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2018 | OriginalPaper | Chapter

1. Flame Retardant Biobased Polymers

Authors : Rodolphe Sonnier, Aurélie Taguet, Laurent Ferry, José-Marie Lopez-Cuesta

Published in: Towards Bio-based Flame Retardant Polymers

Publisher: Springer International Publishing

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Abstract

Environmental concerns arising from the limits to the waste management of plastics have entailed a strong development of biobased and biodegradable polymers for a wide range of applications. Tailoring new plastics and composites within a perspective of sustainable development aims to create an environmentally safe alternative to oil based polymer materials. Different categories of these polymers can be distinguished according to their complete or only partial renewable character as well as their ability to biodegrade.

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Literature
1.
go back to reference Shen L, Haufe J, Patel MK (2009) Product overview and market projection of emerging bio-based plastics. Utrecht University, www.epnoe.eu Shen L, Haufe J, Patel MK (2009) Product overview and market projection of emerging bio-based plastics. Utrecht University, www.​epnoe.​eu
3.
go back to reference Alongi J, Han Z, Bourbigot S (2015) Intumescence: tradition versus novelty. A comprehensive review. Prog Polym Sci 51:28–73CrossRef Alongi J, Han Z, Bourbigot S (2015) Intumescence: tradition versus novelty. A comprehensive review. Prog Polym Sci 51:28–73CrossRef
4.
go back to reference Reti C, Casetta M, Duquesne S, Bourbigot S, Delobel R (2008) Flammability properties of intumescent PLA including starch and lignin. Polym Adv Technol 19:628–635CrossRef Reti C, Casetta M, Duquesne S, Bourbigot S, Delobel R (2008) Flammability properties of intumescent PLA including starch and lignin. Polym Adv Technol 19:628–635CrossRef
5.
go back to reference Wang X, Hu Y, Song L, Xuan S, Xing W, Bai Z, Lu H (2011) Flame retardancy and thermal degradation of intumescent flame retardant poly(lactic acid)/starch, biocomposites. Ind Eng Chem Res 50:713–720CrossRef Wang X, Hu Y, Song L, Xuan S, Xing W, Bai Z, Lu H (2011) Flame retardancy and thermal degradation of intumescent flame retardant poly(lactic acid)/starch, biocomposites. Ind Eng Chem Res 50:713–720CrossRef
6.
go back to reference Wu K, Hu Y, Song L, Lu HD, Wang ZZ (2009) Flame retardancy and thermal degradation of intumescent flame retardant starch-based biodegradable composites. Ind Eng Chem Res 48:3150–3157CrossRef Wu K, Hu Y, Song L, Lu HD, Wang ZZ (2009) Flame retardancy and thermal degradation of intumescent flame retardant starch-based biodegradable composites. Ind Eng Chem Res 48:3150–3157CrossRef
7.
go back to reference Lyon RE, Walters RN (2004) Pyrolysis combustion flow calorimetry. J Anal Appl Pyrol 71:27–46CrossRef Lyon RE, Walters RN (2004) Pyrolysis combustion flow calorimetry. J Anal Appl Pyrol 71:27–46CrossRef
8.
go back to reference Cayla A, Rault F, Giraud S, Salaün F, Fierro V, Celzard A (2016) PLA with intumescent system containing lignin and ammonium polyphosphate for flame retardant textile. Polymers 8:331–346CrossRef Cayla A, Rault F, Giraud S, Salaün F, Fierro V, Celzard A (2016) PLA with intumescent system containing lignin and ammonium polyphosphate for flame retardant textile. Polymers 8:331–346CrossRef
9.
go back to reference Zhang R, Xiao X, Tai Q, Huang H, Yang J, Hu Y (2012) Preparation of lignin–silica hybrids and its application in intumescent flame-retardant poly(lactic acid) system. High Perform Polym 24:738–746CrossRef Zhang R, Xiao X, Tai Q, Huang H, Yang J, Hu Y (2012) Preparation of lignin–silica hybrids and its application in intumescent flame-retardant poly(lactic acid) system. High Perform Polym 24:738–746CrossRef
10.
