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Optical and Quantum Electronics

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01-11-2023

Fabrication and tuning the morphological and optical characteristics of PMMA/PEO/SiC/BaTiO3 newly quaternary nanostructures for optical and quantum electronics fields

Authors: Hiba Kamil Jaafar, Ahmed Hashim, Bahaa H. Rabee

Published in: Optical and Quantum Electronics | Issue 11/2023

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Abstract

This study objects to synthesize of silicon carbide (SiC)/barium titanate (BaTiO₃) nanostructures doped polymethylmethacrylate (PMMA)/polyethylene oxide (PEO) blend as a promising nanosystems to apply in photonics and optics applications with few cost, flexible, lightweight, and excellent optical properties compared to other nanosystems. The morphological and optical properties of PMMA/PEO/SiC/BaTiO₃ nanostructures were explored. The morphology of films surface for PMMA/PEO/SiC/BaTiO₃ nanostructures was investigated by optical microscope(OM) and scanning electron microscope (SEM). The optical characteristics were examined at wavelength range from 240 to 840 nm. The OM and SEM analysis were indicated to the excellent homogeneous of SiC/BaTiO₃ NPs within the PMMA/PEO matrix. The optical characteristics of PMMA/PEO/SiC/BaTiO₃ nanostructures demonstrated that the absorbance(A) increased of 45.7% at UV-λ = 280 nm, 53.3 at VIS-λ = 480 nm and 57.4% at IR-λ = 780 nm when the content of SiC/BaTiO₃ NPs reached of 6.4 wt.%. The energy band gap decreased for allowed from 3.4 to 1.9 eV and from 2.8 to 1.7 eV for forbidden indirect transitions. The other optical parameters: absorption coefficient (α), extinction coefficient (k), refractive index (n), real (ε₁) and imaginary(ε₂) parts of dielectric constants and optical conductivity (σ_op) of PMMA/PEO blend enhanced with rising of the SiC/BaTiO₃ NPs, this performance lead to create the PMMA/PEO/SiC/BaTiO₃ nanostructures as a superior optical nanomaterials for optical and electronics approaches. Finally, the excellent obtained results make the PMMA/PEO/SiC/BaTiO₃ nanostructures are welcomed in various optical and photonics devices.

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Title: Fabrication and tuning the morphological and optical characteristics of PMMA/PEO/SiC/BaTiO3 newly quaternary nanostructures for optical and quantum electronics fields
Authors: Hiba Kamil Jaafar
Ahmed Hashim
Bahaa H. Rabee
Publication date: 01-11-2023
Publisher: Springer US
Published in: Optical and Quantum Electronics / Issue 11/2023
Print ISSN: 0306-8919
Electronic ISSN: 1572-817X
DOI: https://doi.org/10.1007/s11082-023-05208-7

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