Skip to main content
Top
Published in: Tribology Letters 2/2013

01-02-2013 | Original Paper

Effect of MoS2 and WS2 Nanotubes on Nanofriction and Wear Reduction in Dry and Liquid Environments

Published in: Tribology Letters | Issue 2/2013

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Nano-objects in dry and liquid conditions have shown reductions in friction and wear on the macroscale. Studies in low viscosity liquids with nanoparticles and nanotubes made of lubricating materials such as molybdenum disulfide (MoS2) and tungsten disulfide (WS2) are limited. In this research, MoS2 and WS2 nanotubes with spherical gold (Au) nano-objects as a control are studied on the nanoscale under dry and low viscosity liquid environments for their effect on friction and wear reduction. Atomic forces microscopy (AFM) experiments on the nanoscale are performed in single-nano-object contact with an AFM tip, where nano-objects are laterally manipulated and multiple nano-object contact with a tip attached to a glass sphere sliding over several nano-objects. Wear tests were performed on the nanoscale by means of AFM as well as on the macroscale using a ball-on-flat tribometer to relate friction and wear reduction on both scales. Results indicate that nano-objects such as MoS2 and WS2 nanotubes contribute to friction and wear reduction due to the reduced contact area and the possible rolling and sliding on the nanoscale. On the macroscale, reductions in friction and wear occur due to possible exfoliation of outer layers in addition to other mechanisms just mentioned.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Hu, H.S., Dong, J.X., Chen, G.X.: Study on antiwear and reducing friction additive of nanometer ferric oxide. Tribol. Int. 31, 355–360 (1998)CrossRef Hu, H.S., Dong, J.X., Chen, G.X.: Study on antiwear and reducing friction additive of nanometer ferric oxide. Tribol. Int. 31, 355–360 (1998)CrossRef
2.
go back to reference Cizaire, L., Vacher, B., Mogne, T., Le Martin, J.M., Rapoport, L., Margolin, A., Tenne, R.: Mechanisms of ultra-low friction by hollow inorganic fullerene-like MoS2 nanoparticles. Surf. Coat. Technol. 160, 282–287 (2002)CrossRef Cizaire, L., Vacher, B., Mogne, T., Le Martin, J.M., Rapoport, L., Margolin, A., Tenne, R.: Mechanisms of ultra-low friction by hollow inorganic fullerene-like MoS2 nanoparticles. Surf. Coat. Technol. 160, 282–287 (2002)CrossRef
3.
go back to reference Greenberg, R., Halperin, G., Etsion, I., Tenne, R.: The effect of WS2 nanoparticles on friction reduction in various lubrication regimes. Tribol. Lett. 17, 179–186 (2004)CrossRef Greenberg, R., Halperin, G., Etsion, I., Tenne, R.: The effect of WS2 nanoparticles on friction reduction in various lubrication regimes. Tribol. Lett. 17, 179–186 (2004)CrossRef
4.
go back to reference Joly-Pottuz, L., Dassenoy, F., Belin, M., Vacher, B., Martin, J.M., Fleischer, N.: Ultralow-friction and wear properties of IF-WS2 under boundary lubrication. Tribol. Lett. 18, 477–485 (2005)CrossRef Joly-Pottuz, L., Dassenoy, F., Belin, M., Vacher, B., Martin, J.M., Fleischer, N.: Ultralow-friction and wear properties of IF-WS2 under boundary lubrication. Tribol. Lett. 18, 477–485 (2005)CrossRef
5.
go back to reference Rapoport, L., Nepomnyashchy, O., Lapsker, I., Verdyan, A., Soifer, Y., Popovitz-Biro, R., Tenne, R.: Friction and wear of fullerene-like WS2 under severe contact conditions: friction of ceramic materials. Tribol. Lett. 19, 143–149 (2005)CrossRef Rapoport, L., Nepomnyashchy, O., Lapsker, I., Verdyan, A., Soifer, Y., Popovitz-Biro, R., Tenne, R.: Friction and wear of fullerene-like WS2 under severe contact conditions: friction of ceramic materials. Tribol. Lett. 19, 143–149 (2005)CrossRef
6.
