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Metallurgical and Materials Transactions A
Published in: Metallurgical and Materials Transactions A 11/2014

01-10-2014

Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram

Authors: Milena Premović, Duško Minić, Vladan Ćosović, Dragan Manasijević, Dragana Živković

Published in: Metallurgical and Materials Transactions A | Issue 11/2014

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Abstract

A phase diagram of the Bi-Ge-Sb ternary system was investigated experimentally by differential thermal analysis (DTA), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), and X-ray powder diffraction (XRD) methods and theoretically by the CALPHAD method. The liquidus projection; invariant equilibria; and three vertical sections, Sb-Bi0.5Ge0.5, Ge-Bi0.5Sb0.5, and Bi-Ge0.5Sb0.5, as well as isothermal sections at 773 K and 373 K (500 °C and 100 °C), were predicted using optimized thermodynamic parameters for constitutive binary systems from the literature. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Predicted isothermal sections at 773 K and 373 K (500 °C and 100 °C) were compared with the results of the SEM-EDS and XRD analysis from this work. In both cases, good agreement between the extrapolated phase diagram and experimental results was obtained. Alloys from the three studied vertical sections were additionally analyzed using the Brinell hardness test.
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Literature
1.
F. von Rohr, A. Schilling, and R.J. Cava: J. Phys.: Condens. Matter., 2013, vol. 25 (7), p. 075804. CrossRef
2.
3.
D. Ielmini and A.L. Lacaita: Mater. Today, 2011, vol. 14 (12), pp. 600–07.CrossRef
4.
S. Raoux, R.M. Shelby, J.J. Sweet, B. Munoz, M. Salinga, Y.-C. Chen, Y.-H. Shih, E.-K. Lai, and M.-H. Lee: Microelectron. Eng., 2008, vol. 85, pp. 2330–33.CrossRef
5.
S.O. Ryu, S.M. Yoon, K.J. Choi, N.Y. Lee, Y.S. Park, S.Y. Lee, B.G. Yu, J.B. Park, and W.C. Shin: J. Electrochem. Soc., 2006, vol. 153, pp. 234–37.CrossRef
6.
T.C. Chong, X. Hu, L.P. Shi, P.K. Tan, X.S. Miao, and R. Zhao: Jpn. J. Appl. Phys., 2003, vol. 42 (2B), pp. 824–27.CrossRef
7.
G.W. Burr, B.N. Kurdi, J.C. Scott, C.H. Lam, K. Gopalakrishnan, and R.S. Shenoy: IBM J. Res. Dev., 2008, vol. 52 (4–5), pp. 449–64.CrossRef
8.
A. Kostov, D. Živković, and Ž. Živković: J. Therm. Anal. Calorim., 2000, vol. 60, pp. 473–87.CrossRef
9.
J.M. del Pozo and L. Diaz: J. Non-Cryst. Solids, 1999, vol. 243, pp. 45–51.CrossRef
10.
V. Gandova, K. Lilova, H. Malakova, B. Huber, N. Milcheva, H. Ipser, J. Vrestal, and G. Vassilev: J. Min. Metall. Sect. B–Metall., 2010, vol. 46 (1), pp. 11–23.CrossRef
11.
12.
J. Solis, C.N. Afonso, J.F. Trull, and M.C. Morilla: J. Appl. Phys., 1994, vol. 75 (12), pp. 7788–93.CrossRef
