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Journal of Polymer Research
Published in: Journal of Polymer Research 3/2017

01-03-2017 | ORIGINAL PAPER

Electrically conductive polyaniline/polyimide microfiber membrane prepared via a combination of solution blowing and subsequent in situ polymerization growth

Authors: Ning Wang, Yang Chen, Jianyu Ren, Xiongyi Huang, Xueyan Chen, Guodong Li, Dongqin Liu

Published in: Journal of Polymer Research | Issue 3/2017

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Abstract

Dodecylbenzene sulfonic acid (DBSA) doped-polyaniline (PANI) coated conductive polyimide (PI) microfiber membrane was prepared by chemical oxidation polymerization. PI nanofiber membrane was prepared by solution blowing. Fourier transform infrared spectra (FTIR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM) proved that the successful preparation of composite microfiber membrane with core-shell structures. At the same time, the PANI had an effect of protection on PI nanofiber, which was detected by thermal gravimetric analysis (TGA). The orthogonal experiments were designed to determine the optimal reaction conditions for the conductivity of PANI/PI microfiber membranes as following: ANI concentration (0.15 mol L−1), APS concentration (0.1 mol L−1) and DBSA concentration (0.3 mol L−1). The conductivity of PANI/PI microfiber membranes could arrive to 3.83 × 10−2 S cm−1. Moreover, the PANI/PI microfiber membranes had a superior hexavalent chromium (Cr (VI)) adsorption performance. The factors affecting the performance of hexavalent chromium (Cr (VI)) removal from the aqueous solutions were investigated.
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Metadata
Title
Electrically conductive polyaniline/polyimide microfiber membrane prepared via a combination of solution blowing and subsequent in situ polymerization growth
Authors
Ning Wang
Yang Chen
Jianyu Ren
Xiongyi Huang
Xueyan Chen
Guodong Li
Dongqin Liu
Publication date
01-03-2017
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 3/2017
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-017-1198-3

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