Skip to main content
Top
Published in: Emission Control Science and Technology 1/2020

04-02-2020

Effect of Additives to Improve Calcium-Based Sorbents in Semi-Dry Flue Gas Desulphurization

Authors: Ítalo W. L. França, Samuel J. M. Cartaxo, Moises Bastos-Neto, Luciana R. B. Gonçalves, Fabiano A. N. Fernandes

Published in: Emission Control Science and Technology | Issue 1/2020

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Semi-dry flue gas desulfurization (FGD) technology is used by some coal-based power plants to remove sulfur dioxide from flue gas. In semi-dry FGD systems, SO2 is removed by calcium-based sorbents in a reactive spray dryer, but the level of desulfurization is lower than in wet FGD systems. This work evaluates the effects of seven additives in the desulfurization of the flue gas: magnesium hydroxide, ammonium nitrate, ammonium acetate, ammonium phosphate, sodium hydroxide, citric acid, and urea. Slurries with calcium hydroxide concentrations of 10 and 20 wt% containing 2 and 4 wt% of an additive were applied in the removal of SO2. Additives containing ammonium intensified the removal of SO2 and increased the yield of the reaction. The SO2 content in the flue gas reduced by 73.8% when applying a slurry containing 4 wt% of ammonium nitrate and 10 wt% of Ca(OH)2. The use of this slurry increased the removal of SO2 by 13.5% when compared to the best result obtained using calcium hydroxide slurry without any additive.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Valle-Zermeno, R., Formosa, J., Chimenos, J.M.: Wet flue gas desulfurization using alkaline agents. Rev. Chem. Eng. 31, 303–327 (2015) Valle-Zermeno, R., Formosa, J., Chimenos, J.M.: Wet flue gas desulfurization using alkaline agents. Rev. Chem. Eng. 31, 303–327 (2015)
2.
go back to reference Hill, F.F., Zank, J.: Flue gas desulphurization by spray dry absorption. Chem. Eng. Process. 39, 45–52 (2000)CrossRef Hill, F.F., Zank, J.: Flue gas desulphurization by spray dry absorption. Chem. Eng. Process. 39, 45–52 (2000)CrossRef
3.
go back to reference Katolicky, J., Jicha, M.: Influence of the lime slurry droplet spectrum on the efficiency of semi-dry flue gas desulfurization. Chem. Eng. Technol. 36, 156–166 (2013)CrossRef Katolicky, J., Jicha, M.: Influence of the lime slurry droplet spectrum on the efficiency of semi-dry flue gas desulfurization. Chem. Eng. Technol. 36, 156–166 (2013)CrossRef
4.
go back to reference Getler, J.L., Shelton, H.L., Furlong, D.A.: Modeling the spray absorption process for SO2 removal. APCA J. 29, 1270–1274 (1979) Getler, J.L., Shelton, H.L., Furlong, D.A.: Modeling the spray absorption process for SO2 removal. APCA J. 29, 1270–1274 (1979)
5.
go back to reference Newton, G.H., Kramlich, J., Payne, R.: Modeling the SO2 slurry droplet reaction. AICHE J. 36, 1865–1872 (1990)CrossRef Newton, G.H., Kramlich, J., Payne, R.: Modeling the SO2 slurry droplet reaction. AICHE J. 36, 1865–1872 (1990)CrossRef
6.
go back to reference Kinzey, J.R., Kinzey, M.K.: Modeling the gas and liquid-phase resistances in the dry scrubbing process for sulfur-dioxide removal, (1988) Kinzey, J.R., Kinzey, M.K.: Modeling the gas and liquid-phase resistances in the dry scrubbing process for sulfur-dioxide removal, (1988)
7.
go back to reference Koech, L., Everson, R., Neomagus, H., Rutto, H.: Dissolution kinetics of sorbents and effect of additives in wet flue gas desulfurization. Rev. Chem. Eng. 30, 553–565 (2014)CrossRef Koech, L., Everson, R., Neomagus, H., Rutto, H.: Dissolution kinetics of sorbents and effect of additives in wet flue gas desulfurization. Rev. Chem. Eng. 30, 553–565 (2014)CrossRef
