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Published in: Environmental Earth Sciences 1/2010

01-07-2010 | Original Article

Even-numbered n-alkanes/n-alkenes predominance in surface sediments of Gabes Gulf in Tunisia

Authors: Fatma Aloulou, Monem Kallel, Mohamed Dammak, Boubaker Elleuch, Alain Saliot

Published in: Environmental Earth Sciences | Issue 1/2010

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Abstract

Hydrocarbons in surface sediments were studied quantitatively and qualitatively in 18 stations along the coastline of Gabes Gulf in Tunisia. The results show that the total hydrocarbon levels vary along a wide range from 90 to 1,800 ppm. The GC–MS profiles of aliphatic hydrocarbons vary according to the stations and show that the hydrocarbons were derived from various sources. A special feature prevalent in several stations was identified: aliphatic hydrocarbons with distinctive chemical features. This includes a high abundance of even-numbered n-alkanes (n-C14–n-C26, maximizing at n-C18, n-C20 and n-C22) and n-alk-1-enes (n-C14:1–n-C24:1, maximizing at n-C16:1, n-C18:1, n-C20:1 and n-C22:1). This unusual predominance of even-numbered n-alkanes/alkenes is reported for the first time in the Gulf of Gabes and it thus contributes to the information on the rare occurrence of such distributions in the geosphere.

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Literature
go back to reference Aboul-Kassim TAT, Simoneit BRT (1995) Petroleum hydrocarbon fingerprinting and sediment transport assessed by molecular biomarker and multivariate statistical analyses in the Eastern Harbour of Alexandria, Egypt. Mar Pollut Bull 30:63–73CrossRef Aboul-Kassim TAT, Simoneit BRT (1995) Petroleum hydrocarbon fingerprinting and sediment transport assessed by molecular biomarker and multivariate statistical analyses in the Eastern Harbour of Alexandria, Egypt. Mar Pollut Bull 30:63–73CrossRef
go back to reference Albaigés J, Cuberes MR (1980) On the degradation of petroleum residues in the marine environment. Chemosphere 9:539–545CrossRef Albaigés J, Cuberes MR (1980) On the degradation of petroleum residues in the marine environment. Chemosphere 9:539–545CrossRef
go back to reference Albaigés J, Grimalt J, Bayona JM, Risebrough R, De Lappe B, Walker W (1984) Dissolved, particulate and sedimentary hydrocarbons in a deltaic environment. Org Geochem 6:237–248CrossRef Albaigés J, Grimalt J, Bayona JM, Risebrough R, De Lappe B, Walker W (1984) Dissolved, particulate and sedimentary hydrocarbons in a deltaic environment. Org Geochem 6:237–248CrossRef
go back to reference Baumard P, Budzinski H, Garrigues P, Narbonne JF, Burgeot T, Michel X, Bellocq J (1999) Polycyclic aromatic hydrocarbons (PAH) burden of mussels (Mytilus sp.) in different marine environments in relation with sediment PAH contamination and bioavailability. Mar Environ Res 47:415–439CrossRef Baumard P, Budzinski H, Garrigues P, Narbonne JF, Burgeot T, Michel X, Bellocq J (1999) Polycyclic aromatic hydrocarbons (PAH) burden of mussels (Mytilus sp.) in different marine environments in relation with sediment PAH contamination and bioavailability. Mar Environ Res 47:415–439CrossRef
go back to reference Ben Othmane S (1971) Observations hydrologiques, dragages, et chalutage dans le sud-est tunisien. Bull Inst Océanogr Pêche Salammbôo 2:103–120 Ben Othmane S (1971) Observations hydrologiques, dragages, et chalutage dans le sud-est tunisien. Bull Inst Océanogr Pêche Salammbôo 2:103–120
go back to reference Benlahcen KT, Chaoui A, Budzinski H, Bellocq J, Garrigues P (1997) Distribution and sources of polycyclic aromatic hydrocarbons in some Mediterranean coastal sediments. Mar Pollut Bull 34:298–305CrossRef Benlahcen KT, Chaoui A, Budzinski H, Bellocq J, Garrigues P (1997) Distribution and sources of polycyclic aromatic hydrocarbons in some Mediterranean coastal sediments. Mar Pollut Bull 34:298–305CrossRef
