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Optical and Quantum Electronics

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01-02-2020

Electronic polarizability, optical basicity and mechanical properties of aluminum lead phosphate glasses

Authors: Kh. S. Shaaban, E. A. Abdel Wahab, E. R. Shaaban, El Sayed Yousef, Safwat A. Mahmoud

Published in: Optical and Quantum Electronics | Issue 2/2020

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Abstract

A series of aluminum, lead phosphate glasses with chemical composition 70P₂O₅–5Al₂O₃–(25-x) Na₂O-x PbO, where x = (0, 5, 10, 15, 20 and 25 mol%) have been prepared and synthesized using a conventional melting method. The structural analysis has been performed using FTIR techniques. FT-IR confirmed that PbO₄, and AlO₄ are structural units. The optical absorption spectra have been studied and the optical band gap has been estimated. The optical band gap increases with increasing the concentration of PbO. The physical parameters such as density, electronegativity (χ), electron polarizability (α°), optical basicity (˄), molar refractivity R_m, molar polarizability α_m, urbach energy (E_u) and elastic moduli are increased.

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Title: Electronic polarizability, optical basicity and mechanical properties of aluminum lead phosphate glasses
Authors: Kh. S. Shaaban
E. A. Abdel Wahab
E. R. Shaaban
El Sayed Yousef
Safwat A. Mahmoud
Publication date: 01-02-2020
Publisher: Springer US
Published in: Optical and Quantum Electronics / Issue 2/2020
Print ISSN: 0306-8919
Electronic ISSN: 1572-817X
DOI: https://doi.org/10.1007/s11082-020-2191-3

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