go back to reference Zhang X, Xiao Q, Tai H, Huang J, Yang YHu (2013) The effect of different organic modified montmorillonites (OMMTs) on the thermal properties and flammability of PLA/MCAPP/lignin systems. J Appl Polym Sci 127:4967–4973CrossRef Zhang X, Xiao Q, Tai H, Huang J, Yang YHu (2013) The effect of different organic modified montmorillonites (OMMTs) on the thermal properties and flammability of PLA/MCAPP/lignin systems. J Appl Polym Sci 127:4967–4973CrossRef
11.
go back to reference Morgan A, Wilkie CA (eds) (2010) Multicomponents FR systems: polymer nanocomposites combined with additional materials. In: Fire retardancy of polymeric materials. CRC Press (Chap. 12) Morgan A, Wilkie CA (eds) (2010) Multicomponents FR systems: polymer nanocomposites combined with additional materials. In: Fire retardancy of polymeric materials. CRC Press (Chap. 12)
12.
go back to reference Fontaine G, Bourbigot S (2009) Intumescent polylactide: a nonflammable material. J Appl Polym Sci 113:3860–3865CrossRef Fontaine G, Bourbigot S (2009) Intumescent polylactide: a nonflammable material. J Appl Polym Sci 113:3860–3865CrossRef
13.
go back to reference Matusinovic Z, Wilkie CA (2012) Fire retardancy and morphology of layered double hydroxide nanocomposites: a review. J Mater Chem 22:18701–18704CrossRef Matusinovic Z, Wilkie CA (2012) Fire retardancy and morphology of layered double hydroxide nanocomposites: a review. J Mater Chem 22:18701–18704CrossRef
14.
go back to reference Wang X, Zhou S, Xing WY, Yu B, Feng XM, Song L, Hu Y (2013) Self-assembly of Ni–Fe layered double hydroxide/graphene hybrids for reducing fire hazard in epoxy composites. J Mater Chem A 1:4383–4390CrossRef Wang X, Zhou S, Xing WY, Yu B, Feng XM, Song L, Hu Y (2013) Self-assembly of Ni–Fe layered double hydroxide/graphene hybrids for reducing fire hazard in epoxy composites. J Mater Chem A 1:4383–4390CrossRef
15.
go back to reference Dasari A, Yu ZZ, Cai GP, Mai YW (2013) Recent developments in the fire retardancy of polymeric materials. Prog Polym Sci 38:1357–1387CrossRef Dasari A, Yu ZZ, Cai GP, Mai YW (2013) Recent developments in the fire retardancy of polymeric materials. Prog Polym Sci 38:1357–1387CrossRef
16.
go back to reference Wang DY, Leuteritz A, Wang Y-Z, Wagenknecht U, Heinrich G (2010) Preparation and burning behaviors of flame retarding biodegradable poly(lactic acid) nanocomposite based on zinc aluminum layered double hydroxide. Polym Deg Stab 95:2474–2480CrossRef Wang DY, Leuteritz A, Wang Y-Z, Wagenknecht U, Heinrich G (2010) Preparation and burning behaviors of flame retarding biodegradable poly(lactic acid) nanocomposite based on zinc aluminum layered double hydroxide. Polym Deg Stab 95:2474–2480CrossRef
17.
go back to reference Sue HJ, Gam KT (2004) Epoxy nanocomposites based on the synthetic α-zirconium phosphate layer structure. Chem Mater 16:242–249CrossRef Sue HJ, Gam KT (2004) Epoxy nanocomposites based on the synthetic α-zirconium phosphate layer structure. Chem Mater 16:242–249CrossRef
18.
go back to reference Zhang R, Hu Y, Li BG, Chen ZY, Fan WC (2007) Studies on the preparation and structure of polyacrylamide/α-zirconium phosphate nanocomposites. J Mater Sci 42:5641–5646CrossRef Zhang R, Hu Y, Li BG, Chen ZY, Fan WC (2007) Studies on the preparation and structure of polyacrylamide/α-zirconium phosphate nanocomposites. J Mater Sci 42:5641–5646CrossRef
19.