go back to reference Blumer M, Snyder WD (1965) Isoprenoid hydrocarbons in recent sediments: presence of pristane and probable absence of phytane. Science 150:1588–1589CrossRef Blumer M, Snyder WD (1965) Isoprenoid hydrocarbons in recent sediments: presence of pristane and probable absence of phytane. Science 150:1588–1589CrossRef
go back to reference Boehm PD, Requejo AG (1986) Overview of the recent sediment hydrocarbon geochemistry of Atlantic and Gulf coast outer continental shelf environments. Estuar Coast Shelf Sci 23:29–58CrossRef Boehm PD, Requejo AG (1986) Overview of the recent sediment hydrocarbon geochemistry of Atlantic and Gulf coast outer continental shelf environments. Estuar Coast Shelf Sci 23:29–58CrossRef
go back to reference Bray EE, Evans ED (1961) Distribution of n-paraffins as a clue to recognition of source beds. Geochim Cosmochim Acta 22:2–15CrossRef Bray EE, Evans ED (1961) Distribution of n-paraffins as a clue to recognition of source beds. Geochim Cosmochim Acta 22:2–15CrossRef
go back to reference Broman D, Colmsjo A, Ganning B, Naf C, Zebuhr Y, Ostman C (1987) Fingerprinting petroleum hydrocarbons in bottom sediment, plankton, and sediment trap collected seston. Mar Pollut Bull 18:380–388CrossRef Broman D, Colmsjo A, Ganning B, Naf C, Zebuhr Y, Ostman C (1987) Fingerprinting petroleum hydrocarbons in bottom sediment, plankton, and sediment trap collected seston. Mar Pollut Bull 18:380–388CrossRef
go back to reference Colombo JC, Pelletier E, Brochu C, Khalil M, Catoggio JA (1989) Determination of hydrocarbon sources using n-alkane and polyaromatic hydrocarbon distribution indexes. Case study: Rio de La Plata Estuary, Argentina. Environ Sci Technol 23:888–894CrossRef Colombo JC, Pelletier E, Brochu C, Khalil M, Catoggio JA (1989) Determination of hydrocarbon sources using n-alkane and polyaromatic hydrocarbon distribution indexes. Case study: Rio de La Plata Estuary, Argentina. Environ Sci Technol 23:888–894CrossRef
go back to reference Debyser Y, Pelet R, Dastillung M (1977) Geochimie organique des sediments marins recents: Mer Noire, Baltique, Atlantique (Mauritanie). In: Campos R, Goni J (eds) Advances in organic geochemistry 1975. Enadisma, Madrid, pp 289–320 Debyser Y, Pelet R, Dastillung M (1977) Geochimie organique des sediments marins recents: Mer Noire, Baltique, Atlantique (Mauritanie). In: Campos R, Goni J (eds) Advances in organic geochemistry 1975. Enadisma, Madrid, pp 289–320
go back to reference De Luca G, Furesi A, Leardi R, Micera G, Panzanelli A, Piu PC, Sanna G (2004) Polycyclic aromatic hydrocarbons assessment in the sediments of the Porto Torres harbor (Northern Sardinia, Italy). Mar Chem 86:15–32CrossRef De Luca G, Furesi A, Leardi R, Micera G, Panzanelli A, Piu PC, Sanna G (2004) Polycyclic aromatic hydrocarbons assessment in the sediments of the Porto Torres harbor (Northern Sardinia, Italy). Mar Chem 86:15–32CrossRef
go back to reference Ekpo BO, Oyo-Ita OE, Wehner H (2005) Even-n-alkane/alkene predominances in surface sediments from the Calabar River, SE Niger Delta, Nigeria. Naturwissenschaften 92:341–346CrossRef Ekpo BO, Oyo-Ita OE, Wehner H (2005) Even-n-alkane/alkene predominances in surface sediments from the Calabar River, SE Niger Delta, Nigeria. Naturwissenschaften 92:341–346CrossRef
go back to reference Farrington JW, Tripp BW (1977) Hydrocarbons in western North Atlantic surface sediments. Geochim Cosmochim Acta 41:1627–1641CrossRef Farrington JW, Tripp BW (1977) Hydrocarbons in western North Atlantic surface sediments. Geochim Cosmochim Acta 41:1627–1641CrossRef
go back to reference Giger W, Schaffner C (1977) Aliphatic, olefinic and aromatic hydrocarbons in recent sediments of a highly eutrophic lake. In: Campos R, Goňi J (eds) Advances in organic geochemistry, 1975. Enadisma, Madrid, pp 375–390 Giger W, Schaffner C (1977) Aliphatic, olefinic and aromatic hydrocarbons in recent sediments of a highly eutrophic lake. In: Campos R, Goňi J (eds) Advances in organic geochemistry, 1975. Enadisma, Madrid, pp 375–390
