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Published in: Journal of Materials Science 6/2014

01-03-2014

Enhanced novel orange red emission in LiSr4−x (BO3)3:xSm3+ by K+

Authors: Zhi-wei Zhang, You-shun Peng, Xi-hai Shen, Jian-ping Zhang, Shi-tao Song, Qi Lian

Published in: Journal of Materials Science | Issue 6/2014

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Abstract

LiSr4−x (BO3)3:xSm3+ and LiSr3.985−x (BO3)3:0.015Sm3+, xK+ phosphors were prepared by solid-state reactions. The phases and luminescent properties of the obtained phosphors were characterized. The results demonstrate that the phosphors particles emit an intensive reddish orange light emission under excitation at 403 nm. LiSr4−x (BO3)3:xSm3+ phosphor can be efficiently excited by ultraviolet and blue light, and the emission spectrum consists of three emission peaks at 564, 601 and 647 nm. The introduction of the charge compensator K+ into the LiSr4−x (BO3)3:xSm3+ phosphor matrix promotes the increase of the emission intensity, as well as the decrease of the E g value. Results suggest that LiSr3.97(BO3)3:0.015Sm3+, 0.015 K+ is a promising orange–red emitting phosphor for UV LED applications.

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Literature
1.
go back to reference Kim JS, Jeon PE, Choi JC, Park HL, Mho SI, Kim GC (2004) Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor. Appl Phys Lett 84:2931CrossRef Kim JS, Jeon PE, Choi JC, Park HL, Mho SI, Kim GC (2004) Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor. Appl Phys Lett 84:2931CrossRef
2.
go back to reference Dobrowolska A, Zych E (2012) Spectroscopic characterization of Ca3Y2Si3O12:Eu2+, Eu3+ powders in VUV-UV−Vis region. J Phys Chem C 116:25493CrossRef Dobrowolska A, Zych E (2012) Spectroscopic characterization of Ca3Y2Si3O12:Eu2+, Eu3+ powders in VUV-UV−Vis region. J Phys Chem C 116:25493CrossRef
3.
go back to reference Mueller AH, Petruska MA, Achermann M, Werder DJ, Akhadov EA, Koleske DD, Hoffbauer MA, Klimov VI (2005) Multicolor light-emitting diodes based on semiconductor nanocrystals encapsulated in GaN charge injection layers. Nanoletters 5:1039CrossRef Mueller AH, Petruska MA, Achermann M, Werder DJ, Akhadov EA, Koleske DD, Hoffbauer MA, Klimov VI (2005) Multicolor light-emitting diodes based on semiconductor nanocrystals encapsulated in GaN charge injection layers. Nanoletters 5:1039CrossRef
4.
go back to reference Dorman JA, Choi JH, Kuzmanich G, Chang JP (2012) High-quality white light using core–shell RE3+:LaPO4(RE = Eu, Tb, Dy, Ce) phosphors. J Phys Chem C 116:12854CrossRef Dorman JA, Choi JH, Kuzmanich G, Chang JP (2012) High-quality white light using core–shell RE3+:LaPO4(RE = Eu, Tb, Dy, Ce) phosphors. J Phys Chem C 116:12854CrossRef
5.
go back to reference Song X, Fu R, Agathopoulos S, He H, Zhao X, Yu X (2011) Synthesis of BaSi2O2N2:Ce3+, Eu2+ phosphors and determination of their luminescence properties. J Am Ceram Soc 94:501CrossRef Song X, Fu R, Agathopoulos S, He H, Zhao X, Yu X (2011) Synthesis of BaSi2O2N2:Ce3+, Eu2+ phosphors and determination of their luminescence properties. J Am Ceram Soc 94:501CrossRef
6.
