–737
74.
go back to reference Singh B, Chauhan GS, Kumar S, Chauhan N (2007) Synthesis, characterization and swelling responses of pH sensitive psyllium and polyacrylamide based hydrogels for the use in drug delivery (I). Carbohydr Polym 67(2):190–200 Singh B, Chauhan GS, Kumar S, Chauhan N (2007) Synthesis, characterization and swelling responses of pH sensitive psyllium and polyacrylamide based hydrogels for the use in drug delivery (I). Carbohydr Polym 67(2):190–200
75.
go back to reference Xianglin Y, Jiehui W, Biyu Z et al (2016) Study on adsorption properties of Polyacrylic acid-acrylamide water absorbent resin for dyes. New Chem Mater 1:048 Xianglin Y, Jiehui W, Biyu Z et al (2016) Study on adsorption properties of Polyacrylic acid-acrylamide water absorbent resin for dyes. New Chem Mater 1:048
76.
go back to reference Xu S, Li H, Ding H et al (2019) Preparation of superabsorbent resin with fast water absorption rate based on hydroxymethyl cellulose sodium and its application. Carbohydr Polym 225:115214 Xu S, Li H, Ding H et al (2019) Preparation of superabsorbent resin with fast water absorption rate based on hydroxymethyl cellulose sodium and its application. Carbohydr Polym 225:115214
77.
go back to reference Vieira JN, Posada JJ, Rezende RA, Sabino MA (2014) Starch and chitosan oligosaccharides as interpenetrating phases in poly(N-isopropylacrylamide) injectable gels. Mater Sci Eng C Mater Biol Appl 37(1):20–27PubMed Vieira JN, Posada JJ, Rezende RA, Sabino MA (2014) Starch and chitosan oligosaccharides as interpenetrating phases in poly(N-isopropylacrylamide) injectable gels. Mater Sci Eng C Mater Biol Appl 37(1):20–27PubMed
78.
go back to reference Cheng S, Liu X, Zhen J, Lei Z (2019) Preparation of superabsorbent resin with fast water absorption rate based on hydroxymethyl cellulose sodium and its application. Carbohydr Polym 225:115214PubMed Cheng S, Liu X, Zhen J, Lei Z (2019) Preparation of superabsorbent resin with fast water absorption rate based on hydroxymethyl cellulose sodium and its application. Carbohydr Polym 225:115214PubMed
79.
go back to reference Abdullah M F, Ahmad A, Mat L A. Methylene blue removal by using pectin-based hydrogels extracted from dragon fruit peel waste using gamma and microwave radiation polymerization techniques. Journal of Biomaterials Science, Polymer Edition, 2018:1–28 Abdullah M F, Ahmad A, Mat L A. Methylene blue removal by using pectin-based hydrogels extracted from dragon fruit peel waste using gamma and microwave radiation polymerization techniques. Journal of Biomaterials Science, Polymer Edition, 2018:1–28
80.
go back to reference Mondal D, Ghosh SK, Banthia AK, Singha NK (2014) Preparation of poly(2-Hydroxyethyl methacrylate) microspheres bearing metronidazole, an antiprotozoal drug. Adv Sci Eng Medicine 6(6):637–641 Mondal D, Ghosh SK, Banthia AK, Singha NK (2014) Preparation of poly(2-Hydroxyethyl methacrylate) microspheres bearing metronidazole, an antiprotozoal drug. Adv Sci Eng Medicine 6(6):637–641
82.
go back to reference Carmo Iago, Almeida Camila, Brandao Humberto,De Oliveira L F, Souza Nelson. Experimental planning applied to the synthesis of superabsorbent polymer by acrylic acid graft in pectin extracted from passion fruit peel . Materials Research Express, 2019(6) Carmo Iago, Almeida Camila, Brandao Humberto,De Oliveira L F, Souza Nelson. Experimental planning applied to the synthesis of superabsorbent polymer by acrylic acid graft in pectin extracted from passion fruit peel . Materials Research Express, 2019(6)
83.
go back to reference Zhang M , Lan G , Qiu H, et al. Preparation of ion exchange resin using soluble starch and acrylamide by graft polymerization and hydrolysis. Environmental Science and Pollution Research, 2018 Zhang M , Lan G , Qiu H, et al. Preparation of ion exchange resin using soluble starch and acrylamide by graft polymerization and hydrolysis. Environmental Science and Pollution Research, 2018
84.
go back to reference Mohammadzadeh Pakdel P, Peighambardoust SJ (2018) A review on acrylic based hydrogels and their applications in wastewater treatment. J Environ Manag 217:123–143 Mohammadzadeh Pakdel P, Peighambardoust SJ (2018) A review on acrylic based hydrogels and their applications in wastewater treatment. J Environ Manag 217:123–143
85.