go back to reference Giger W, Schaffner C, Wakehams G (1980) Aliphatic and olefinic hydrocarbons in recent sediments of Greifensee, Switzerland. Geochim Cosmochim Acta 44:119–129CrossRef Giger W, Schaffner C, Wakehams G (1980) Aliphatic and olefinic hydrocarbons in recent sediments of Greifensee, Switzerland. Geochim Cosmochim Acta 44:119–129CrossRef
go back to reference Gogou A, Stephanou EG (2004) Marine organic geochemistry of the Eastern Mediterranean: 2. Polar biomarkers in Cretan Sea surficial sediments. Mar Chem 85:1–25CrossRef Gogou A, Stephanou EG (2004) Marine organic geochemistry of the Eastern Mediterranean: 2. Polar biomarkers in Cretan Sea surficial sediments. Mar Chem 85:1–25CrossRef
go back to reference Gogou A, Bouloubassi I, Stephanou EG (2000) Marine organic geochemistry of Eastern Mediterranean: aliphatic and polyaromatic hydrocarbons in Cretean Sea surficial sediments. Mar Chem 68:265–282 Gogou A, Bouloubassi I, Stephanou EG (2000) Marine organic geochemistry of Eastern Mediterranean: aliphatic and polyaromatic hydrocarbons in Cretean Sea surficial sediments. Mar Chem 68:265–282
go back to reference Grimalt J, Albaigés J (1985) n-Alkane Distributions in Surface Sediments from the Arabian Gulf. Naturwissenschaften 72:35–37CrossRef Grimalt J, Albaigés J (1985) n-Alkane Distributions in Surface Sediments from the Arabian Gulf. Naturwissenschaften 72:35–37CrossRef
go back to reference Grimalt J, Albaigés J (1986) Predominance of even carbon-numbered n-alkanes in coal seam samples of Nograd Basin (Hungary). Naturwissenschaften 73:729–731 Grimalt J, Albaigés J (1986) Predominance of even carbon-numbered n-alkanes in coal seam samples of Nograd Basin (Hungary). Naturwissenschaften 73:729–731
go back to reference Grimalt J, Albaigés J (1987) Sources and occurrence of C12–C22 n-alkane distributions with even carbon-number preference in sedimentary environments. Geochim Cosmochim Acta 51:1379–1384CrossRef Grimalt J, Albaigés J (1987) Sources and occurrence of C12–C22 n-alkane distributions with even carbon-number preference in sedimentary environments. Geochim Cosmochim Acta 51:1379–1384CrossRef
go back to reference Jarde E (2002) Composition organique de boues résiduaires de station d’épuration lorraines: caractérisation moléculaire et effets de la biodégradation. Thèse de Doctorat, Université Henri Poincaré, Nancy I, p 271 Jarde E (2002) Composition organique de boues résiduaires de station d’épuration lorraines: caractérisation moléculaire et effets de la biodégradation. Thèse de Doctorat, Université Henri Poincaré, Nancy I, p 271
go back to reference Jovančićević B, Polić P, Vitorović D, Scheeder G, Teschner M, Wehner H (2001) Biodegradation of oil-type pollutants in Danube alluvial sediments (Yugoslavia). Fresen Environ Bull 10:178–182 Jovančićević B, Polić P, Vitorović D, Scheeder G, Teschner M, Wehner H (2001) Biodegradation of oil-type pollutants in Danube alluvial sediments (Yugoslavia). Fresen Environ Bull 10:178–182
go back to reference Lecaros OP, Alberti P, Astorga MS (1991) Hidrocarburos parafínicos en aguas del Estrecho de Magallanes. Rev Biol Mar 26:61–74 Lecaros OP, Alberti P, Astorga MS (1991) Hidrocarburos parafínicos en aguas del Estrecho de Magallanes. Rev Biol Mar 26:61–74
go back to reference Louati A, Elleuch B, Kallel M, Saliot A, Dagaut J, Oudot J (2001) Hydrocarbon contamination of coastal sediments from the Sfax area (Tunisia), Mediterranean sea. Mar Pollut Bull 42:444–451CrossRef Louati A, Elleuch B, Kallel M, Saliot A, Dagaut J, Oudot J (2001) Hydrocarbon contamination of coastal sediments from the Sfax area (Tunisia), Mediterranean sea. Mar Pollut Bull 42:444–451CrossRef