13.
14.
E. Dichia, A. Wojakowskab, and B. Legendrea: J. Alloys Compd., 2001, vol. 320, pp. 218–23.CrossRef
15.
A. Kostov, D. Živković, and Ž. Živković: Thermochim. Acta, 1999, vol. 338, pp. 35–43.CrossRef
16.
L.H. Belz: Adv. Mater. Process. Inc. Met. Progr., 1987, vol. 132 (5), pp. 65–69.
17.
M.C. Roberts: Mater. Soc., 1989, vol. 13 (4), pp. 411–30.
18.
19.
J. Liu, C. Guo, C. Li, and Z. Du: Thermochim. Acta, 2011, vol. 520, pp. 38–47.CrossRef
20.
H. Ohtani and K. Ishida: J. Electr. Mater., 1994, vol. 23 (8), pp. 747–755.CrossRef
21.
22.
N. Saunders and A.P. Miodownik: CALPHAD (A Comprehensive Guide), Elsevier, London, 1998.
23.
H.L. Lukas, S.G. Fries, and B. Sundman: Computational Thermodynamics: CALPHAD Method, Cambridge University Press, Cambridge, United Kingdom, 2007.CrossRef
24.
S. Suriñach, M.D. Baró, and F. Tejerina: ICTA 80, Therm. Anal., 1980, vol. 1, pp. 155–60.CrossRef
25.
26.
F.A. Trumbore, W.G. Spitzer, R.A. Logan, and C.L. Luke: J. Electrochem. Soc., 1962, vol. 109, pp. 734–38.CrossRef
27.
R.A. Akopyan and A.A. Abdullayev: Izv. Askad. Nauk SSSR Neorg. Mater., 1978, vol. 14, pp. 1827–33.
28.
V.M. Glazov and A.A. Abdullyev: Izv. Askad. Nauk. SSSR Neorg. Mater., 1978, vol. 14, pp. 1823–26.
29.
30.
K. Ruttewit and G. Masing: Z. Metallkd., 1940, vol. 32, pp. 52–61.
31.
Y. Malmejac, P. Desre, and E. Bonnier: Mem. Sci. Rev. Metall., 1972, vol. 69, pp. 565–77.
32.
S.A. Alfer, L.A. Mechkovskij, and A.A. Vecher: Z. Fiz. Khim., 1983, vol. 57, pp. 1292–93.
33.
R.W. Olesinski and G.J. Abbaschian: Alloy Phase Diagrams, 1986, vol. 7, pp. 219–22.CrossRef
34.
A. Kostov, D. Zivkovic, and Z. Zivkovic: Thermochim. Acta, 1999, vol. 338, pp. 35–43.CrossRef
35.
V.B. Predel and D.W. Stein: Z. Metallkd., 1970, vol. 61, pp. 909–14.
36.
S.A. Alfer, A.A. Vecher, and O.A. Egorov: Russ. J. Phys. Chem., 1981, vol. 55, pp. 910–12.
37.
J. Wang, C. Leinenbach, and M. Roth: J. Alloys Compd., 2009, vol. 485, pp. 577–82.CrossRef
38.
N. Nasir, A. Grytsiv, P. Rogl, A. Saccone, and G. Giester: J. Solid State Chem., 2009, vol. 182, pp. 645–56.CrossRef
39.
40.
M. Cook: J. Inst. Met., 1922, vol. 28, pp. 421–45.
41.
42.
Y.E. Gegusin and B.Y. Pines: Z. Fiz. Khim., 1952, vol. 26, pp. 27–30.
43.
V.M. Glazov and Y.L. Liu: Izv. Akad. Nauk SSSR, Otd. Technol. Nauk, Metall. Toplivo, 1961, vol. 2, pp. 99–107.
44.
A.N. Campbell and J. Winkler: Can. J. Chem., 1963, vol. 41 (4), pp. 848–51.CrossRef
45.
M. Akaishi and S. Saito: Bull. Tokyo Inst. Technol., 1974, vol. 120, pp. 81–87.
46.
47.
V.S. Zemskov, A.D. Belaya, S.A. Roslov, L.V. Chani, and E.F. Pershina: Inorg. Mater., 1976, vol. 12, pp. 685–88.
48.
N.T. Gladkikh, S.P. Chizhik, V.I. Latin, L.K. Grigor’eva, A.L. Samsonik, and V.N. Sukhov: Russ. Metall., 1987, vol. 1, pp. 173–81.