go back to reference Liu CH, Yang YJ (2009) Effects of α-zirconium phosphate aspect ratio on the properties of polyvinyl alcohol nanocomposites. Polym Test 28:801–807CrossRef Liu CH, Yang YJ (2009) Effects of α-zirconium phosphate aspect ratio on the properties of polyvinyl alcohol nanocomposites. Polym Test 28:801–807CrossRef
20.
go back to reference Wang DY, Liu XQ, Wang JS, Wang YZ, Stec AA, Hull TR (2009) Preparation and characterization of a novel fire retardant PET/α-zirconium phosphate nanocomposite. Polym Degrad Stab 94:544–549CrossRef Wang DY, Liu XQ, Wang JS, Wang YZ, Stec AA, Hull TR (2009) Preparation and characterization of a novel fire retardant PET/α-zirconium phosphate nanocomposite. Polym Degrad Stab 94:544–549CrossRef
21.
go back to reference Liu XQ, Wang DY, Wang XL, Chen L, Wang YZ (2011) Synthesis of organo-modified α-zirconium phosphate and its effect on the flame retardancy of IFR poly(lactic acid) systems. Polym Deg Stab 96:771–777CrossRef Liu XQ, Wang DY, Wang XL, Chen L, Wang YZ (2011) Synthesis of organo-modified α-zirconium phosphate and its effect on the flame retardancy of IFR poly(lactic acid) systems. Polym Deg Stab 96:771–777CrossRef
22.
go back to reference Hu XP, Li WY, Wang YZ (2004) Synthesis and characterization of a novel nitrogen containing flame retardant. J Appl Polym Sci 94:1556–1561CrossRef Hu XP, Li WY, Wang YZ (2004) Synthesis and characterization of a novel nitrogen containing flame retardant. J Appl Polym Sci 94:1556–1561CrossRef
23.
go back to reference Vahabi H, Ferry L, Longuet C, Otazaghine B, Negrell-Guirao C, David G, Lopez-Cuesta J-M (2012) Combination effect of polyhedral oligomeric silsesquioxane (POSS) and a phosphorus modified PMMA, flammability and thermal stability properties. Mater Chem Phys 136:762–770CrossRef Vahabi H, Ferry L, Longuet C, Otazaghine B, Negrell-Guirao C, David G, Lopez-Cuesta J-M (2012) Combination effect of polyhedral oligomeric silsesquioxane (POSS) and a phosphorus modified PMMA, flammability and thermal stability properties. Mater Chem Phys 136:762–770CrossRef
24.
go back to reference Didane N, Giraud S, Devaux E, Lemort G (2012) A comparative study of POSS as synergists with zinc phosphinates for PET fire retardancy. Polym Degrad Stab 97:383–391CrossRef Didane N, Giraud S, Devaux E, Lemort G (2012) A comparative study of POSS as synergists with zinc phosphinates for PET fire retardancy. Polym Degrad Stab 97:383–391CrossRef
25.
go back to reference Fox DM, Lee J, Citro CJ, Novy M (2013) Flame retarded poly(lactic acid) using POSS-modified cellulose. 1. Thermal and combustion properties of intumescing composites. Polym Degrad Stab 98:590–596CrossRef Fox DM, Lee J, Citro CJ, Novy M (2013) Flame retarded poly(lactic acid) using POSS-modified cellulose. 1. Thermal and combustion properties of intumescing composites. Polym Degrad Stab 98:590–596CrossRef
26.
go back to reference Fox DM, Novy M, Brown K, Zammarano M, Harris RH, Murariu M, McCarthy ED, Seppala JE, Gilman JW (2014) Flame retarded poly(lactic acid) using POSS-modified cellulose. 2. Effects of intumescing flame retardant formulations on polymer degradation and composite physical properties. Polym Degrad Stab 106:54–62CrossRef Fox DM, Novy M, Brown K, Zammarano M, Harris RH, Murariu M, McCarthy ED, Seppala JE, Gilman JW (2014) Flame retarded poly(lactic acid) using POSS-modified cellulose. 2. Effects of intumescing flame retardant formulations on polymer degradation and composite physical properties. Polym Degrad Stab 106:54–62CrossRef
27.
