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Metallurgical and Materials Transactions A
Published in: Metallurgical and Materials Transactions A 4/2020

03-02-2020

Effect of Mo Addition on the Corrosion Behavior of Al-40Cr-xMo Coatings on Type 316L Stainless Steel

Authors: Avinash V. Ingle, V. S. Raja, P. Mishra, J. Rangarajan

Published in: Metallurgical and Materials Transactions A | Issue 4/2020

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Abstract

In the present study, the corrosion behavior of sputter-deposited amorphous Al-40Cr-xMo alloy coatings in 0.5 M H2SO4 + 2 ppm NaF solution at 70 °C (± 2 °C) was investigated for a possible application as bipolar plates (BPPs) for proton exchange membrane fuel cells (PEMFCs). Particular attention was given to understand the effect of Mo concentration on the passive films and, thereby, on the corrosion behavior of the sputter-deposited alloy coatings. X-ray diffraction (XRD), scanning electron microscopy, X-ray photoelectron spectroscopy (XPS), and electrochemical techniques were carried out to characterize the Al-40Cr-xMo coated specimens. XRD plots of the Al-40Cr-xMo coated specimens indicated the deposits to be amorphous in nature. SEM images showed the coatings were dense and uniform without the presence of any coating defects. XPS analysis indicated a depletion of Mo at concentrations above 12 at. pct. Potentiodynamic polarization test results indicated that the addition of Mo at approximately 12 at. pct is effective in enhancing the corrosion resistance by decreasing the passive current density. However, further addition of Mo raises the anodic current density, thereby lowering the protective ability of the passive film.
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Literature
1.
N.P. Brandon, S. Skinner, and B.C.H. Steele: Annu. Rev. Mater. Res., 2003, pp. 183–213.
2.
3.
3.Z.W.L. Yang, H. Yu, L. Jiang, L. Zhu, and X. Jian: 2010, vol. 195, pp. 2810–14.
4.
W.R.W.D.N.F. Asri, T. Husaini, A.B. Sulong, and E.H. Majlan: Int. J. Hydrogen Energy, 2015, vol. 42, pp. 9135–48.
5.
5.H. Wang, J.A. Turner, X. Li, and R. Bhattacharya: 2007, vol. 171, pp. 567–74.
6.
6.L. Wang, J. Sun, J. Sun, Y. Lv, S. Li, S. Ji, and Z. Wen: J. Power Sources, 2012, vol. 199, pp. 195–200.CrossRef
7.
7.Y. Wang and D.O. Northwood: J. Power Sources, 2006, vol. 163, pp. 500–08.CrossRef
8.
8.M.P. Brady, K.L.M.K. Weisbrod, I. Paulauskas, R.A. Buchanan, L.R.W.H. Wang, M. Wilson, and F. Garzon: Scripta Mater., 2004, vol. 50, pp. 1017–22.CrossRef
9.
9.C. Kyu and C. Gil: Int. J. Hydrogen Energy, 2011, vol. 37, pp. 1661–76.
10.
11.
11.Q. Yan, H. Toghiani, and H. Causey: J. Power Sources, 2006, vol. 161, pp. 492–502.CrossRef
12.
12.W. Vielstich, A. Lamm, and H. Gasteiger: Handbook of Fuel Cells Fundamentals, Technology and Applications, John Wiley & Sons, West Sussex, 2003.
13.
13.K. Feng, G.S. Wu, Z.G. Li, X. Cai, and P.K. Chu: Int. J. Hydrogen Energy, 2011, vol. 36, pp. 13032–13042.CrossRef
14.
14.Y. Yang, L. Guo, and H. Liu: Int. J. Hydrogen Energy, 2011, vol. 36, pp. 1654–63.CrossRef
15.
15.Y. Yang, L. Guo, and H. Liu: J. Power Sources, 2010, vol. 195, pp. 5651–59.CrossRef
16.
16.M.P. Brady, B. Yang, H. Wang, J.A. Turner, K.L. More, M. Wilson, and F. Garzon: J. Met., 2006, vol. 1, pp. 50–57.
17.
17.Y. Wang and D.O. Northwood: Int. J. Electrochem. Sci., 2006, vol. 1, pp. 447–55.
18.
18.R.S.J. Wind and G.B.W. Kaiser: J. Power Sources, 2002, vol. 105, pp. 256–60.CrossRef
19.
19.S. Vengatesan, H.J. Kim, E.A. Cho, S.U. Jeong, H.Y. Ha, and I.H. Oh: J. Power Sources, 2006, vol. 156, pp. 294–99.CrossRef
