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Metallurgical and Materials Transactions A
Published in: Metallurgical and Materials Transactions A 3/2019

01-01-2019

Fabrication of Metal-Doped Hierarchical Trimodal Porous Li3V2(PO4)3/C Composites with Enhanced Electrochemical Performances for Lithium-Ion Batteries

Authors: He Wang, Longfang Li, Shulan Wang, Xuan Liu, Li Li

Published in: Metallurgical and Materials Transactions A | Issue 3/2019

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Abstract

Na/Cr-doped Li3V2(PO4)3/C composites with a hierarchical trimodal porous structure, including micro-, meso-, and macropores, are synthesized by a feasible ice-templating method and investigated as cathodes for lithium-ion batteries (LIBs). Na and Cr doping decrease the charge transfer resistance of Li3V2(PO4)3/C and increase the diffusion coefficient of Li ions within the three-dimensional interconnected network, resulting in enhancement of both the capacity and rate performances of hierarchical porous Li3V2(PO4)3/C with maximized electrochemical performances at a doping level of x = 0.04. Cr doping shows a higher enhancement than Na in the capacity of Li3V2(PO4)3. As-prepared Cr-doped Li3V1.96Cr0.04(PO4)3/C shows the high capacity and rate performance of 116.8 mAh g−1 at 10 C as well as an excellent cyclability. This work provides a simple and feasible method to fabricate metal-doped hierarchical trimodal porous cathode materials and deepens our understanding on design of high-performance electrode materials for LIBs.
previous article Quantifying Void Formation and Changes to Microstructure During Hydrogen Charging: A Precursor to Embrittlement and Blistering
next article Modeling Microstructure Evolution in a Martensitic Stainless Steel Subjected to Hot Working Using a Physically Based Model

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Appendix
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Metadata
Title
Fabrication of Metal-Doped Hierarchical Trimodal Porous Li3V2(PO4)3/C Composites with Enhanced Electrochemical Performances for Lithium-Ion Batteries
Authors
He Wang
Longfang Li
Shulan Wang
Xuan Liu
Li Li
Publication date
01-01-2019
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 3/2019
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-018-5075-4

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