go back to reference Fu, X., Zhou, X., Shi, H., Wu, D., Hu, Z.: Investigation of the tribological properties of surfactant-modified MoS2 microsized spheres in base oil 500 SN. ASME J. Tribol. 129, 913–919 (2007)CrossRef Fu, X., Zhou, X., Shi, H., Wu, D., Hu, Z.: Investigation of the tribological properties of surfactant-modified MoS2 microsized spheres in base oil 500 SN. ASME J. Tribol. 129, 913–919 (2007)CrossRef
7.
go back to reference St. Dennis, J.E., Jin, K., John, V.T., Pesika, N.S.: Carbon microspheres as ball bearings in aqueous-based lubrication. ACS Appl. Mater. Interfaces 3, 2215–2218 (2011)CrossRef St. Dennis, J.E., Jin, K., John, V.T., Pesika, N.S.: Carbon microspheres as ball bearings in aqueous-based lubrication. ACS Appl. Mater. Interfaces 3, 2215–2218 (2011)CrossRef
8.
go back to reference Kalin, M., Kogovšek, J., Remškar, M.: Mechanisms and improvements in the friction and wear behavior using MoS2 nanotubes as potential oil additives. Wear 280–281, 36–45 (2012)CrossRef Kalin, M., Kogovšek, J., Remškar, M.: Mechanisms and improvements in the friction and wear behavior using MoS2 nanotubes as potential oil additives. Wear 280–281, 36–45 (2012)CrossRef
9.
go back to reference Maharaj, D., Bhushan, B.: Effect of spherical Au nanoparticles on nanofriction and wear reduction in dry and liquid environments. Belstein J. Nanotechnol. 3, 759–772 (2012) Maharaj, D., Bhushan, B.: Effect of spherical Au nanoparticles on nanofriction and wear reduction in dry and liquid environments. Belstein J. Nanotechnol. 3, 759–772 (2012)
10.
go back to reference Akbulut, M., Belman, N., Golan, Y., Israelachvili, J.: Frictional properties of confined nanorods. Adv. Mater. 18, 2589–2592 (2006)CrossRef Akbulut, M., Belman, N., Golan, Y., Israelachvili, J.: Frictional properties of confined nanorods. Adv. Mater. 18, 2589–2592 (2006)CrossRef
11.
go back to reference Ritter, C., Heyde, M., Stegemann, B., Schwarz, U.D., Rademann, K.: Controlled translational manipulation of small latex spheres by dynamic force microscopy. Langmuir 18, 7798–7803 (2002)CrossRef Ritter, C., Heyde, M., Stegemann, B., Schwarz, U.D., Rademann, K.: Controlled translational manipulation of small latex spheres by dynamic force microscopy. Langmuir 18, 7798–7803 (2002)CrossRef
12.
go back to reference Ritter, C., Heyde, M., Stegemann, B., Rademann, K., Schwarz, U.D.: Contact-area dependence of frictional forces: moving adsorbed antimony nanoparticles. Phys. Rev. B 71, 085405 (2005)CrossRef Ritter, C., Heyde, M., Stegemann, B., Rademann, K., Schwarz, U.D.: Contact-area dependence of frictional forces: moving adsorbed antimony nanoparticles. Phys. Rev. B 71, 085405 (2005)CrossRef
13.
go back to reference Dietzel, D., Monninghoff, G.S., Jansen, L., Fuchs, H., Ritter, C., Scharwz, U.D., Schirmeisen, A.: Interfacial friction obtained by lateral manipulation of nanoparticles using atomic force microscopy techniques. J. Appl. Phys. 102, 084306 (2007)CrossRef Dietzel, D., Monninghoff, G.S., Jansen, L., Fuchs, H., Ritter, C., Scharwz, U.D., Schirmeisen, A.: Interfacial friction obtained by lateral manipulation of nanoparticles using atomic force microscopy techniques. J. Appl. Phys. 102, 084306 (2007)CrossRef
14.
