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Published in: Optical and Quantum Electronics 13/2023

01-12-2023

Electrical and optical properties of sol–gel-deposited NiO films and corresponding response to annealing temperature

Authors: M. Rajesh, K Vengatesan, Moustafa H. Aly, R. Sitharthan, Shanmuga Sundar Dhanabalan, Madurakavi Karthikeyan

Published in: Optical and Quantum Electronics | Issue 13/2023

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Abstract

The electrical and optical properties of sol–gel deposited nickel oxide (NiO) films are studied as a function of the annealing temperature. NiOX films are successfully obtained by spin coating process on glass and silicon substrates, and their transparency and conductivity have been improved using sol–gel technology. Further, the vibrational, optical, and electrical properties of NiOX film are investigated concerning annealing temperatures between 150 and 450 °C. From the investigation, annealing at 350 °C results in the formation of NiO, and through X-ray Photoelectron Spectroscopy (XPS), it evidences the existence of Ni3 + which is confirmed along with Ni2+ state. Furthermore, when the NiOX samples are treated at 150 °C, their optical transparency in the visible region reaches 90%, and when the temperature is increased to 450 °C, the optical transparency drops to 75–78%. Through investigation, it is also identified that the optical band gaps get reduced to the region of 3.93–3.67 eV through thermal treatments. From the investigation, it is identified that thin films are excellent p-type electrical conductors having a specific resistivity of around 4.8 × 103 Ω/cm. Hence, they can be used in the manufacturing of transparent solar cells such as Hole Transport Layers (HTLs) and wideband semiconductors.