go back to reference Gao L, Zheng G, Zhou Y, Hu L, Feng G, Zhang M (2014) Synergistic effect of expandable graphite, diethyl ethylphosphonate and organically-modified layered double hydroxide on flame retardancy and fire behavior of polyisocyanurate-polyurethane foam nanocomposite. Polym Degrad Stab 101:92–101CrossRef Gao L, Zheng G, Zhou Y, Hu L, Feng G, Zhang M (2014) Synergistic effect of expandable graphite, diethyl ethylphosphonate and organically-modified layered double hydroxide on flame retardancy and fire behavior of polyisocyanurate-polyurethane foam nanocomposite. Polym Degrad Stab 101:92–101CrossRef
28.
go back to reference Murariu M, Dechief AL, Bonnaud L, Paint Y, Gallos A, Fontaine G, Bourbigot S, Dubois P (2010) The production and properties of polylactide composites filled with expanded graphite. Polym Degrad Stab 95:889–900CrossRef Murariu M, Dechief AL, Bonnaud L, Paint Y, Gallos A, Fontaine G, Bourbigot S, Dubois P (2010) The production and properties of polylactide composites filled with expanded graphite. Polym Degrad Stab 95:889–900CrossRef
29.
go back to reference Zhu H, Zhu Q, Li J, Tao K, Xue L, Yan Q (2011) Synergistic effect between expandable graphite and ammonium polyphosphate on flame retarded polylactide. Polym Degrad Stab 96:183–189CrossRef Zhu H, Zhu Q, Li J, Tao K, Xue L, Yan Q (2011) Synergistic effect between expandable graphite and ammonium polyphosphate on flame retarded polylactide. Polym Degrad Stab 96:183–189CrossRef
30.
go back to reference Laachachi A, Cochez M, Leroy E, Gaudon P, Ferriol M, Lopez Cuesta JM (2006) Effect of Al2O3 and TiO2 nanoparticles and APP on thermal stability and flame retardance of PMMA. Polym Adv Technol 17:327–334CrossRef Laachachi A, Cochez M, Leroy E, Gaudon P, Ferriol M, Lopez Cuesta JM (2006) Effect of Al2O3 and TiO2 nanoparticles and APP on thermal stability and flame retardance of PMMA. Polym Adv Technol 17:327–334CrossRef
31.
go back to reference Feng C, Liang M, Zhang Y, Jiang J, Huang J, Liu H (2016) Synergistic effect of lanthanum oxide on the flame retardant properties and mechanism of an intumescent flame retardant PLA composites. J Anal Appl Pyrol 122:241–248CrossRef Feng C, Liang M, Zhang Y, Jiang J, Huang J, Liu H (2016) Synergistic effect of lanthanum oxide on the flame retardant properties and mechanism of an intumescent flame retardant PLA composites. J Anal Appl Pyrol 122:241–248CrossRef
32.
go back to reference Yang HE, Chapin JT, Gandhi P, Lackhouse T (2013) Micro-scale evaluation of flammability for cable materials. In: Proceeding of 62th international wire & cable symposium Yang HE, Chapin JT, Gandhi P, Lackhouse T (2013) Micro-scale evaluation of flammability for cable materials. In: Proceeding of 62th international wire & cable symposium
33.
go back to reference Ke CH, Li J, Fang KY, Zhu Q-L, Zhu J, Yan Q, Wang YZ (2010) Synergistic effect between a novel hyperbranched charring agent and ammonium polyphosphate on the flame retardant and anti-dripping properties of polylactide. Polym Degrad Stab 95:763–770CrossRef Ke CH, Li J, Fang KY, Zhu Q-L, Zhu J, Yan Q, Wang YZ (2010) Synergistic effect between a novel hyperbranched charring agent and ammonium polyphosphate on the flame retardant and anti-dripping properties of polylactide. Polym Degrad Stab 95:763–770CrossRef
34.