go back to reference Mougin, K., Gnecco, E., Rao, A., Cuberes, M.T., Jayaraman, S., McFarland, E.W., Haidara, H., Meyer, E.: Manipulation of gold nanoparticles: influence of surface chemistry, temperature, and environment (vacuum versus ambient atmosphere). Langmuir 24, 1577–1581 (2008)CrossRef Mougin, K., Gnecco, E., Rao, A., Cuberes, M.T., Jayaraman, S., McFarland, E.W., Haidara, H., Meyer, E.: Manipulation of gold nanoparticles: influence of surface chemistry, temperature, and environment (vacuum versus ambient atmosphere). Langmuir 24, 1577–1581 (2008)CrossRef
15.
go back to reference Palacio, M., Bhushan, B.: A nanoscale friction investigation during manipulation of nanoparticles in controlled environments. Nanotechnology 19, 315710 (2008)CrossRef Palacio, M., Bhushan, B.: A nanoscale friction investigation during manipulation of nanoparticles in controlled environments. Nanotechnology 19, 315710 (2008)CrossRef
16.
go back to reference Lahouij, I., Dassenoy, F., de Knoop, L., Martin, J.-M., Vacher, B.: In situ TEM observation of the behavior of an individual fullerene-like MoS2 nanoparticle in a dynamic contact. Tribol. Lett. 42, 133–140 (2011)CrossRef Lahouij, I., Dassenoy, F., de Knoop, L., Martin, J.-M., Vacher, B.: In situ TEM observation of the behavior of an individual fullerene-like MoS2 nanoparticle in a dynamic contact. Tribol. Lett. 42, 133–140 (2011)CrossRef
17.
go back to reference Tevet, O., Von-Huth, P., Popovitz-Biro, R., Rosentsveig, R., Wagner, H.D., Tenne, R.: Friction mechanism of individual multilayered nanoparticles. Proc. Natl. Acad. Sci. USA 108, 19901–19906 (2011)CrossRef Tevet, O., Von-Huth, P., Popovitz-Biro, R., Rosentsveig, R., Wagner, H.D., Tenne, R.: Friction mechanism of individual multilayered nanoparticles. Proc. Natl. Acad. Sci. USA 108, 19901–19906 (2011)CrossRef
18.
go back to reference Hui, X., Regnier, S.: High-efficiency automated nanomanipulation with parallel imaging/manipulation force microscopy. IEEE Trans. Nanotechnol. 11, 21–33 (2012)CrossRef Hui, X., Regnier, S.: High-efficiency automated nanomanipulation with parallel imaging/manipulation force microscopy. IEEE Trans. Nanotechnol. 11, 21–33 (2012)CrossRef
19.
go back to reference Duncan, R.: The dawning era of polymer therapeutics. Nat. Rev. Drug Discov. 2, 347–360 (2003)CrossRef Duncan, R.: The dawning era of polymer therapeutics. Nat. Rev. Drug Discov. 2, 347–360 (2003)CrossRef
20.
go back to reference Ferrari, M.: Cancer nanotechnology: opportunities and challenges. Nat. Rev. Cancer 5, 161–171 (2005)CrossRef Ferrari, M.: Cancer nanotechnology: opportunities and challenges. Nat. Rev. Cancer 5, 161–171 (2005)CrossRef
21.
go back to reference Panyala, N.R., Pena-Mendez, E.M., Havel, J.: Gold and nano-gold in medicine: overview, toxicology and perspectives. J. Appl. Biomed. 7, 75–91 (2009) Panyala, N.R., Pena-Mendez, E.M., Havel, J.: Gold and nano-gold in medicine: overview, toxicology and perspectives. J. Appl. Biomed. 7, 75–91 (2009)
22.
