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Published in: Journal of Polymer Research 7/2013

01-07-2013 | Original Paper

Effects of various polyolefin copolymers on the interfacial interaction, microstructure and physical properties of cyclic olefin copolymer(COC)/graphite composites

Authors: Alper Kaşgöz, Dinçer Akın, Ali Durmus, Nevra Ercan, Faruk Öksüzömer, Ahmet Kaşgöz

Published in: Journal of Polymer Research | Issue 7/2013

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Abstract

In this study, effects of various types of functional polyolefin copolymers (FPOCs), poly(isobutylene-alt-maleic anhydride), poly(maleic anhydride-alt-1-octadecene) and poly(ethylene-graft-maleic anhydride), on the microstructure formation, interfacial interaction and physical properties of cyclic olefin copolymer (COC)/graphite composites were investigated. The COC/graphite composites were prepared in a lab. scale twin screw extruder. Microstructural features of samples were studied in a field emission scanning electron microscopy (FESEM). Viscoelastic properties of samples, obtained from the rheology tests in melt state and the dynamic mechanical analysis in solid state were used to quantify interfacial interactions between the COC and graphite depending on the types of FPOC. The average aspect ratio (A f) values of graphite flakes in the COC phase were determined about 40–65 by SEM observation and image analysis study on the samples prepared with different types of FPOC. Based on the gas permeability measurements, tortuous diffusion model suggested that the A f values of graphite flakes varied between 40 and 80 depending on the amount of graphite. It was shown that the poly(isobutylene-alt-maleic anhydride) copolymer provided relatively higher interfacial interaction between the COC and graphite flakes than the other FPOCs.

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Metadata
Title
Effects of various polyolefin copolymers on the interfacial interaction, microstructure and physical properties of cyclic olefin copolymer(COC)/graphite composites
Authors
Alper Kaşgöz
Dinçer Akın
Ali Durmus
Nevra Ercan
Faruk Öksüzömer
Ahmet Kaşgöz
Publication date
01-07-2013
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 7/2013
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-013-0194-5

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