go back to reference Krishna RH, Nagabhushana BM, Kuzmanich G, Nagabhushana H, Murthy NS, Sharma SC, Shivakumara C, Chakradhar RPS (2013) Effect of calcination temperature on structural, photoluminescence, and thermoluminescence properties of Y2O3:Eu3+ nanophosphor. J Phys Chem C 117:1915CrossRef Krishna RH, Nagabhushana BM, Kuzmanich G, Nagabhushana H, Murthy NS, Sharma SC, Shivakumara C, Chakradhar RPS (2013) Effect of calcination temperature on structural, photoluminescence, and thermoluminescence properties of Y2O3:Eu3+ nanophosphor. J Phys Chem C 117:1915CrossRef
7.
go back to reference Rack PD, Naman A, Holloway PH, Sun SS, Tuenge RT (1996) Materials used in electroluminescent displays. MRS Bull 21:49 Rack PD, Naman A, Holloway PH, Sun SS, Tuenge RT (1996) Materials used in electroluminescent displays. MRS Bull 21:49
8.
go back to reference Nakano H, Ozono K, Hayashi H, Fujihara S (2012) Synthesis and luminescent properties of a new Eu3+-doped Li1+x (Ta1−z Nb z )1−x Ti x O3 red phosphor. J Am Ceram Soc 95:2795CrossRef Nakano H, Ozono K, Hayashi H, Fujihara S (2012) Synthesis and luminescent properties of a new Eu3+-doped Li1+x (Ta1−z Nb z )1−x Ti x O3 red phosphor. J Am Ceram Soc 95:2795CrossRef
9.
go back to reference Bandi VR, Grandhe BK, Jang K, Lee HS, Yi SS, Jeong JH (2011) Citric based sol-gel synthesis and photoluminescence properties of un-doped and Sm3+ doped Ca3Y2Si3O12 phosphors. Ceram Int 37:2001CrossRef Bandi VR, Grandhe BK, Jang K, Lee HS, Yi SS, Jeong JH (2011) Citric based sol-gel synthesis and photoluminescence properties of un-doped and Sm3+ doped Ca3Y2Si3O12 phosphors. Ceram Int 37:2001CrossRef
10.
go back to reference Sun JY, Zeng JH, Sun YN, Zhu JC, Du HY (2013) Synthesis and luminescence properties of novel Y2Si4N6C:Sm3+ carbonitride phosphor. Ceram Int 39:1097CrossRef Sun JY, Zeng JH, Sun YN, Zhu JC, Du HY (2013) Synthesis and luminescence properties of novel Y2Si4N6C:Sm3+ carbonitride phosphor. Ceram Int 39:1097CrossRef
11.
go back to reference Wang ZJ, Li PL, Yang ZP, Guo QL (2009) A novel red phosphor BaZn2(PO4)2:Sm3+, R+ (R=Li, Na, K). J Lumin 132:1944CrossRef Wang ZJ, Li PL, Yang ZP, Guo QL (2009) A novel red phosphor BaZn2(PO4)2:Sm3+, R+ (R=Li, Na, K). J Lumin 132:1944CrossRef
12.
go back to reference Chen Y, Wang J, Liu C, Kuang XJ, Su Q (2011) A host sensitized reddish-orange Gd2MoO6:Sm3+ phosphor for light emitting diodes. Appl Phys Lett 98:081917CrossRef Chen Y, Wang J, Liu C, Kuang XJ, Su Q (2011) A host sensitized reddish-orange Gd2MoO6:Sm3+ phosphor for light emitting diodes. Appl Phys Lett 98:081917CrossRef
13.
go back to reference Li PL, Wang ZJ, Yang ZP, Guo QL, Li X (2009) Emission features of LiBaBO3:Sm3+ red phosphor for white LED. Mater Lett 63:751CrossRef Li PL, Wang ZJ, Yang ZP, Guo QL, Li X (2009) Emission features of LiBaBO3:Sm3+ red phosphor for white LED. Mater Lett 63:751CrossRef
14.
go back to reference Vengala RB, Rambabu U, Buddhudu S (2007) Emission analysis of Sm3+:Ca4GdO(BO3)3 powder phosphor. Mater Lett 61:2868CrossRef Vengala RB, Rambabu U, Buddhudu S (2007) Emission analysis of Sm3+:Ca4GdO(BO3)3 powder phosphor. Mater Lett 61:2868CrossRef
15.