go back to reference Berlin, J.M., Yu, J., Lu, W., Walsh, E.E., Zhang, L., Zhang, P., Chen, W., Kan, A.T., Wong, M.S., Tomson, M.B., Tour, J.M.: Engineered nanoparticles for hydrocarbon detection in oil-field rocks. Energy Environ. Sci. 4, 505–509 (2011)CrossRef Berlin, J.M., Yu, J., Lu, W., Walsh, E.E., Zhang, L., Zhang, P., Chen, W., Kan, A.T., Wong, M.S., Tomson, M.B., Tour, J.M.: Engineered nanoparticles for hydrocarbon detection in oil-field rocks. Energy Environ. Sci. 4, 505–509 (2011)CrossRef
23.
go back to reference Matteo, C., Candido, P., Vera, R., Francesca, V.: Current and future nanotech applications in the oil industry. Am. J. Appl. Sci. 9, 784–793 (2012) Matteo, C., Candido, P., Vera, R., Francesca, V.: Current and future nanotech applications in the oil industry. Am. J. Appl. Sci. 9, 784–793 (2012)
24.
go back to reference Ryoo, S., Rahmani, A.R., Yoon, K.Y., Prodanovic, M., Kotsmar, C., Milner, T.E., Huh, C.: Theoretical and experimental investigation of the motion of multiphase fluids containing paramagnetic nanoparticles in porous media. J. Petrol. Sci. Eng. 81, 129–144 (2012)CrossRef Ryoo, S., Rahmani, A.R., Yoon, K.Y., Prodanovic, M., Kotsmar, C., Milner, T.E., Huh, C.: Theoretical and experimental investigation of the motion of multiphase fluids containing paramagnetic nanoparticles in porous media. J. Petrol. Sci. Eng. 81, 129–144 (2012)CrossRef
25.
go back to reference Thanikaivelan, P., Narayanan, N. T., Pradhan, B. K., Ajayan, P. M.: Collagen based magnetic nanocomposites for oil removal applications. Sci. Rep. 2, (2012). doi:10.1038/srep00230 Thanikaivelan, P., Narayanan, N. T., Pradhan, B. K., Ajayan, P. M.: Collagen based magnetic nanocomposites for oil removal applications. Sci. Rep. 2, (2012). doi:10.​1038/​srep00230
26.
go back to reference Bhushan, B. (ed.): Springer Handbook of Nanotechnology, 3rd edn. Springer, Heidelberg (2010) Bhushan, B. (ed.): Springer Handbook of Nanotechnology, 3rd edn. Springer, Heidelberg (2010)
27.
go back to reference Bhushan, B. (ed.): Nanotribology and Nanomechanics, I and II, 3rd edn. Springer, Heidelberg (2011) Bhushan, B. (ed.): Nanotribology and Nanomechanics, I and II, 3rd edn. Springer, Heidelberg (2011)
28.
go back to reference Bhushan, B., Gupta, B.K.: Handbook of Tribology: Materials, Coatings, and Surface Treatments. McGraw-Hill, New York (1991) Bhushan, B., Gupta, B.K.: Handbook of Tribology: Materials, Coatings, and Surface Treatments. McGraw-Hill, New York (1991)
29.
go back to reference Bhushan, B.: Introduction to Tribology. Wiley, CRC Press, New York (2002) Bhushan, B.: Introduction to Tribology. Wiley, CRC Press, New York (2002)
30.
go back to reference Rapoport, L., Lvovsky, M., Lapsker, I., Leshinsky, V., Volovik, Y., Feldman, Y., Zak, A., Tenne, R.: Slow release of fullerene-like WS2 nanoparticles as a superior solid lubrication mechanism in composite matrices. Adv. Eng. Mater. 3, 71–75 (2001)CrossRef Rapoport, L., Lvovsky, M., Lapsker, I., Leshinsky, V., Volovik, Y., Feldman, Y., Zak, A., Tenne, R.: Slow release of fullerene-like WS2 nanoparticles as a superior solid lubrication mechanism in composite matrices. Adv. Eng. Mater. 3, 71–75 (2001)CrossRef
31.
go back to reference Bhushan, B.: Modern Tribology Handbook, Vol. 1—Principles of Tribology; Vol. 2—Materials, Coatings, and Industrial Applications. CRC Press Inc., Boca Raton (2001) Bhushan, B.: Modern Tribology Handbook, Vol. 1—Principles of Tribology; Vol. 2—Materials, Coatings, and Industrial Applications. CRC Press Inc., Boca Raton (2001)
32.