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Literature
go back to reference Faria, I.C., Kleinke, M., Gorenstein, A., Fantini, M.C.A., Tabacniks, M.H.: Toward efficient Electrochromic NiOx Films: A study of microstructure, morphology, and stoichiometry of radio frequency sputtered Films. J. Electrochem. Soc. 145, 235–240 (1998). https://doi.org/10.1149/1.1838240ADSCrossRef Faria, I.C., Kleinke, M., Gorenstein, A., Fantini, M.C.A., Tabacniks, M.H.: Toward efficient Electrochromic NiOx Films: A study of microstructure, morphology, and stoichiometry of radio frequency sputtered Films. J. Electrochem. Soc. 145, 235–240 (1998). https://​doi.​org/​10.​1149/​1.​1838240ADSCrossRef
go back to reference Kim, S.K., Seok, H.J., Kim, D.H., Choi, D.H., Nam, S.J., Kim, S.C., Kim, H.K.: Comparison of NiOX thin film deposited by spincoating or thermal evaporation for application as a hole transport layer of perovskite solar cells. RSC Adv. 10, 43847–43852 (2020). https://doi.org/10.1039/D0RA08776AADSCrossRef Kim, S.K., Seok, H.J., Kim, D.H., Choi, D.H., Nam, S.J., Kim, S.C., Kim, H.K.: Comparison of NiOX thin film deposited by spincoating or thermal evaporation for application as a hole transport layer of perovskite solar cells. RSC Adv. 10, 43847–43852 (2020). https://​doi.​org/​10.​1039/​D0RA08776AADSCrossRef
go back to reference Klochko, N. P., Kopach, V. R., Tyukhov, I. I., Zhadan, D. O., Klepikova, K. S., Khrypunov, G. S., Petrushenko, S. I., Lyubov, V. M., Kirichenko, M. V., Dukarov, S. V., et al. (2018). Metal oxide heterojunction (NiO/ZnO) prepared by low temperature solution growth for UV-photodetector and semi-transparent solar cell. Sol. Energy,164, 149–159. https://doi.org/10.1016/j.solener.2018.01.054ADSCrossRef Klochko, N. P., Kopach, V. R., Tyukhov, I. I., Zhadan, D. O., Klepikova, K. S., Khrypunov, G. S., Petrushenko, S. I., Lyubov, V. M., Kirichenko, M. V., Dukarov, S. V., et al. (2018). Metal oxide heterojunction (NiO/ZnO) prepared by low temperature solution growth for UV-photodetector and semi-transparent solar cell. Sol. Energy,164, 149–159. https://​doi.​org/​10.​1016/​j.​solener.​2018.​01.​054ADSCrossRef
go back to reference Mihelcic, M., Vuk, A., Jerman, I., Orel, B., Švegl, F., Moulki, H., Faure, C., Campet, G., Rougier, A.: Comparison of electrochromic properties of NixO in lithium and lithium-free aprotic electrolytes: From Ni1-xO pigment coatings to flexible electrochromic devices. Sol. Energy Mater. Sol. Cells 120, 116–130 (2014). https://doi.org/10.1016/j.solmat.2013.08.025CrossRef Mihelcic, M., Vuk, A., Jerman, I., Orel, B., Švegl, F., Moulki, H., Faure, C., Campet, G., Rougier, A.: Comparison of electrochromic properties of NixO in lithium and lithium-free aprotic electrolytes: From Ni1-xO pigment coatings to flexible electrochromic devices. Sol. Energy Mater. Sol. Cells 120, 116–130 (2014). https://​doi.​org/​10.​1016/​j.​solmat.​2013.​08.​025CrossRef
go back to reference Sundar, D.S., Sridarshini, T., Sitharthan, R., Karthikeyan, M., Raja, A.S., Carrasco, M.F.: Performance investigation of 16/32-channel DWDM PON and long-reach PON systems using an ASE noise source. In: Jose, G., Ferreira, M. (eds.) Advances in Optoelectronic Technology and Industry Development, pp. 93–99. CRC Press, Boca Raton (2019). https://doi.org/10.1201/9780429283628CrossRef Sundar, D.S., Sridarshini, T., Sitharthan, R., Karthikeyan, M., Raja, A.S., Carrasco, M.F.: Performance investigation of 16/32-channel DWDM PON and long-reach PON systems using an ASE noise source. In: Jose, G., Ferreira, M. (eds.) Advances in Optoelectronic Technology and Industry Development, pp. 93–99. CRC Press, Boca Raton (2019). https://​doi.​org/​10.​1201/​9780429283628CrossRef
go back to reference Weidler, N., Schuch, J., Knaus, F., Stenner, P., Hoch, S., Maljusch, A., Schäfer, R., Kaiser, B., Jaegermann, W.: X-ray photoelectron spectroscopic investigation of plasma-enhanced chemical vapor deposited NiOx, NiOx(OH)y, and CoNiOx(OH)y: influence of the chemical composition on the catalytic activity for the oxygen evolution reaction. J. Phys. Chem. C. 121, 6455–6465 (2017). https://doi.org/10.1021/acs.jpcc.6b12652CrossRef Weidler, N., Schuch, J., Knaus, F., Stenner, P., Hoch, S., Maljusch, A., Schäfer, R., Kaiser, B., Jaegermann, W.: X-ray photoelectron spectroscopic investigation of plasma-enhanced chemical vapor deposited NiOx, NiOx(OH)y, and CoNiOx(OH)y: influence of the chemical composition on the catalytic activity for the oxygen evolution reaction. J. Phys. Chem. C. 121, 6455–6465 (2017). https://​doi.​org/​10.​1021/​acs.​jpcc.​6b12652CrossRef
Metadata
Title
Electrical and optical properties of sol–gel-deposited NiO films and corresponding response to annealing temperature
Authors
M. Rajesh
K Vengatesan
Moustafa H. Aly
R. Sitharthan
Shanmuga Sundar Dhanabalan
Madurakavi Karthikeyan
Publication date
01-12-2023
Publisher
Springer US
Published in
Optical and Quantum Electronics / Issue 13/2023
Print ISSN: 0306-8919
Electronic ISSN: 1572-817X
DOI
https://doi.org/10.1007/s11082-023-05254-1

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