16.
go back to reference Yang Z, Han Y, Song Y, Zhao Q, Zhou D, Liu Y (2012) Preparation and luminescence properties of Ba2–x B2O5:xSm3+ red-emitting phosphor. J Chin Ceram Soc 40:031 Yang Z, Han Y, Song Y, Zhao Q, Zhou D, Liu Y (2012) Preparation and luminescence properties of Ba2–x B2O5:xSm3+ red-emitting phosphor. J Chin Ceram Soc 40:031
17.
go back to reference Wu L, Chen XL, Li H, He M, Xu YP, Li XZ (2005) Structure determination and relative properties of novel cubic borates MM′4(BO3)3 (M = Li, M′ = Sr; M = Na, M′ = Sr, Ba). Inorg Chem 44:6409CrossRef Wu L, Chen XL, Li H, He M, Xu YP, Li XZ (2005) Structure determination and relative properties of novel cubic borates MM′4(BO3)3 (M = Li, M′ = Sr; M = Na, M′ = Sr, Ba). Inorg Chem 44:6409CrossRef
18.
go back to reference Guo C, Ding X, Seo HJ, Ren Z, Bai J (2011) Luminescent properties of UV excitable blue emitting phosphors MSr4(BO3)3:Ce3+ (M=Li and Na). J Alloy Compd 509:4871CrossRef Guo C, Ding X, Seo HJ, Ren Z, Bai J (2011) Luminescent properties of UV excitable blue emitting phosphors MSr4(BO3)3:Ce3+ (M=Li and Na). J Alloy Compd 509:4871CrossRef
19.
go back to reference Zhang XM, Lang HY, Seo HJ (2011) On the luminescence of Ce3+, Eu3+, and Tb3+ in novel borate LiSr4(BO3)3. J Fluoresc 21:1111CrossRef Zhang XM, Lang HY, Seo HJ (2011) On the luminescence of Ce3+, Eu3+, and Tb3+ in novel borate LiSr4(BO3)3. J Fluoresc 21:1111CrossRef
20.
go back to reference Zhang ZW, Sun XY, Liu L, Peng YS, Shen XH, Zhang WG, Wang DJ (2013) Synthesis and luminescence properties of novel LiSr4(BO3)3:Dy3+ phosphors. Ceram Int 39:1723CrossRef Zhang ZW, Sun XY, Liu L, Peng YS, Shen XH, Zhang WG, Wang DJ (2013) Synthesis and luminescence properties of novel LiSr4(BO3)3:Dy3+ phosphors. Ceram Int 39:1723CrossRef
21.
go back to reference Wang Q, Deng DW, Hua YJ, Huang LH, Wang HP, Zhao SL, Jia GH, Li CX, Xu SQ (2012) Potential tunable white-emitting phosphor LiSr4(BO3)3:Ce3+, Eu2+ for ultraviolet light-emitting diodes. J Lumin 132:434CrossRef Wang Q, Deng DW, Hua YJ, Huang LH, Wang HP, Zhao SL, Jia GH, Li CX, Xu SQ (2012) Potential tunable white-emitting phosphor LiSr4(BO3)3:Ce3+, Eu2+ for ultraviolet light-emitting diodes. J Lumin 132:434CrossRef
22.
go back to reference Ding XM, Liang HB, Hou DJ, Jia SC, Su Q, Sun SS, Tao Y (2012) Site occupancy and luminescence of Ce3+ in NaSr4(BO3)3. J Phys D Appl Phys 45:365301CrossRef Ding XM, Liang HB, Hou DJ, Jia SC, Su Q, Sun SS, Tao Y (2012) Site occupancy and luminescence of Ce3+ in NaSr4(BO3)3. J Phys D Appl Phys 45:365301CrossRef
23.