8.
go back to reference Frandsen, J.B., Kiil, S., Johnsson, J.E.: Optimisation of a wet FGD pilot plant using fine limestone and organic acids. Chem. Eng. Sci. 56, 3275–3287 (2001)CrossRef Frandsen, J.B., Kiil, S., Johnsson, J.E.: Optimisation of a wet FGD pilot plant using fine limestone and organic acids. Chem. Eng. Sci. 56, 3275–3287 (2001)CrossRef
9.
go back to reference Arpagaus, C., Collenberg, A., Rutti, D., Assadpour, E., Jafari, S.M.: Nano spray drying for encapsulation of pharmaceuticals. Int. J. Pharm. 546(1-2), 194–214 (2018)CrossRef Arpagaus, C., Collenberg, A., Rutti, D., Assadpour, E., Jafari, S.M.: Nano spray drying for encapsulation of pharmaceuticals. Int. J. Pharm. 546(1-2), 194–214 (2018)CrossRef
10.
go back to reference Arpagaus, C., John, P., Collenberg, A., Rutti, D.: Nanocapsules formation by nano spray drying. In: Jafari, S.M. (ed.) Nanoencapsulation Technologies for the Food and Nutraceutical Industries, pp. 346–401. Elsevier, New York, USA (2017)CrossRef Arpagaus, C., John, P., Collenberg, A., Rutti, D.: Nanocapsules formation by nano spray drying. In: Jafari, S.M. (ed.) Nanoencapsulation Technologies for the Food and Nutraceutical Industries, pp. 346–401. Elsevier, New York, USA (2017)CrossRef
11.
go back to reference Song, H., Park, J.: Improvement of SO2 removal by the solubility change of Ca(OH)2 in the spray dryer system. Environ. Technol. 22(9), 1001–1006 (2001)CrossRef Song, H., Park, J.: Improvement of SO2 removal by the solubility change of Ca(OH)2 in the spray dryer system. Environ. Technol. 22(9), 1001–1006 (2001)CrossRef
12.
go back to reference Haghnegahdar, M.R., Rahimi, A., Hatamipour, M.S.: A rate equation for Ca(OH)2 and CO2 reaction in a spouted bed reactor at low gas concentrations. Chem. Eng. Res. Des. 89, 616–620 (2011)CrossRef Haghnegahdar, M.R., Rahimi, A., Hatamipour, M.S.: A rate equation for Ca(OH)2 and CO2 reaction in a spouted bed reactor at low gas concentrations. Chem. Eng. Res. Des. 89, 616–620 (2011)CrossRef
13.
go back to reference Chen, B., Laucks, M.L., Davis, E.J.: Carbon dioxide uptake by hydrated lime aerosol particles. Aerosol Sci. Technol. 45, 8765–8769 (2004) Chen, B., Laucks, M.L., Davis, E.J.: Carbon dioxide uptake by hydrated lime aerosol particles. Aerosol Sci. Technol. 45, 8765–8769 (2004)
14.
go back to reference Jarvis, J., Meserole, F., Owens, D., Roothaan, E.: Factors involved in the selection of limestone reagents for use in wet FGD systems. In: EPRI/EPA/DOE SO3 Control Symposium. 8 (1991) Jarvis, J., Meserole, F., Owens, D., Roothaan, E.: Factors involved in the selection of limestone reagents for use in wet FGD systems. In: EPRI/EPA/DOE SO3 Control Symposium. 8 (1991)
15.
go back to reference Letterman, R.D.: Calcium carbonate dissolution rate in limestone contactors. US Environmental Protection Agency, Washington, USA (1995) Letterman, R.D.: Calcium carbonate dissolution rate in limestone contactors. US Environmental Protection Agency, Washington, USA (1995)
16.
go back to reference Rochelle, G.T., King, C.J.: The effect of additives on mass transfer in CaCO3 or CaO slurry scrubbing of SO2 from waste gases. Ind. Eng. Chem. Fundam. 16, 67–75 (1977)CrossRef Rochelle, G.T., King, C.J.: The effect of additives on mass transfer in CaCO3 or CaO slurry scrubbing of SO2 from waste gases. Ind. Eng. Chem. Fundam. 16, 67–75 (1977)CrossRef
17.
