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Published in: Topics in Catalysis 1-8/2013

01-05-2013 | Original Paper

Effect of Soot During Operation of a Pt–K/Al2O3 LNT Catalyst

Authors: R. Matarrese, L. Lietti, L. Castoldi, G. Busca, P. Forzatti

Published in: Topics in Catalysis | Issue 1-8/2013

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Abstract

The effect of soot on the NO x storage-reduction performances of a Pt–K/Al2O3 catalyst is analysed in this work by performing lean-rich cycles at constant temperature. The interaction between soot and the stored NO x has been also investigated by temperature programmed methods. It has been found that the presence of soot reduces the NO x storage capacity of the catalyst; besides the presence of soot favours the decomposition of the stored nitrates. A direct reaction between the stored nitrates and soot is suggested, that has been explained on the basis of the surface mobility of the adsorbed nitrates.

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Literature
1.
go back to reference Johnson TV (2009) Review of diesel emissions and control. Int J Engine Res 10:275–285CrossRef Johnson TV (2009) Review of diesel emissions and control. Int J Engine Res 10:275–285CrossRef
2.
go back to reference Takahashi N, Shinjoh H, Iijima T, Suzuki T, Yamazaki K, Yokota K, Suzuki H, Miyoshi N, Matsumoto S, Tanizawa T, Tanaka T, Tateishi S, Kasahara K (1996) The new concept 3-way catalyst for automotive lean-burn engine: NO x storage and reduction catalyst. Catal Today 27:63–69CrossRef Takahashi N, Shinjoh H, Iijima T, Suzuki T, Yamazaki K, Yokota K, Suzuki H, Miyoshi N, Matsumoto S, Tanizawa T, Tanaka T, Tateishi S, Kasahara K (1996) The new concept 3-way catalyst for automotive lean-burn engine: NO x storage and reduction catalyst. Catal Today 27:63–69CrossRef
3.
go back to reference Suzuki J, Matsumoto S (2004) Development of catalysts for diesel particulate NO x reduction. Top Catal 28:171–176CrossRef Suzuki J, Matsumoto S (2004) Development of catalysts for diesel particulate NO x reduction. Top Catal 28:171–176CrossRef
4.
go back to reference Castoldi L, Matarrese R, Lietti L, Forzatti P (2006) Simultaneous removal of NO x and soot on Pt–Ba/Al2O3 NSR catalysts. Appl Catal B 64:25–34CrossRef Castoldi L, Matarrese R, Lietti L, Forzatti P (2006) Simultaneous removal of NO x and soot on Pt–Ba/Al2O3 NSR catalysts. Appl Catal B 64:25–34CrossRef
5.
go back to reference Matarrese R, Castoldi L, Lietti L, Forzatti P (2007) High performances of Pt–K/Al2O3 versus Pt–Ba/Al2O3 LNT catalysts in the simultaneous removal of NO x and soot. Top Catal 42–43:293–297CrossRef Matarrese R, Castoldi L, Lietti L, Forzatti P (2007) High performances of Pt–K/Al2O3 versus Pt–Ba/Al2O3 LNT catalysts in the simultaneous removal of NO x and soot. Top Catal 42–43:293–297CrossRef
6.
go back to reference Artioli N, Matarrese R, Castoldi R, Lietti L, Forzatti P (2011) Effect of soot on the storage-reduction performances of PtBa/Al2O3 LNT catalyst. Catal Today 169:36–44CrossRef Artioli N, Matarrese R, Castoldi R, Lietti L, Forzatti P (2011) Effect of soot on the storage-reduction performances of PtBa/Al2O3 LNT catalyst. Catal Today 169:36–44CrossRef
7.
go back to reference Matarrese R, Artioli N, Castoldi L, Lietti L, Forzatti P (2012) Interaction between soot and stored NO x during operation of LNT Pt–Ba/Al2O3 catalysts. Catal Today 184:271–278CrossRef Matarrese R, Artioli N, Castoldi L, Lietti L, Forzatti P (2012) Interaction between soot and stored NO x during operation of LNT Pt–Ba/Al2O3 catalysts. Catal Today 184:271–278CrossRef
8.
go back to reference Sullivan JA, Keane O, Cassidy A (2007) Beneficial and problematic interactions between NO x trapping materials and carbonaceous particulate matter. Appl Catal B 75:102–106CrossRef Sullivan JA, Keane O, Cassidy A (2007) Beneficial and problematic interactions between NO x trapping materials and carbonaceous particulate matter. Appl Catal B 75:102–106CrossRef
