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Electrochemical Fundamentals of Corrosion and Corrosion Protection Read chapter Read first chapter

2018 | OriginalPaper | Chapter

4. Electrochemical Measurement of Atmospheric Corrosion

Authors : Toshiaki Ohtsuka, Atsushi Nishikata, Masatoshi Sakairi, Koji Fushimi

Published in: Electrochemistry for Corrosion Fundamentals

Publisher: Springer Singapore

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Abstract

Electrochemical measurements for studying atmospheric corrosion are written in this chapter. Firstly, typical cells employed for electrochemical studies under a thin electrolyte film are introduced. As electrochemical techniques that are suitable for atmospheric corrosion study, electrochemical impedance spectroscopy (EIS) and Kelvin methods are described. Secondly, EIS and polarization curves measured under the simulated atmospheric environments in laboratory are introduced, and then the mechanism of atmospheric corrosion and cathodic oxygen reduction under thin electrolyte films is discussed. In addition, electrochemical monitoring of pitting corrosion of stainless steel that takes place under cyclic wet–dry environments in the presence of chloride is also described. Finally, atmospheric corrosion monitoring of carbon steel and weathering steels in real atmospheric sites by continuous measurements of electrochemical impedance is demonstrated where impedance of high and low frequencies is employed.

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previous chapter Identification of Passive Films and Corrosion Products
next chapter Hydrogen Embrittlement and Hydrogen Absorption
Literature
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Nishikata A, Ichihara Y, Tsuru T (1995) An application of electrochemical impedance spectroscopy to atmospheric corrosion study. Corros Sci 37:897–911CrossRef
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Nishikata A, Ichihara Y, Hayashi Y, Tsuru T (1997) Influence of electrolyte layer thickness and pH on the initial stage of the atmospheric corrosion of iron. J Electrochem Soc 144:1244–1252CrossRef
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Nishikata A, Zhu Q, Tada E (2014) Long-term monitoring of atmospheric corrosion at weathering steel bridges by an electrochemical impedance method. Corros Sci 87:80–88CrossRef
Metadata
Title
Electrochemical Measurement of Atmospheric Corrosion
Authors
Toshiaki Ohtsuka
Atsushi Nishikata
Masatoshi Sakairi
Koji Fushimi
Copyright Year
2018
Publisher
Springer Singapore
Book
Electrochemistry for Corrosion Fundamentals

Print ISBN: 978-981-10-6819-5

Electronic ISBN: 978-981-10-6820-1

Copyright Year: 2018

DOI
https://doi.org/10.1007/978-981-10-6820-1_4

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