go back to reference Nalam, P., Clasohm, J., Mashaghi, A., Spencer, N.: Macrotribological studies of poly(l-lysine)-graft-poly (ethylene glycol) in aqueous glycerol mixtures. Tribol. Lett. 37, 541–552 (2010)CrossRef Nalam, P., Clasohm, J., Mashaghi, A., Spencer, N.: Macrotribological studies of poly(l-lysine)-graft-poly (ethylene glycol) in aqueous glycerol mixtures. Tribol. Lett. 37, 541–552 (2010)CrossRef
33.
go back to reference Resch, R., Lewis, D., Meltzer, S., Montoya, N., Koel, B.E., Madhukar, A., Requicha, A.A., Will, P.: Manipulation of gold nanoparticles in liquid environments using scanning force microscopy. Ultramicroscopy 82, 135–139 (2000)CrossRef Resch, R., Lewis, D., Meltzer, S., Montoya, N., Koel, B.E., Madhukar, A., Requicha, A.A., Will, P.: Manipulation of gold nanoparticles in liquid environments using scanning force microscopy. Ultramicroscopy 82, 135–139 (2000)CrossRef
34.
go back to reference Burton, Z., Bhushan, B.: Hydrophobicity, adhesion and friction properties of nanopatterned polymers and scale dependence for MEMS/NEMS. Nano Lett. 5, 1607–1613 (2005)CrossRef Burton, Z., Bhushan, B.: Hydrophobicity, adhesion and friction properties of nanopatterned polymers and scale dependence for MEMS/NEMS. Nano Lett. 5, 1607–1613 (2005)CrossRef
36.
go back to reference Rothschild, A., Sloan, J., Tenne, R.: The growth of WS2 nanotubes phases. J. Am. Chem. Soc. 122, 5169–5179 (2000)CrossRef Rothschild, A., Sloan, J., Tenne, R.: The growth of WS2 nanotubes phases. J. Am. Chem. Soc. 122, 5169–5179 (2000)CrossRef
37.
go back to reference Zak, A., Sallacan-Ecker, L., Margolin, A., Feldman, Y., Popovitz-Biro, R., Albu-Yaron, A., Genut, M., Tenne, R.: Scaling up of the WS2 nanotubes synthesis. Fullerenes Nanotubes Carbon Nanostruct. 19, 18–26 (2010)CrossRef Zak, A., Sallacan-Ecker, L., Margolin, A., Feldman, Y., Popovitz-Biro, R., Albu-Yaron, A., Genut, M., Tenne, R.: Scaling up of the WS2 nanotubes synthesis. Fullerenes Nanotubes Carbon Nanostruct. 19, 18–26 (2010)CrossRef
38.
go back to reference Remškar, M., Mrzel, A., Viršek, M., Jesih, A.: Inorganic nanotubes as nanoreactors: the first MoS2 nanopods. Adv. Mater. 19, 4276–4278 (2007)CrossRef Remškar, M., Mrzel, A., Viršek, M., Jesih, A.: Inorganic nanotubes as nanoreactors: the first MoS2 nanopods. Adv. Mater. 19, 4276–4278 (2007)CrossRef
39.
go back to reference Remskar, M., Mrzel, A., Virsek, M., Godec, M., Krause, M., Kolitsch, A., Singh, A., Seabaugh, A.: The MoS2 nanotubes with defect-controlled electric properties. Nanoscale Res. Lett. 6, 26 (2011) Remskar, M., Mrzel, A., Virsek, M., Godec, M., Krause, M., Kolitsch, A., Singh, A., Seabaugh, A.: The MoS2 nanotubes with defect-controlled electric properties. Nanoscale Res. Lett. 6, 26 (2011)
40.
go back to reference Lide, D.R. (ed.): CRC Handbook of Chemistry and Physics, 90th edn. CRC Press, Boca Raton (2009) Lide, D.R. (ed.): CRC Handbook of Chemistry and Physics, 90th edn. CRC Press, Boca Raton (2009)
41.