go back to reference Saber-Samandari S, Saber-Samandari S, Gazi M (2013) Cellulose-graft-polyacrylamide/hydroxyapatite composite hydrogel with possible application in removal of cu (II) ions. React Funct Polym 73(11):1523–1530 Saber-Samandari S, Saber-Samandari S, Gazi M (2013) Cellulose-graft-polyacrylamide/hydroxyapatite composite hydrogel with possible application in removal of cu (II) ions. React Funct Polym 73(11):1523–1530
86.
go back to reference Liu DH, Lv ZP, Jiang L (2011). Chem Eng 2:37–48 Liu DH, Lv ZP, Jiang L (2011). Chem Eng 2:37–48
87.
go back to reference El-Mohdy HLA (2013) Radiation synthesis of nanosilver/poly vinyl alcohol/cellulose acetate/gelatin hydrogels for wound dressing. J Polym Res 20(6):1–12 El-Mohdy HLA (2013) Radiation synthesis of nanosilver/poly vinyl alcohol/cellulose acetate/gelatin hydrogels for wound dressing. J Polym Res 20(6):1–12
88.
go back to reference Jaiswal A, Ghosh SS, Chattopadhyay A (2012) One step synthesis of C-dots by microwave mediated caramelization of poly(ethylene glycol). Chem Commun 48(3):407–409 Jaiswal A, Ghosh SS, Chattopadhyay A (2012) One step synthesis of C-dots by microwave mediated caramelization of poly(ethylene glycol). Chem Commun 48(3):407–409
89.
go back to reference Nho YC, Park JS, Lim YM (2014) Preparation of poly(acrylic acid) hydrogel by radiation crosslinking and its application for Mucoadhesives. Polymers-Basel 6(3):890–898 Nho YC, Park JS, Lim YM (2014) Preparation of poly(acrylic acid) hydrogel by radiation crosslinking and its application for Mucoadhesives. Polymers-Basel 6(3):890–898
90.
go back to reference Hemvichian K, Chanthawong A, Suwanmala P (2014) Synthesis and characterization of superabsorbent polymer prepared by radiation-induced graft copolymerization of acrylamide onto carboxymethyl cellulose for controlled release of agrochemicals. Radiat Phys Chem 103:167–171 Hemvichian K, Chanthawong A, Suwanmala P (2014) Synthesis and characterization of superabsorbent polymer prepared by radiation-induced graft copolymerization of acrylamide onto carboxymethyl cellulose for controlled release of agrochemicals. Radiat Phys Chem 103:167–171
91.
go back to reference Zhang S, Wang W, Wang H, Qi W, Yue L, Ye Q (2014) Synthesis and characterisation of starch grafted superabsorbent via 10 MeV electron-beam irradiation. Carbohydr Polym 101:798–803PubMed Zhang S, Wang W, Wang H, Qi W, Yue L, Ye Q (2014) Synthesis and characterisation of starch grafted superabsorbent via 10 MeV electron-beam irradiation. Carbohydr Polym 101:798–803PubMed
92.
go back to reference Abd El-Mohdy H L , Hegazy E A , El-Nesr E M , et al. Synthesis, characterization and properties of radiation-induced starch/(EG-co-MAA) hydrogels. Arab J Chem, 2012:S1878535212000901 Abd El-Mohdy H L , Hegazy E A , El-Nesr E M , et al. Synthesis, characterization and properties of radiation-induced starch/(EG-co-MAA) hydrogels. Arab J Chem, 2012:S1878535212000901
93.
go back to reference Salmawi K M E , El-Naggar A A , Ibrahim S M. Modeling and Optimization of the Injection-Molding Process: A Review. Advances in Polymer Technology, 2016:n/a-n/a Salmawi K M E , El-Naggar A A , Ibrahim S M. Modeling and Optimization of the Injection-Molding Process: A Review. Advances in Polymer Technology, 2016:n/a-n/a
94.
go back to reference Haroon M, Wang L, Yu H, Abbasi NM, Zain-ul-Abdin ZUA, Saleem M, Khan RU, Ullah RS, Chen Q, Wu J (2016) Chemical modification of starch and its application as an adsorbent material. RSC Adv 6(82):78264–78285 Haroon M, Wang L, Yu H, Abbasi NM, Zain-ul-Abdin ZUA, Saleem M, Khan RU, Ullah RS, Chen Q, Wu J (2016) Chemical modification of starch and its application as an adsorbent material. RSC Adv 6(82):78264–78285
95.
go back to reference Bardajee GR, Pourjavadi A, Soleyman R (2009) Irradiation synthesis of biopolymer-based superabsorbent hydrogel: optimization using the Taguchi method and investigation of its swelling behavior. Adv Polym Technol 28(2):131–140 Bardajee GR, Pourjavadi A, Soleyman R (2009) Irradiation synthesis of biopolymer-based superabsorbent hydrogel: optimization using the Taguchi method and investigation of its swelling behavior. Adv Polym Technol 28(2):131–140
96.
