Top

Journal of Materials Science

Published in:

28-08-2020 | Composites & nanocomposites

Enhanced dielectric properties of polyvinylidene fluoride-based composite films with layered perovskite KCa₂Na₃Nb₆O₁₉-derived fillers

Authors: Yumi Inagaki, Takahiro Kozawa, Kazuhisa Yano, Tadashi Nakamura

Published in: Journal of Materials Science | Issue 34/2020

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

A polyvinylidene fluoride (PVDF)-based composite film embedded with plate-like fillers was investigated as a novel dielectric composite material that can serve as a candidate film capacitor. Plate-like particles of the dielectric Ca₂Na₃Nb₆O₁₉ (CNN6) filler material were prepared through liquid-phase exfoliation of KCa₂Na₃Nb₆O₁₉ synthesized by a conventional solid-state reaction method. CNN6 fillers with an average aspect ratio of 2.0 were successfully dispersed in a PVDF matrix without large aggregation using a solution blending and casting method. The resultant CNN6/PVDF composite film exhibited higher breakdown strength than a dielectric PVDF-based composite embedded with spherical BaTiO₃ fillers. The superiority of the plate-like filler particles over spherical filler particles was qualitatively confirmed by finite element simulation using a simplified filler/matrix model. A CNN6/PVDF composite film with a thickness of 3.8 µm exhibited a high capacitance density of 10.1 F m⁻³, which was three times higher than that of a biaxially oriented polypropylene film currently used for film capacitors in the power control units of hybrid vehicles.

previous article Magnetic and high-dielectric-constant nanoparticle polymer tri-composites for sensor applications

next article Enhanced photocathodic antifouling/antibacterial properties of polyaniline–Ag–N-doped TiO2 coatings

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Wang YF, Cui J, Wang LX, Yuan QB, Niu YJ, Chen J, Wang Q, Wang H (2017) Compositional tailoring effect on electric field distribution for significantly enhanced breakdown strength and restrained conductive loss in sandwich-structured ceramic/polymer nanocomposites. J Mater Chem A 5:4710–4718. https://doi.org/10.1039/C6TA10709ECrossRef

Qiao YL, Islam MS, Han K, Leonhardt E, Zhang JY, Wang Q, Ploehn HJ, Tang CB (2013) Polymers containing highly polarizable conjugated side chains as high-performance all-organic nanodielectric materials. Adv Funct Mater 23:5638–5646. https://doi.org/10.1002/adfm.201300736CrossRef

Pan JL, Li K, Li JJ, Hsu T, Wang Q (2009) Dielectric characteristics of poly(ether ketone ketone) for high temperature capacitive energy storage. Appl Phys Lett 95:022902. https://doi.org/10.1063/1.3176219CrossRef

Tan Q, Irwin P, Cao Y (2006) Advanced dielectrics for capacitors. IEEE Trans FM 126(11):1153–1159CrossRef

Tan D, Zhang LL, Chen Q, Patricia Irwin (2014) High-temperature capacitor polymer films. J Electron Mater 43(12):4569–4575. https://doi.org/10.1007/s11664-014-3440-7CrossRef

Dang ZM, Yuan JK, Zhan JW, Zhou T, Li ST, Hu GH (2012) Fundamentals, processes and applications of high-permittivity polymer–matrix composites. Prog Mater Sci 57(4):660–723. https://doi.org/10.1016/j.pmatsci.2011.08.001CrossRef

Hu XP, Yi KW, Liu J, Chu BJ (2018) High energy density dielectrics based on PVDF-based polymers. Energy Technol 6:849–864. https://doi.org/10.1002/ente.201700901CrossRef

Dang ZM, Yuan JK, Yao SH, Liao RJ (2013) Flexible nanodielectric materials with high permittivity for power energy storage. Adv Mater 25:6334–6365. https://doi.org/10.1002/adma.201301752CrossRef

Chan KY, Jia BH, Lin H, Hameed N, Lee JH, Lau KT (2018) A critical review on multifunctional composites as structural capacitors for energy storage. Compos Struct 188:123–142. https://doi.org/10.1016/j.compstruct.2017.12.072CrossRef

10.