go back to reference Shabanian M, Kang NJ, Wang DY, Wagenknecht U, Heinrich G (2013) Synthesis of aromatic aliphatic polyamide acting as adjuvant in polylactic acid (PLA)/ammonium polyphosphate (APP) system. Polym Degrad Stab 98:1036–1042CrossRef Shabanian M, Kang NJ, Wang DY, Wagenknecht U, Heinrich G (2013) Synthesis of aromatic aliphatic polyamide acting as adjuvant in polylactic acid (PLA)/ammonium polyphosphate (APP) system. Polym Degrad Stab 98:1036–1042CrossRef
35.
go back to reference Bocz K, Domonkos M, Igricz T, Kmetty Á, Bárány T, Marosi G (2015) Flame retarded self-reinforced poly(lactic acid) composites of outstanding impact resistance. Compos A 70:27–34CrossRef Bocz K, Domonkos M, Igricz T, Kmetty Á, Bárány T, Marosi G (2015) Flame retarded self-reinforced poly(lactic acid) composites of outstanding impact resistance. Compos A 70:27–34CrossRef
36.
go back to reference Carosio F, Laufer G, Alongi J, Camino G, Grunlan JA (2011) Layer-by-layer assembly of silica-based flame retardant thin film on PET fabric. Polym Degrad Stab 96:745–750CrossRef Carosio F, Laufer G, Alongi J, Camino G, Grunlan JA (2011) Layer-by-layer assembly of silica-based flame retardant thin film on PET fabric. Polym Degrad Stab 96:745–750CrossRef
37.
go back to reference Garlotta DA (2001) A literature review of poly(lactic acid). J Polym Environ 9:63–84CrossRef Garlotta DA (2001) A literature review of poly(lactic acid). J Polym Environ 9:63–84CrossRef
38.
go back to reference Jing J, Zhang Y, Tang X, Zhou Y, Li X, Kandola BK, Fang Z (2017) Layer by layer deposition of polyethylenimine and bio-based polyphosphate on ammonium polyphosphate: A novel hybrid for simultaneously improving the flame retardancy and toughness of polylactic acid. Polymer 108:361–371CrossRef Jing J, Zhang Y, Tang X, Zhou Y, Li X, Kandola BK, Fang Z (2017) Layer by layer deposition of polyethylenimine and bio-based polyphosphate on ammonium polyphosphate: A novel hybrid for simultaneously improving the flame retardancy and toughness of polylactic acid. Polymer 108:361–371CrossRef
39.
go back to reference Levchik SV, Costa L, Camino G (1992) Effect of the fire-retardant, ammonium polyphosphate, on the thermal decomposition on of aliphatic polyamides. I. Polyamides 11 and 12. Polym Degrad Stab 36:31–41CrossRef Levchik SV, Costa L, Camino G (1992) Effect of the fire-retardant, ammonium polyphosphate, on the thermal decomposition on of aliphatic polyamides. I. Polyamides 11 and 12. Polym Degrad Stab 36:31–41CrossRef
40.
go back to reference Dorez G, Taguet A, Ferry L, Lopez-Cuesta JM (2013) Thermal and fire behavior of natural fibers/PBS biocomposites. Polym Degrad Stab 98:87–95CrossRef Dorez G, Taguet A, Ferry L, Lopez-Cuesta JM (2013) Thermal and fire behavior of natural fibers/PBS biocomposites. Polym Degrad Stab 98:87–95CrossRef
41.
go back to reference Dumazert L, Rasselet D, Pang B, Gallard B, Kennouche S, Lopez-Cuesta J-M. Thermal stability and fire reaction of poly(butylene succinate) nanocomposites using natural clays and FR additives. Polym Adv Technol (accepted) Dumazert L, Rasselet D, Pang B, Gallard B, Kennouche S, Lopez-Cuesta J-M. Thermal stability and fire reaction of poly(butylene succinate) nanocomposites using natural clays and FR additives. Polym Adv Technol (accepted)
42.