20.
20.S. Wang, J. Peng, W. Lui, and J. Zhang: J. Power Sources, 2006, vol. 162, pp. 486–91.CrossRef
21.
21.J. Pettersson, B. Ramsey, and D. Harrison: J. Power Sources, 2006, vol. 157, pp. 28–34.CrossRef
22.
A.S. Gago, S.A. Ansar, B. Saruhan, U. Schulz, P. Lettenmeier, N.A. Canas, P. Gazdzicki, T. Morawietz, R. Hiesgen, J. Arnold, and K.A. Friedrich: DOI:10.1016/j.jpowsour.2015.12.071CrossRef
23.
23.K.H.E. Akiyama, A. Kawashima, and K. Asami: Corros. Sci., 1996, vol. 38, pp. 1281–94.CrossRef
24.
24.E.A.K. Hashimoto, K. Asami, A. Kawashima, and H. Habazaki: Corros. Sci., 2007, vol. 49, pp. 42–52.CrossRef
25.
25.K.H.E. Akiyama, A. Kawashima, and K. Asami: Corros. Sci., 1996, vol. 38, pp. 279–92.CrossRef
26.
26.K.H.E. Akiyama, H. Habazaki, A. Kawashima, and K. Asami: Mater. Sci. Eng. A, 1997, vols. 226–228, pp. 920–24.CrossRef
27.
27.E. Akiyama, A. Kawashima, K. Asami, and K. Hashimoto: Corros. Sci., 1996, vol. 38, pp. 1127–40.CrossRef
28.
28.D.A. Jones: Principles and Prevention of Corrosion, Princeton Hall, Upper Saddle River, NJ, 1996.
29.
H.P. Klug and L.E. Alexander: X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials, 2nd ed., Patterson, 1974.
30.
30.G. Wang, L. Feng, W. Shen, and Z. Liu: Res. Phys., 2019, vol. 14, pp. 102512–102517.
31.
31.H. Wang and J.A. Turner: J. Power Sources, 2007, vol. 170, pp. 387–94.CrossRef
32.
32.J.T.H. Wan and G. Teeter: J. Electrochem. Soc., 2005, vol. 152, pp. B99–B104.CrossRef
33.
34.
35.
35.J. Pan, D. Thierry, and C. Leygraf: Electrochim. Acta, 1996, vol. 41, pp. 1143–53.CrossRef
36.
36.A.M.C. Liu, Q. Bi, and A. Leyland: Corros. Sci., 2003, vol. 45, pp. 1257–73.CrossRef
37.
38.
D.D.M.J.R. Park: Corros. Sci., 1983, pp. 295–315.
39.
39.H.P. Hack and J.R. Scully: J. Electrochem. Soc., 1991, vol. 138, pp. 33–39.CrossRef
40.
40.Z.B. Wang, H.X. Hu, and Y.G. Zheng: Corros. Sci., 2018, vol. 130, pp. 203–17.CrossRef
41.
41.Z.B. Wang, H.X. Hu, Y.G. Zheng, W. Ke, and Y.X. Qiao: Corros. Sci., 2016, vol. 103, pp. 50–65.CrossRef
42.
42.Z. Wang, L. Zhang, X. Tang, Z. Zhang, and M. Lu: Appl. Surf. Sci., 2017, vol. 423, pp. 457–64.CrossRef
43.
43.Y. Behnamian, A. Mostafaei, A. Kohandehghan, B. Zahiri, W. Zheng, D. Guzonas, M. Chmielus, W. Chen, and J.L. Luo: J. Supercrit. Fluids, 2017, vol. 127, pp. 191–99.CrossRef
44.
K.Y.K.K.M. Kim, J.H. Kim, and Y.Y. Lee: Int. J. Hydrogen Energy, 2012, vol. 37, pp. 1653–60.
45.
45.K. Feng, Y. Shen, D. Liu, P.K. Chu, and X. Cai: Int. J. Hydrogen Energy, 2010, vol. 35, pp. 690–700.CrossRef
46.
46.R.J. Tian, J.C. Sun, and L. Wang: J. Power Sources, 2007, vol. 163, pp. 719–24.CrossRef
47.
47.P.L. Hentall, J.B. Lakeman, G.O. Mepsted, J.M. Moore, and P.L. Adcock: J. Power Sources, 1999, vol. 80, pp. 235–41.CrossRef
48.
48.H. Wang, M.A. Sweikart, and J.A. Turner: J. Power Sources, 2003, vol. 115, pp. 243–51.CrossRef
49.
49.L. Wang, J. Sun, P. Li, J. Sun, Y. Lv, B. Jing, S. Li, and S. Ji: Int. J. Hydrogen Energy, 2012, vol. 37, pp. 5876–83.CrossRef
50.
50.M. Hashemzadeh, K. Raeissi, F. Ashrafizadeh, and S. Khorsand: Surf. Coat. Technol., 2015, vol. 283, pp. 318–28.CrossRef
51.
51.V. Rajaei, H. Rashtchi, K. Raeissi, and M. Shamanian: Int. J. Hydrogen Energy, 2017, vol. 42, pp. 14264–14278.CrossRef
Metadata
Title
Effect of Mo Addition on the Corrosion Behavior of Al-40Cr-xMo Coatings on Type 316L Stainless Steel
Authors
Avinash V. Ingle
V. S. Raja
P. Mishra
J. Rangarajan
Publication date
03-02-2020
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 4/2020
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-020-05628-0

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