go back to reference Guo CF, Ding X, Seo HJ, Ren ZY, Bai JT (2011) Double emitting phosphor NaSr4(BO3)3:Ce3+, Tb3+ for near-UV light-emitting diodes. Opt Laser Technol 43:1351CrossRef Guo CF, Ding X, Seo HJ, Ren ZY, Bai JT (2011) Double emitting phosphor NaSr4(BO3)3:Ce3+, Tb3+ for near-UV light-emitting diodes. Opt Laser Technol 43:1351CrossRef
24.
go back to reference Zhang XM, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. Phys B 406:77CrossRef Zhang XM, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. Phys B 406:77CrossRef
25.
go back to reference Zhang XM, Qiao XB, Seo JS (2011) Luminescence properties of novel Ce3+, Mn2+ doped NaSr4(BO3)3 phosphors. Curr Appl Phys 11:442CrossRef Zhang XM, Qiao XB, Seo JS (2011) Luminescence properties of novel Ce3+, Mn2+ doped NaSr4(BO3)3 phosphors. Curr Appl Phys 11:442CrossRef
26.
go back to reference Jiang LH, Zhang YL, Li CY, Hao JQ, Su Q (2009) Synthesis, photoluminescence, thermoluminescence and dosimetry properties of novel phosphor KSr4(BO3)3:Ce3+. J Alloy Compd 482:313CrossRef Jiang LH, Zhang YL, Li CY, Hao JQ, Su Q (2009) Synthesis, photoluminescence, thermoluminescence and dosimetry properties of novel phosphor KSr4(BO3)3:Ce3+. J Alloy Compd 482:313CrossRef
27.
go back to reference Zhang Y, Wu L, Ji MY, Wang B, Kong YF, Xu JJ (2012) Structure and photoluminescence properties of KSr4(BO3)3:Eu3+ red-emitting phosphor. Opt Mater 2:92 Zhang Y, Wu L, Ji MY, Wang B, Kong YF, Xu JJ (2012) Structure and photoluminescence properties of KSr4(BO3)3:Eu3+ red-emitting phosphor. Opt Mater 2:92
28.
go back to reference Bajaj NS, Omanwar SK (2013) Combustion synthesis and characterization of phosphor KSr4(BO3)3:Dy3+. Opt Mater 35:1222CrossRef Bajaj NS, Omanwar SK (2013) Combustion synthesis and characterization of phosphor KSr4(BO3)3:Dy3+. Opt Mater 35:1222CrossRef
29.
go back to reference Wu L, Zhang Y, Gui MY, Lu PZ, Zhao LX, Tian S, Kong YF, Xu JJ (2012) Luminescence and energy transfer of a color tunable phosphor: Dy3+-, Tm3+-, and Eu3+-coactivated KSr4(BO3)3 for warm white UV LEDs. J Mater Chem 22:6463CrossRef Wu L, Zhang Y, Gui MY, Lu PZ, Zhao LX, Tian S, Kong YF, Xu JJ (2012) Luminescence and energy transfer of a color tunable phosphor: Dy3+-, Tm3+-, and Eu3+-coactivated KSr4(BO3)3 for warm white UV LEDs. J Mater Chem 22:6463CrossRef
30.
go back to reference Zhang XM, Seo HJ (2010) Photoluminescence and concentration quenching of NaCa4(BO3)3:Eu3+ phosphor. J Alloy Compd 30:L14CrossRef Zhang XM, Seo HJ (2010) Photoluminescence and concentration quenching of NaCa4(BO3)3:Eu3+ phosphor. J Alloy Compd 30:L14CrossRef
31.
go back to reference Zhang XM, Zhang Z, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. J Alloy Compd 509:4875CrossRef Zhang XM, Zhang Z, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. J Alloy Compd 509:4875CrossRef
32.
go back to reference Zhang XM, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. Phys B 406:77CrossRef Zhang XM, Seo HJ (2011) Luminescence properties of novel NaBa4(BO3)3:Ce3+, Eu3+ phosphors. Phys B 406:77CrossRef
33.