go back to reference Wang X, Yang H, Song L, Hu Y, Xing W, Lu H (2011) Morphology, mechanical and thermal properties of graphene-reinforced poly(butylene succinate) nanocomposites. Compos Sci Technol 72:1–6CrossRef Wang X, Yang H, Song L, Hu Y, Xing W, Lu H (2011) Morphology, mechanical and thermal properties of graphene-reinforced poly(butylene succinate) nanocomposites. Compos Sci Technol 72:1–6CrossRef
43.
go back to reference Song L, Xuan S, Wang X, Hu Y (2012) Flame retardancy and thermal degradation behaviors of phosphate in combination with POSS in polylactide composites. Thermochim Acta 527:1–7CrossRef Song L, Xuan S, Wang X, Hu Y (2012) Flame retardancy and thermal degradation behaviors of phosphate in combination with POSS in polylactide composites. Thermochim Acta 527:1–7CrossRef
44.
go back to reference Murariu M, Dubois P (2016) PLA composites: from production to properties. Adv Drug Deliv Rev 107:17–46CrossRef Murariu M, Dubois P (2016) PLA composites: from production to properties. Adv Drug Deliv Rev 107:17–46CrossRef
45.
go back to reference Pack S, Bobo E, Muir N, Yang K, Swaraj S, Ade H, Cao C, Korach CS, Kashiwagi T, Rafailovich MH (2012) Engineering biodegradable polymer blends containing flame retardant-coated starch/nanoparticles. Polymer 53:4787–4799CrossRef Pack S, Bobo E, Muir N, Yang K, Swaraj S, Ade H, Cao C, Korach CS, Kashiwagi T, Rafailovich MH (2012) Engineering biodegradable polymer blends containing flame retardant-coated starch/nanoparticles. Polymer 53:4787–4799CrossRef
46.
go back to reference Ju Y, Liao F, Dai X, Cao Y, Li J, Wang X (2016) Flame-retarded biocomposites of poly(lactic acid), distiller’s dried grains with solubles and resorcinol di(phenyl phosphate). Compos A 81:52–60CrossRef Ju Y, Liao F, Dai X, Cao Y, Li J, Wang X (2016) Flame-retarded biocomposites of poly(lactic acid), distiller’s dried grains with solubles and resorcinol di(phenyl phosphate). Compos A 81:52–60CrossRef
47.
go back to reference Jing J, Zhang Y, Fang Z (2017) Diphenolic acid based biphosphate on the properties of polylactic acid: synthesis, fire behavior and flame retardant mechanism. Polymer 108:29–37CrossRef Jing J, Zhang Y, Fang Z (2017) Diphenolic acid based biphosphate on the properties of polylactic acid: synthesis, fire behavior and flame retardant mechanism. Polymer 108:29–37CrossRef
48.
go back to reference Chen X, Zhuo J, Jiao C (2012) Thermal degradation characteristics of flame retardant polylactide using TG-IR. Polym Degrad Stab 97:2143–2147CrossRef Chen X, Zhuo J, Jiao C (2012) Thermal degradation characteristics of flame retardant polylactide using TG-IR. Polym Degrad Stab 97:2143–2147CrossRef
49.
go back to reference Laachachi A, Cochez M, Leroy E, Ferriol M, Lopez-Cuesta JM (2007) Fire retardant systems in poly(methyl methacrylate): interactions between metal oxide nanoparticles and phosphinates. Polym Degrad Stab 92:61–69CrossRef Laachachi A, Cochez M, Leroy E, Ferriol M, Lopez-Cuesta JM (2007) Fire retardant systems in poly(methyl methacrylate): interactions between metal oxide nanoparticles and phosphinates. Polym Degrad Stab 92:61–69CrossRef
50.