go back to reference Medeiros PM, Bícegoc MC, Castelaob RM, Del Rossod C, Fillmannd G, Zambonid AJ (2005) Natural and anthropogenic hydrocarbon inputs to sediments of Patos Lagoon Estuary, Brazil. Environ Int 31:77–87CrossRef Medeiros PM, Bícegoc MC, Castelaob RM, Del Rossod C, Fillmannd G, Zambonid AJ (2005) Natural and anthropogenic hydrocarbon inputs to sediments of Patos Lagoon Estuary, Brazil. Environ Int 31:77–87CrossRef
go back to reference Mille G, Rivet L, Ila Jawadt A, Bertrand JC (1992) Hydrocarbon distributions in low polluted surface sediments from Kuwait, Bahrain and Oman coastal zones (before the Gulf war). Mar Pollut Bull 24:622–626 Mille G, Rivet L, Ila Jawadt A, Bertrand JC (1992) Hydrocarbon distributions in low polluted surface sediments from Kuwait, Bahrain and Oman coastal zones (before the Gulf war). Mar Pollut Bull 24:622–626
go back to reference Mille G, Asia L, Guiliano M, Malleret L, Doumenq P (2007) Hydrocarbons in coastal sediments from the Mediterranean Sea (Gulf of Fos area, France). Mar Pollut Bull 54:566–575CrossRef Mille G, Asia L, Guiliano M, Malleret L, Doumenq P (2007) Hydrocarbons in coastal sediments from the Mediterranean Sea (Gulf of Fos area, France). Mar Pollut Bull 54:566–575CrossRef
go back to reference Nishimura M, Baker EW (1986) Possible origin of n-alkanes with a remarkable even to odd predominance in recent marine sediments. Geochim Cosmochim Acta 50:299–305CrossRef Nishimura M, Baker EW (1986) Possible origin of n-alkanes with a remarkable even to odd predominance in recent marine sediments. Geochim Cosmochim Acta 50:299–305CrossRef
go back to reference Noor A, Mille G, Liong S, Jawahir B (1989) n-Alkane distribution in coastal surficial sediments from Ujungpandang, Indonesia. Mar Pollut Bull 18:505–507CrossRef Noor A, Mille G, Liong S, Jawahir B (1989) n-Alkane distribution in coastal surficial sediments from Ujungpandang, Indonesia. Mar Pollut Bull 18:505–507CrossRef
go back to reference Prahl FG, Ertel JR, Goni MA, Sparrow MA, Eversmeyer B (1994) Terrestrial organic carbon contributions to sediments on the Washington margin. Geochim Cosmochim Acta 58:3035–3048CrossRef Prahl FG, Ertel JR, Goni MA, Sparrow MA, Eversmeyer B (1994) Terrestrial organic carbon contributions to sediments on the Washington margin. Geochim Cosmochim Acta 58:3035–3048CrossRef
go back to reference Rushdi AI, Dou Abul AA, Mohammed SS, Simoneit BRT (2006) Compositions and sources of extractable organic matter in Mesopotamian marshland surface sediments of Iraq. I. Aliphatic lipids. Environ Geol 50:857–866CrossRef Rushdi AI, Dou Abul AA, Mohammed SS, Simoneit BRT (2006) Compositions and sources of extractable organic matter in Mesopotamian marshland surface sediments of Iraq. I. Aliphatic lipids. Environ Geol 50:857–866CrossRef
go back to reference Saliot A (1981) Natural hydrocarbons in sea water. In: Duursma EK, Dawson R (eds) Marine organic chemistry. Elsevier, Amsterdam, pp 327–374 Saliot A (1981) Natural hydrocarbons in sea water. In: Duursma EK, Dawson R (eds) Marine organic chemistry. Elsevier, Amsterdam, pp 327–374
go back to reference Simoneit BRT (1984) Organic matter of the troposphere-III. Characterization and sources of petroleum and pyrogenic residues in aerosols over the western United States. Atmos Environ 18:51–67CrossRef Simoneit BRT (1984) Organic matter of the troposphere-III. Characterization and sources of petroleum and pyrogenic residues in aerosols over the western United States. Atmos Environ 18:51–67CrossRef
go back to reference Simoneit BRT (1985) Application of molecular marker analysis to vehicular exhaust for source reconciliation. Int J Environ Anal Chem 22:203–233CrossRef Simoneit BRT (1985) Application of molecular marker analysis to vehicular exhaust for source reconciliation. Int J Environ Anal Chem 22:203–233CrossRef