go back to reference Ruan, J., Bhushan, B.: Atomic-scale friction measurements using friction force microscopy: part I—general principles and new measurement techniques. ASME J. Tribol. 116, 378–388 (1994)CrossRef Ruan, J., Bhushan, B.: Atomic-scale friction measurements using friction force microscopy: part I—general principles and new measurement techniques. ASME J. Tribol. 116, 378–388 (1994)CrossRef
42.
go back to reference Falvo, M.R., Taylor Ii, R.M., Helser, A., Chi, V., Brooks Jr, F.P., Washburn, S., Superfine, R.: Nanometre-scale rolling and sliding of carbon nanotubes. Nature 397, 236–238 (1999)CrossRef Falvo, M.R., Taylor Ii, R.M., Helser, A., Chi, V., Brooks Jr, F.P., Washburn, S., Superfine, R.: Nanometre-scale rolling and sliding of carbon nanotubes. Nature 397, 236–238 (1999)CrossRef
43.
go back to reference Cayre, O.J., Paunov, V.N.: Contact angles of colloid silica and gold particles at air–water and oil–water interfaces determined with the gel trapping technique. Langmuir 20, 9594–9599 (2004)CrossRef Cayre, O.J., Paunov, V.N.: Contact angles of colloid silica and gold particles at air–water and oil–water interfaces determined with the gel trapping technique. Langmuir 20, 9594–9599 (2004)CrossRef
44.
go back to reference Fuerstenau, M.C., Han, K.N. (eds.).: Principles of Mineral Processing, Society for Mining, Metallurgy, and Exploration (SME) (2003) Fuerstenau, M.C., Han, K.N. (eds.).: Principles of Mineral Processing, Society for Mining, Metallurgy, and Exploration (SME) (2003)
45.
go back to reference Zhang, S., Zeng, X.T., Tang, Z.G., Tan, M.J.: Exploring the antisticking properties of solid lubricant thin films in transfer molding. Int. J. Mod. Phys. B 16, 1080–1085 (2002)CrossRef Zhang, S., Zeng, X.T., Tang, Z.G., Tan, M.J.: Exploring the antisticking properties of solid lubricant thin films in transfer molding. Int. J. Mod. Phys. B 16, 1080–1085 (2002)CrossRef
46.
go back to reference Bhushan, B., Sundararajan, S.: Micro/nanoscale friction and wear mechanisms of thin films using atomic force and friction force microscopy. Act. Mater. 46, 3793–3804 (1998)CrossRef Bhushan, B., Sundararajan, S.: Micro/nanoscale friction and wear mechanisms of thin films using atomic force and friction force microscopy. Act. Mater. 46, 3793–3804 (1998)CrossRef
47.
go back to reference Pope, L.E., Panitz, J.K.G.: The effects of hertzian stress and test atmosphere on the friction coefficients of MoS2 coatings. Surf. Coat. Technol. 36, 341–350 (1988)CrossRef Pope, L.E., Panitz, J.K.G.: The effects of hertzian stress and test atmosphere on the friction coefficients of MoS2 coatings. Surf. Coat. Technol. 36, 341–350 (1988)CrossRef
48.
go back to reference Prasad, S.V., Zabinski, J.S.: Tribology of tungsten disulfide (WS2)–characterization of wear–induced transfer films. J. Mater. Sci. Lett. 12, 1413–1415 (1993)CrossRef Prasad, S.V., Zabinski, J.S.: Tribology of tungsten disulfide (WS2)–characterization of wear–induced transfer films. J. Mater. Sci. Lett. 12, 1413–1415 (1993)CrossRef
Metadata
Title
Effect of MoS2 and WS2 Nanotubes on Nanofriction and Wear Reduction in Dry and Liquid Environments
Publication date
01-02-2013
Published in
Tribology Letters / Issue 2/2013
Print ISSN: 1023-8883
Electronic ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-012-0071-0

Other articles of this Issue 2/2013

Tribology Letters 2/2013 Go to the issue

Premium Partners