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Adsorption
Published in: Adsorption 8/2016

31-10-2016

Effect of amine double-functionalization on CO2 adsorption behaviors of silica gel-supported adsorbents

Authors: Hyunchul Jung, Chang Hun Lee, Sunbin Jeon, Dong Hyun Jo, June Huh, Sung Hyun Kim

Published in: Adsorption | Issue 8/2016

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Abstract

Amine double-functionalized adsorbents were fabricated using silica gel as supports and their capabilities for CO2 capture were examined. Aminopropyltrimethoxysilane (1N-APS), and N1-(3-trimethoxysilylpropyl)diethylenetriamine (3N-APS) were used as grafted amine compounds, and tetraethylenepentamine and polyethyleneimine were used as impregnated species. The influence of double-functionalization method on the CO2 adsorption performance and textural properties of adsorbents was investigated. The adsorption capacity, the amine efficiency, and the thermal stability of double-functionalized sorbents depend strongly upon molecular variables associated with two different functional states (i.e., chemically grafted and physically impregnated amines). The temperature dependence of adsorption isotherms reveals that the CO2 adsorption behavior in the double-functionalized adsorbents follow the diffusion limitation model proposed by Xu et al. (Energy Fuels 16:1463–1469, 2002) where the CO2 adsorption is helped by the diffusion of impregnated amines. It is also found that the adsorption isotherm in the double-functionalized sorbent system with a proper choice for grafted and impregnated amines is nearly independent of temperature, which may offer a novel means to fabricate practically useful sorbents that can be used in a wide range of temperature without loss of CO2 adsorption capacity.
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Appendix
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Metadata
Title
Effect of amine double-functionalization on CO2 adsorption behaviors of silica gel-supported adsorbents
Authors
Hyunchul Jung
Chang Hun Lee
Sunbin Jeon
Dong Hyun Jo
June Huh
Sung Hyun Kim
Publication date
31-10-2016
Publisher
Springer US
Published in
Adsorption / Issue 8/2016
Print ISSN: 0929-5607
Electronic ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-016-9837-2

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