go back to reference Simoneit BRT (2002) Biomass burning—a review of organic tracers from smoke from incomplete combustion. Appl Geochem 17:129–162CrossRef Simoneit BRT (2002) Biomass burning—a review of organic tracers from smoke from incomplete combustion. Appl Geochem 17:129–162CrossRef
go back to reference Simoneit BRT, Mazurek MA (1982) Organic matter of the troposphere-II. Natural background of biogenic lipid matter in aerosols over the rural western United States. Atmos Environ 16:2139–2159CrossRef Simoneit BRT, Mazurek MA (1982) Organic matter of the troposphere-II. Natural background of biogenic lipid matter in aerosols over the rural western United States. Atmos Environ 16:2139–2159CrossRef
go back to reference Simoneit BRT, Mazurek MA, Brenner S, Crisp PT, Kaplan IR (1979) Organic geochemistry of recent sediments from Guaymas Basin, Gulf of California. Deep Sea Res 26:879–891CrossRef Simoneit BRT, Mazurek MA, Brenner S, Crisp PT, Kaplan IR (1979) Organic geochemistry of recent sediments from Guaymas Basin, Gulf of California. Deep Sea Res 26:879–891CrossRef
go back to reference Tsapakis M, Stephanou EG, Karakassis I (2003) Evaluation of atmospheric transport as a nonpoint source of polycyclic aromatic hydrocarbons in marine sediments of the eastern Mediterranean. Mar Chem 80:283–298CrossRef Tsapakis M, Stephanou EG, Karakassis I (2003) Evaluation of atmospheric transport as a nonpoint source of polycyclic aromatic hydrocarbons in marine sediments of the eastern Mediterranean. Mar Chem 80:283–298CrossRef
go back to reference Venkatesan MI, Kaplan RI (1982) Distribution and transport of hydrocarbons in surface sediments of the Alaskan outer continental shelf. Geochim Cosmochim Acta 46:2135–2149CrossRef Venkatesan MI, Kaplan RI (1982) Distribution and transport of hydrocarbons in surface sediments of the Alaskan outer continental shelf. Geochim Cosmochim Acta 46:2135–2149CrossRef
go back to reference Winters K, Parker PL, Van Baalen C (1960) Hydrocarbons of blue-green algae: geochemical significance. Science 163:467–468CrossRef Winters K, Parker PL, Van Baalen C (1960) Hydrocarbons of blue-green algae: geochemical significance. Science 163:467–468CrossRef
go back to reference Youngblood WW, Blumer M, Guillard RI, Fiore F (1971) Saturated and unsaturated hydrocarbons in marine benthic algae. Mar Biol 8:190–201CrossRef Youngblood WW, Blumer M, Guillard RI, Fiore F (1971) Saturated and unsaturated hydrocarbons in marine benthic algae. Mar Biol 8:190–201CrossRef
go back to reference Zaghden H, Kallel M, Louati A, Elleuch B, Oudot J, Saliot A (2005) Hydrocarbons in surface sediments from the Sfax coastal zone, (Tunisia) Mediterranean Sea. Mar Pollut Bull 50:1287–1294CrossRef Zaghden H, Kallel M, Louati A, Elleuch B, Oudot J, Saliot A (2005) Hydrocarbons in surface sediments from the Sfax coastal zone, (Tunisia) Mediterranean Sea. Mar Pollut Bull 50:1287–1294CrossRef
go back to reference Zrafi-Nouira I, Khedir-Ghenim Z, Zrafi F, Bahri R, Cheraeif I, Rouabhia M, Saidane-Mosbahi D (2008) Hydrocarbon pollution in the sediment from the Jarzouna-Bizerte Coastal Area of Tunisia (Mediterranean Sea). Bull Environ Contam Toxicol 80:566–572CrossRef Zrafi-Nouira I, Khedir-Ghenim Z, Zrafi F, Bahri R, Cheraeif I, Rouabhia M, Saidane-Mosbahi D (2008) Hydrocarbon pollution in the sediment from the Jarzouna-Bizerte Coastal Area of Tunisia (Mediterranean Sea). Bull Environ Contam Toxicol 80:566–572CrossRef
Metadata
Title
Even-numbered n-alkanes/n-alkenes predominance in surface sediments of Gabes Gulf in Tunisia
Authors
Fatma Aloulou
Monem Kallel
Mohamed Dammak
Boubaker Elleuch
Alain Saliot
Publication date
01-07-2010
Publisher
Springer-Verlag
Published in
Environmental Earth Sciences / Issue 1/2010
Print ISSN: 1866-6280
Electronic ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-009-0315-y

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