9.
go back to reference Kustov AL, Makkee M (2009) Application of NO x storage/release materials based on alkali-earth oxides supported on Al2O3 for high-temperature diesel soot oxidation. Appl Catal B 88:263–271CrossRef Kustov AL, Makkee M (2009) Application of NO x storage/release materials based on alkali-earth oxides supported on Al2O3 for high-temperature diesel soot oxidation. Appl Catal B 88:263–271CrossRef
10.
go back to reference Castoldi L, Lietti L, Forzatti P, Morandi S, Ghiotti G, Vindigni F (2010) The NO x storage-reduction on Pt–K–Al2O3 Lean NO x trap catalyst. J Catal 276:335–350CrossRef Castoldi L, Lietti L, Forzatti P, Morandi S, Ghiotti G, Vindigni F (2010) The NO x storage-reduction on Pt–K–Al2O3 Lean NO x trap catalyst. J Catal 276:335–350CrossRef
11.
go back to reference Atribak I, Bueno-López A, García-García A (2010) Uncatalysed and catalysed soot combustion under NO x + O2: real diesel versus model soots. Combust Flame 157:2086–2094CrossRef Atribak I, Bueno-López A, García-García A (2010) Uncatalysed and catalysed soot combustion under NO x  + O2: real diesel versus model soots. Combust Flame 157:2086–2094CrossRef
12.
go back to reference Montanari T, Matarrese R, Artioli N, Busca G (2011) FT-IR study of the surface redox states on platinum–potassium–alumina catalysts. Appl Catal B 105:15–23CrossRef Montanari T, Matarrese R, Artioli N, Busca G (2011) FT-IR study of the surface redox states on platinum–potassium–alumina catalysts. Appl Catal B 105:15–23CrossRef
13.
go back to reference Clayton RD, Harold MP, Balakotaiah V, Wan CZ (2009) Pt dispersion effects during NO x storage and reduction on Pt/BaO/Al2O3 catalysts. Appl Catal B 90:662–676CrossRef Clayton RD, Harold MP, Balakotaiah V, Wan CZ (2009) Pt dispersion effects during NO x storage and reduction on Pt/BaO/Al2O3 catalysts. Appl Catal B 90:662–676CrossRef
14.
go back to reference Bhatia D, Harold MP, Balakotaiah V (2010) Modeling the effect of Pt dispersion and temperature during anaerobic regeneration of a lean NO x trap catalyst. Catal Today 151:314–329CrossRef Bhatia D, Harold MP, Balakotaiah V (2010) Modeling the effect of Pt dispersion and temperature during anaerobic regeneration of a lean NO x trap catalyst. Catal Today 151:314–329CrossRef
15.
go back to reference Lick ID, Carrascull AL, Ponzi MI, Ponzi EN (2008) Zirconia-supported Cu–KNO3 Catalyst: characterization and catalytic behavior in the catalytic combustion of soot with a NO/O2 mixture. Ind Eng Chem Res 47:3834–3839CrossRef Lick ID, Carrascull AL, Ponzi MI, Ponzi EN (2008) Zirconia-supported Cu–KNO3 Catalyst: characterization and catalytic behavior in the catalytic combustion of soot with a NO/O2 mixture. Ind Eng Chem Res 47:3834–3839CrossRef
16.
go back to reference Sánchez BS, Querini CA, Miró EE (2011) Potassium effect on the thermal stability and reactivity of NO x species adsorbed on Pt, Rh/La2O3 catalysts. Appl Catal A Gen 392:158–165CrossRef Sánchez BS, Querini CA, Miró EE (2011) Potassium effect on the thermal stability and reactivity of NO x species adsorbed on Pt, Rh/La2O3 catalysts. Appl Catal A Gen 392:158–165CrossRef
17.
go back to reference MacKee DW (1983) Mechanisms of the alkali metal catalyzed gasification of carbon. Fuel 62:170–175CrossRef MacKee DW (1983) Mechanisms of the alkali metal catalyzed gasification of carbon. Fuel 62:170–175CrossRef
Metadata
Title
Effect of Soot During Operation of a Pt–K/Al2O3 LNT Catalyst
Authors
R. Matarrese
L. Lietti
L. Castoldi
G. Busca
P. Forzatti
Publication date
01-05-2013
Publisher
Springer US
Published in
Topics in Catalysis / Issue 1-8/2013
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-013-0001-x

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