Yu K, Niu YJ, Xiang F, Zhou YC, Bai YY, Wang H (2013) Enhanced electric breakdown strength and high energy density of barium titanate filled polymer nanocomposites. J Appl Phys 114:174107. https://doi.org/10.1063/1.4829671CrossRef

11.

Yu K, Wang H, Zhou YC, Bai YY, Niu YJ (2013) Enhanced dielectric properties of BaTiO₃/poly(vinylidene fluoride) nanocomposites for energy storage applications. J Appl Phys 113:034105. https://doi.org/10.1063/1.4776740CrossRef

12.

Ducharme S (2009) An inside-out approach to storing electrostatic energy. ACS Nano 3(9):2447–2450. https://doi.org/10.1021/nn901078sCrossRef

13.

Kim P, Doss NM, Tillotson JP, Hotchkiss PJ, Pan MJ, Marder SR, Li JG, Calame JP, Perry JW (2009) High energy density nanocomposites based on surface-modified BaTiO₃ and a ferroelectric polymer. ACS Nano 3(9):2581–2592. https://doi.org/10.1021/nn9006412CrossRef

14.

Suo Z (1993) Models for breakdown-resistant dielectric and ferroelectric ceramics. J Mech Phys Solids 41(7):1155–1176. https://doi.org/10.1016/0022-5096(93)90088-WCrossRef

15.

Pitike KC, Hong W (2014) Phase-field model for dielectric breakdown in solids. J Appl Phys 115:044101. https://doi.org/10.1063/1.4862929CrossRef

16.

Li BW, Osada M, Kim YH, Ebina Y, Akatsuka K, Sasaki T (2017) Atomic layer engineering of high-κ ferroelectricity in 2D perovskites. J Am Chem Soc 139:10868–10874. https://doi.org/10.1021/jacs.7b05665CrossRef

17.

Ebina Y, Akatsuka K, Fukuda K, Sasaki T (2012) Synthesis and in situ X-ray diffraction characterization of two-dimensional perovskite-type oxide colloids with a controlled molecular thickness. Chem Mater 24:4201–4208. https://doi.org/10.1021/cm302480hCrossRef

18.

Arbatti M, Shan X, Cheng ZY (2007) Ceramic–polymer composites with high dielectric constant. Adv Mater 19(10):1369–1372. https://doi.org/10.1002/adma.200601996CrossRef

19.

Fu YJ, Wang YX, Wang S, Gao ZDF, Xiong CX (2019) Enhanced breakdown strength and energy storage of PVDF-based dielectric composites by incorporating exfoliated mica nanosheets. Polym Compos 40(5):2088–2094. https://doi.org/10.1002/pc.24991CrossRef

20.

COMSOL Multiphysics v.5.4. www.comsol.com COMSOL AB, Stockholm, Sweden

21.

Lin X, Hu PH, Gao SM (2016) Enhanced electric displacement induces large energy density in polymer nanocomposites containing core–shell structured BaTiO₃@TiO₂ nanofibers. J Mater Chem A 4:2313–2320. https://doi.org/10.1039/c5ta09547fCrossRef

Title: Enhanced dielectric properties of polyvinylidene fluoride-based composite films with layered perovskite KCa2Na3Nb6O19-derived fillers
Authors: Yumi Inagaki
Takahiro Kozawa
Kazuhisa Yano
Tadashi Nakamura
Publication date: 28-08-2020
Publisher: Springer US
Published in: Journal of Materials Science / Issue 34/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-020-05169-2

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 34/2020

Controlled fabrication of orchid-like nitrogen-doped hierarchical porous carbon and hollow carbon nanospheres

Automated segmentation of computed tomography images of fiber-reinforced composites by deep learning

Microwave-assisted synthesis of MoS2/graphene composites for supercapacitors

Significantly increased Raman enhancement on defect-rich O-incorporated 1T-MoS2 nanosheets

Electrospinning SnO2 fibers with 3D interconnected structure for efficient soot catalytic combustion

Effect of crystallographic orientation on the friction of copper and graphenized copper

Premium Partners