go back to reference Chang, J.C., Mobley, J.D.: Testing and commercialization of byproduct dibasic acids as buffer additives for limestone flue gas desulfurization systems. J. Air Pollut. Control Assoc. 33, 955–962 (1983)CrossRef Chang, J.C., Mobley, J.D.: Testing and commercialization of byproduct dibasic acids as buffer additives for limestone flue gas desulfurization systems. J. Air Pollut. Control Assoc. 33, 955–962 (1983)CrossRef
18.
go back to reference Stergarsek, A., Gerbec, M., Kocjancic, R., Frkal, P.: Modelling and experimental measurements of limestone dissolution under enhanced wet limestone FGD process conditions. Acta Chim. Slov. 46, 323–333 (1999) Stergarsek, A., Gerbec, M., Kocjancic, R., Frkal, P.: Modelling and experimental measurements of limestone dissolution under enhanced wet limestone FGD process conditions. Acta Chim. Slov. 46, 323–333 (1999)
19.
go back to reference Takashina, T., Honjo, S., Ukawa, N., Iwashita, K.: Effect of ammonium concentration on SO2 absorption in a wet limestone gypsum FGD process. J. Chem. Eng. Japan. 35, 197–204 (2002)CrossRef Takashina, T., Honjo, S., Ukawa, N., Iwashita, K.: Effect of ammonium concentration on SO2 absorption in a wet limestone gypsum FGD process. J. Chem. Eng. Japan. 35, 197–204 (2002)CrossRef
20.
go back to reference Zhou, Y., Zhu, X., Peng, J., Liu, Y., Zhang, D., Zhang, M.: The effect of hydrogen peroxide solution on SO2 removal in the semidry flue gas desulfurization process. J. Hazard. Mater. 170, 436–442 (2009)CrossRef Zhou, Y., Zhu, X., Peng, J., Liu, Y., Zhang, D., Zhang, M.: The effect of hydrogen peroxide solution on SO2 removal in the semidry flue gas desulfurization process. J. Hazard. Mater. 170, 436–442 (2009)CrossRef
21.
go back to reference Feng, S., Xiao, L., Ge, Z., Yang, L., Du, X., Wu, H.: Parameters analysis of atomized droplets sprayed evaporation in flue gas flow. Int. J. Heat Mass Transf. 129, 936–952 (2019)CrossRef Feng, S., Xiao, L., Ge, Z., Yang, L., Du, X., Wu, H.: Parameters analysis of atomized droplets sprayed evaporation in flue gas flow. Int. J. Heat Mass Transf. 129, 936–952 (2019)CrossRef
22.
go back to reference Khatib, J.M., Wright, L., Mangat, P.S.: Mechanical and physical properties of concrete containing FDG waste. Mag. Concr. Res. 68, 550–560 (2016)CrossRef Khatib, J.M., Wright, L., Mangat, P.S.: Mechanical and physical properties of concrete containing FDG waste. Mag. Concr. Res. 68, 550–560 (2016)CrossRef
23.
go back to reference Castro, R.P.V., Medeiros, J.L., Araujo, O.Q.F., Cruz, M.A., Ribeiro, G.T., Oliveira, V.R.: Fluidized bed treatment of residues of semi-dry flue gas desulfurization units of coal-fired power plants for conversion of sulfites to sulfates. Energy Convers. Manag. 143, 173–187 (2017)CrossRef Castro, R.P.V., Medeiros, J.L., Araujo, O.Q.F., Cruz, M.A., Ribeiro, G.T., Oliveira, V.R.: Fluidized bed treatment of residues of semi-dry flue gas desulfurization units of coal-fired power plants for conversion of sulfites to sulfates. Energy Convers. Manag. 143, 173–187 (2017)CrossRef
Metadata
Title
Effect of Additives to Improve Calcium-Based Sorbents in Semi-Dry Flue Gas Desulphurization
Authors
Ítalo W. L. França
Samuel J. M. Cartaxo
Moises Bastos-Neto
Luciana R. B. Gonçalves
Fabiano A. N. Fernandes
Publication date
04-02-2020
Publisher
Springer International Publishing
Published in
Emission Control Science and Technology / Issue 1/2020
Print ISSN: 2199-3629
Electronic ISSN: 2199-3637
DOI
https://doi.org/10.1007/s40825-020-00156-0

Other articles of this Issue 1/2020

Emission Control Science and Technology 1/2020 Go to the issue

Premium Partner