49.
Y. Cui, S. Ishihara, X.J. Liu, I. Ohnuma, R. Kainuma, H. Ohtani, and K. Ishida: Mater. Trans., 2002, vol. 43 (8), pp. 1879–86.CrossRef
50.
51.
A. Yazawa, T. Kawashima, and K. Itagaki: Nippon Kinzoku Gakkaishi, 1968, vol. 32, pp. 1288–93.
52.
A.A. Savitskii, L.A. Mechkovskii, and A.A. Vecher: Russ. J. Phys. Chem., 1975, vol. 49, pp. 1721–29.
53.
M. Kawakami: Sci. Rep. Tohoku Imp. Univ. Ser., 1930, vol. 1(19), pp. 521–27.
54.
Y. Feutelais, G. Morgant, J.R. Didry, and J. Schnitter: CALPHAD, 1992, vol. 16, pp. 111–19.CrossRef
55.
A.T. Dinsdale, A. Kroupa, J. Vizdal, J. Vřešťál, A. Watson, and A. Zemanova: COST Action MP0602, Version 1.0, Thermodynamic Database, Brno, 2009.
56.
A. Kroupa, A.T. Dinsdale, A. Watson, J.J. Vřešťál, A. Zemanova, and P. Broz: J. Min. Metall. Sect. B–Metall., 2012, vol. 48 (3), pp. 339–46.CrossRef
57.
Ž. Živković, D. Živković, and J. Šesták: J. Therm. Anal. Calorim., 1995, vol. 43 (2), pp. 417–26.CrossRef
58.
R.M. Lopez, A. Dauscher, H. Scherrer, J. Hejtmanek, H. Kenzar, and B. Lenoir: Appl. Phys. A, 1999, vol. 68, pp. 597–602.CrossRef
59.
A. Ahmad, R. Bilas, and O. P. Kalyal: J. Mater. Sci., 1995, vol. 30 (17), pp. 4339–42.CrossRef
60.
K. Ruttewitt and G. Masing: Z. Metallkd., 1940, vol. 32, pp. 52–61.
61.
62.
63.
64.
D.G. Schweitzer and J.R. Weeks: ASM Trans. Q., 1961, vol. 54, pp. 185–200.
65.
R.W.Olesinski and G.J. Abbaschian: Bull. Alloy Phase Diagrams, 1986, vol. 7 (6), pp. 535–46.CrossRef
66.
F.A. Trumbore, W.G. Spitzer, R.A. Logan, and C.L. Luke: J. Electrochem. Soc., 1962, vol. 109, pp. 734–38.CrossRef
67.
B. Predel and D.W. Stein: Z. Metallkd., 1971, vol. 62, pp. 381–86.
68.
L.A. Mechkovskij, P.P. Zhuk, and A.A. Vecher: Russ. J. Phys. Chem., 1978, vol. 52, pp. 1702−03.
69.
V.M. Kozlovskaya and R.N. Rubinshtein: Sov. Phys. Solid State, 1962, vol. 3, pp. 2434–40.
70.
Y.M. Muggianu, M. Gambino, and J.P. Bros: J. Chim. Phys., 1975, vol. 72, pp. 83–88.
71.
O. Redlich and A.T. Kister: Indust. Eng. Chem., 1948, vol. 40, pp. 345–48.CrossRef
72.
W. Cao, S.-L. Chen, F. Zhang, K. Wu, Y. Yang, Y.A. Chang, R. Schmid-Fetzer, and W. A. Oates: CALPHAD, 2009, vol. 33 (2), pp. 328–42.CrossRef
73.
T. Swanson: Nat. Bur. Stand. (U.S.), Circ., 1951, vol. 18(I), p. 539.
74.
75.
C.S. Barrett, P. Cucka, and K. Haefner: Acta Crystallogr., 1963, vol. 16, p. 451.CrossRef
76.
S. Lahti: Bull. Geol. Surv. Finl., 1981, vol. 66, p. 314.
Metadata
Title
Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram
Authors
Milena Premović
Duško Minić
Vladan Ćosović
Dragan Manasijević
Dragana Živković
Publication date
01-10-2014
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 11/2014
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-014-2445-4

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