go back to reference Hassan CM, Peppas NA (2000). Adv Polym Sci 153:3765 Hassan CM, Peppas NA (2000). Adv Polym Sci 153:3765
97.
go back to reference Guan Y, Bian J, Peng F, Zhang XM, Sun RC (2014) High strength of hemicelluloses based hydrogels by freeze/thaw technique. Carbohydr Polym 101:272–280PubMed Guan Y, Bian J, Peng F, Zhang XM, Sun RC (2014) High strength of hemicelluloses based hydrogels by freeze/thaw technique. Carbohydr Polym 101:272–280PubMed
98.
go back to reference Kuo SW, Lin CL, Wu HD, Chang FC (2003) Thermal property and hydrogen bonding in blends of poly (vinylphenol) and poly (hydroxylether of bisphenol a). J Polym Res 10(2):87–93 Kuo SW, Lin CL, Wu HD, Chang FC (2003) Thermal property and hydrogen bonding in blends of poly (vinylphenol) and poly (hydroxylether of bisphenol a). J Polym Res 10(2):87–93
99.
go back to reference Zhong M, Shi FK, Liu YT, Liu XY, Xie XM (2016) Tough superabsorbent poly(acrylic acid) nanocomposite physical hydrogels fabricated by a dually cross-linked single network strategy. Chinese Chem Lett 27(3):312–316 Zhong M, Shi FK, Liu YT, Liu XY, Xie XM (2016) Tough superabsorbent poly(acrylic acid) nanocomposite physical hydrogels fabricated by a dually cross-linked single network strategy. Chinese Chem Lett 27(3):312–316
100.
go back to reference Omidian H, Park K (2010) Introduction to hydrogels//biomedical applications of hydrogels handbook. Springer New York:1–16 Omidian H, Park K (2010) Introduction to hydrogels//biomedical applications of hydrogels handbook. Springer New York:1–16
101.
go back to reference Vinogradov S N, Linnell R H. Hydrogen bonding. New York: Van Nostrand Reinhold, 1971.p 156 Vinogradov S N, Linnell R H. Hydrogen bonding. New York: Van Nostrand Reinhold, 1971.p 156
102.
go back to reference Wang W, Wang A (2010) Synthesis and swelling properties of pH-sensitive semi-IPN superabsorbent hydrogels based on sodium alginate-g-poly(sodium acrylate) and polyvinylpyrrolidone. Carbohydr Polym 80(4):1028–1036 Wang W, Wang A (2010) Synthesis and swelling properties of pH-sensitive semi-IPN superabsorbent hydrogels based on sodium alginate-g-poly(sodium acrylate) and polyvinylpyrrolidone. Carbohydr Polym 80(4):1028–1036
103.
go back to reference Boyaci T, Orakdogen N. Tuning the Synthetic Routes of Dimethylaminoethyl methacrylate-Based Superabsorbent Copolymer Hydrogels Containing Sulfonate Groups: Elasticity, Dynamic, and Equilibrium Swelling Properties. Adv Polym Tech, 2015:n/a-n/a Boyaci T, Orakdogen N. Tuning the Synthetic Routes of Dimethylaminoethyl methacrylate-Based Superabsorbent Copolymer Hydrogels Containing Sulfonate Groups: Elasticity, Dynamic, and Equilibrium Swelling Properties. Adv Polym Tech, 2015:n/a-n/a
104.
go back to reference Tang H, Chen H, Duan B, Lu A, Zhang L N, Swelling behaviors of superabsorbent chitin/carboxymethylcellulose hydrogels. J Mater Sci, 2014, 49(5): 2235–2242 Tang H, Chen H, Duan B, Lu A, Zhang L N, Swelling behaviors of superabsorbent chitin/carboxymethylcellulose hydrogels. J Mater Sci, 2014, 49(5): 2235–2242
105.
go back to reference Hu J, Wang X, Liu L, Wu L (2014) A facile and general fabrication method for organic silica hollow spheres and their excellent adsorption properties for heavy metal ions. J Mater Chem A 2(46):19771–19777 Hu J, Wang X, Liu L, Wu L (2014) A facile and general fabrication method for organic silica hollow spheres and their excellent adsorption properties for heavy metal ions. J Mater Chem A 2(46):19771–19777
Metadata
Title
Development history and synthesis of super-absorbent polymers: a review
Authors
Xiaofang Ma
Guohua Wen
Publication date
01-06-2020
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 6/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02097-2

Other articles of this Issue 6/2020

Journal of Polymer Research 6/2020 Go to the issue

Premium Partners