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2014 | OriginalPaper | Chapter

16. EPR Measurement of the Spatial Distribution of Radiation Damage

Authors : Michael K. Bowman, Alexander G. Maryasov, Yuri D. Tsvetkov

Published in: Applications of EPR in Radiation Research

Publisher: Springer International Publishing

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Abstract

EPR methods to determine the nanometer-scale distribution of radiation damage products in solids are reviewed. The emphasis is on pulsed EPR methods that measure weak dipolar interactions between radiation-induced paramagnetic centers. The dipolar interactions provide a convenient ruler for distance measurement that is well-matched to the sizes of spurs and tracks created by photons and particles. The properties of dipolar interactions between paramagnetic centers are discussed with their effect on various EPR measurements. Electron spin echo measurements have determined the pair correlation function between geminate products produced by UV photolysis. Measurements on tracks of ionizing particles show that the paramagnetic centers resulting from the initial holes and electrons have quite different spatial distributions resulting from their different mobilities. Newer methods of EPR dipolar spectroscopy, particularly DEER, have considerable promise for obtaining detailed profiles of the structure of damage distributions in irradiated solids. The radius of the damage region and the number or density of paramagnetic centers created in it can be determined. Both quantities depend on LET of the radiation and can help characterize radiation for dosimetric applications and can aid in understanding the differential effects of irradiation from different sources.

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previous chapter EPR of Primitive Organic Matter: A Tool for Astrobiology

next chapter Study of Spin-Correlated Radical Ion Pairs in Irradiated Solutions by Optically Detected EPR and Related Techniques

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Title: EPR Measurement of the Spatial Distribution of Radiation Damage
Authors: Michael K. Bowman
Alexander G. Maryasov
Yuri D. Tsvetkov
Publisher: Springer International Publishing
Book: Applications of EPR in Radiation Research
Print ISBN: 978-3-319-09215-7

Electronic ISBN: 978-3-319-09216-4

Copyright Year: 2014
DOI: https://doi.org/10.1007/978-3-319-09216-4_16

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