go back to reference Braun U, Schartel B, Ficher MA, Jäger C (2007) Flame retardancy mechanisms of aluminium phosphinate in combination with melamine polyphosphate and zinc borate in glass-fibre reinforced polyamide 6,6. Polym Degrad Stab 92:1528–1545CrossRef Braun U, Schartel B, Ficher MA, Jäger C (2007) Flame retardancy mechanisms of aluminium phosphinate in combination with melamine polyphosphate and zinc borate in glass-fibre reinforced polyamide 6,6. Polym Degrad Stab 92:1528–1545CrossRef
51.
go back to reference Braun U, Schartel B (2008) Flame retardancy mechanisms of aluminium phosphinate in combination with melamine cyanurate in glass-fibre-reinforced poly(1,4-butylene terephthalate). Macromol Mater Eng 293:206–217CrossRef Braun U, Schartel B (2008) Flame retardancy mechanisms of aluminium phosphinate in combination with melamine cyanurate in glass-fibre-reinforced poly(1,4-butylene terephthalate). Macromol Mater Eng 293:206–217CrossRef
52.
go back to reference Bourbigot S, Fontaine G (2010) Flame retardancy of polylactide: an overview. Polym Chem 1:1413–1422CrossRef Bourbigot S, Fontaine G (2010) Flame retardancy of polylactide: an overview. Polym Chem 1:1413–1422CrossRef
53.
go back to reference Isitman NA, Dogan M, Bayramli E, Kaynak C (2012) The role of nanoparticle geometry in flame retardancy of polylactide nanocomposites containing aluminium phosphinate. Polym Degrad Stab 97:1285–1296CrossRef Isitman NA, Dogan M, Bayramli E, Kaynak C (2012) The role of nanoparticle geometry in flame retardancy of polylactide nanocomposites containing aluminium phosphinate. Polym Degrad Stab 97:1285–1296CrossRef
54.
go back to reference Lin HJ, Liu SR, Han LJ, Wang XM, Bian YJ, Dong LS (2013) Effect of a phosphorus-containing oligomer on flame-retardant, rheological and mechanical properties of poly (lactic acid). Polym Degrad Stab 98:1389–1396CrossRef Lin HJ, Liu SR, Han LJ, Wang XM, Bian YJ, Dong LS (2013) Effect of a phosphorus-containing oligomer on flame-retardant, rheological and mechanical properties of poly (lactic acid). Polym Degrad Stab 98:1389–1396CrossRef
55.
go back to reference Avinc O, Day R, Carr C, Wilding M (2012) Effect of combined flame retardant, liquid repellent and softener finishes on poly(lactic acid) (PLA) fabric performance. Text Res J 82:975–984CrossRef Avinc O, Day R, Carr C, Wilding M (2012) Effect of combined flame retardant, liquid repellent and softener finishes on poly(lactic acid) (PLA) fabric performance. Text Res J 82:975–984CrossRef
56.
go back to reference Cheng XW, Guan JP, Tang RC, Liu KQ (2016) Improvement of flame retardancy of poly(lactic acid) nonwoven fabric with a phosphorus containing flame retardant. J Ind Text 46:914–928CrossRef Cheng XW, Guan JP, Tang RC, Liu KQ (2016) Improvement of flame retardancy of poly(lactic acid) nonwoven fabric with a phosphorus containing flame retardant. J Ind Text 46:914–928CrossRef
57.
go back to reference Wei LL, Wang DY, Chen H-B, Chen L, Wang XL, Wang YZ (2011) Effect of a phosphorus-containing flame retardant on the thermal properties and ease of ignition of poly(lactic acid). Polym Degrad Stab 96:1557–1561CrossRef Wei LL, Wang DY, Chen H-B, Chen L, Wang XL, Wang YZ (2011) Effect of a phosphorus-containing flame retardant on the thermal properties and ease of ignition of poly(lactic acid). Polym Degrad Stab 96:1557–1561CrossRef
58.