go back to reference Sun XY, Liang WL, Wang WF, Zhang JC (2011) White-light emission from Li2Sr1−3x/2Dy x SiO4 phosphors. Appl Phys A 104:83CrossRef Sun XY, Liang WL, Wang WF, Zhang JC (2011) White-light emission from Li2Sr1−3x/2Dy x SiO4 phosphors. Appl Phys A 104:83CrossRef
34.
go back to reference Jung SH, Kang DS, Jeon DY (2011) Effect of substitution of nitrogen ions to red-emitting Sr3B2O6−3/2x N x :Eu2+ oxy-nitride phosphor for the application to white LED. J Cryst Growth 326:116CrossRef Jung SH, Kang DS, Jeon DY (2011) Effect of substitution of nitrogen ions to red-emitting Sr3B2O6−3/2x N x :Eu2+ oxy-nitride phosphor for the application to white LED. J Cryst Growth 326:116CrossRef
35.
go back to reference Lin X, Qiao XS, Fan XP (2011) Synthesis and luminescence properties of a novel red SrMoO4:Sm3+, R+ phosphor. Solid State Sci 13:579CrossRef Lin X, Qiao XS, Fan XP (2011) Synthesis and luminescence properties of a novel red SrMoO4:Sm3+, R+ phosphor. Solid State Sci 13:579CrossRef
36.
go back to reference Huang SH, Lou LR (1990) Concentration dependence of sensitizer fluorescence intensity in energy transfer. Chin J Lumin 11:1 Huang SH, Lou LR (1990) Concentration dependence of sensitizer fluorescence intensity in energy transfer. Chin J Lumin 11:1
37.
go back to reference Zhang WF, Yin Z, Zhang MS (2000) Study of photoluminescence and electronic states in nanophase strontium titanate. Appl Phys A 70:93CrossRef Zhang WF, Yin Z, Zhang MS (2000) Study of photoluminescence and electronic states in nanophase strontium titanate. Appl Phys A 70:93CrossRef
38.
go back to reference Zhang Q, Wang J, Zhang M, Ding W, Su Q (2007) Enhanced photoluminescence of Ca2Al2SiO7:Eu3+ by charge compensation method. Appl Phys A 88:805CrossRef Zhang Q, Wang J, Zhang M, Ding W, Su Q (2007) Enhanced photoluminescence of Ca2Al2SiO7:Eu3+ by charge compensation method. Appl Phys A 88:805CrossRef
39.
go back to reference Liu G, Jacquier B (2005) Spectroscopic properties of rare earths in optical materials. Springer, Berlin, p 195 Liu G, Jacquier B (2005) Spectroscopic properties of rare earths in optical materials. Springer, Berlin, p 195
40.
go back to reference Puchalska M, Zych E (2012) The effect of charge compensation by means of Na+ ions on luminescence behavior of Sm3+-doped CaAl4O7. J Lumin 132:826CrossRef Puchalska M, Zych E (2012) The effect of charge compensation by means of Na+ ions on luminescence behavior of Sm3+-doped CaAl4O7. J Lumin 132:826CrossRef
41.
go back to reference Li PL, Wang ZJ, Yang ZP, Guo QL, Li X (2009) Emission features of LiBaBO3:Sm3+ red phosphor for white LED. Mater Lett 63:751CrossRef Li PL, Wang ZJ, Yang ZP, Guo QL, Li X (2009) Emission features of LiBaBO3:Sm3+ red phosphor for white LED. Mater Lett 63:751CrossRef
Metadata
Title
Enhanced novel orange red emission in LiSr4−x (BO3)3:xSm3+ by K+
Authors
Zhi-wei Zhang
You-shun Peng
Xi-hai Shen
Jian-ping Zhang
Shi-tao Song
Qi Lian
Publication date
01-03-2014
Publisher
Springer US
Published in
Journal of Materials Science / Issue 6/2014
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-013-7948-7

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