go back to reference Wang DY, Song YP, Lin L, Wang XL, Wang YZ (2011) A novel phosphorus-containing poly(lactic acid) toward its flame retardation. Polymer 52:233–238CrossRef Wang DY, Song YP, Lin L, Wang XL, Wang YZ (2011) A novel phosphorus-containing poly(lactic acid) toward its flame retardation. Polymer 52:233–238CrossRef
59.
go back to reference Yuan XY, Wang DY, Chen L, Wang XL, Wang YZ (2011) Inherent flame retardation of bio-based poly(lactic acid) by incorporating phosphorus linked pendent group into the backbone. Polym Degrad Stab 96:1669–1675CrossRef Yuan XY, Wang DY, Chen L, Wang XL, Wang YZ (2011) Inherent flame retardation of bio-based poly(lactic acid) by incorporating phosphorus linked pendent group into the backbone. Polym Degrad Stab 96:1669–1675CrossRef
60.
go back to reference Zhan J, Song L, Nie S, Hua Y (2009) Combustion properties and thermal degradation behavior of polylactide with an effective intumescent flame retardant. Polym Degrad Stab 94:291–296CrossRef Zhan J, Song L, Nie S, Hua Y (2009) Combustion properties and thermal degradation behavior of polylactide with an effective intumescent flame retardant. Polym Degrad Stab 94:291–296CrossRef
61.
go back to reference Zhao X, Gao S, Liu G (2016) A THEIC-based polyphosphate melamine intumescent flame retardant and its flame retardancy properties for polylactide. J Anal Appl Pyrol 122:24–34CrossRef Zhao X, Gao S, Liu G (2016) A THEIC-based polyphosphate melamine intumescent flame retardant and its flame retardancy properties for polylactide. J Anal Appl Pyrol 122:24–34CrossRef
62.
go back to reference Liao F, Ju Y, Dai X, Cao Y, Li J, Wang X (2015) A novel efficient polymeric flame retardant for poly (lactic acid) (PLA): synthesis and its effects on flame retardancy and crystallization of PLA. Polym Degrad Stab 120:251–261CrossRef Liao F, Ju Y, Dai X, Cao Y, Li J, Wang X (2015) A novel efficient polymeric flame retardant for poly (lactic acid) (PLA): synthesis and its effects on flame retardancy and crystallization of PLA. Polym Degrad Stab 120:251–261CrossRef
63.
go back to reference Li Z, Wei P, Yang Y, Yan Y, Shi D (2014) Synthesis of a hyperbranched poly(phosphamide ester) oligomer and its high-effective flame retardancy and accelerated nucleation effect in polylactide composites. Polym Degrad Stab 110:104–112CrossRef Li Z, Wei P, Yang Y, Yan Y, Shi D (2014) Synthesis of a hyperbranched poly(phosphamide ester) oligomer and its high-effective flame retardancy and accelerated nucleation effect in polylactide composites. Polym Degrad Stab 110:104–112CrossRef
64.
go back to reference Tao K, Li J, Xu L, Zhao X, Xue L, Fan X, Yan Q (2011) A novel phosphazene cyclomatrix network polymer: design, synthesis and application in flame retardant polylactide. Polym Degrad Stab 96:1248–1254CrossRef Tao K, Li J, Xu L, Zhao X, Xue L, Fan X, Yan Q (2011) A novel phosphazene cyclomatrix network polymer: design, synthesis and application in flame retardant polylactide. Polym Degrad Stab 96:1248–1254CrossRef
65.
go back to reference Tang G, Wang X, Xing W, Zhang P, Wang B, Hong N, Yang W, Hu Y, Song L (2012) Thermal degradation and flame retardance of biobased polylactide composites based on aluminum hypophosphite. Ind Eng Chem Res 51:12009–12016CrossRef Tang G, Wang X, Xing W, Zhang P, Wang B, Hong N, Yang W, Hu Y, Song L (2012) Thermal degradation and flame retardance of biobased polylactide composites based on aluminum hypophosphite. Ind Eng Chem Res 51:12009–12016CrossRef
66.
go back to reference Tang G, Wang X, Zhang R, Wang B, Hong N, Hu Y, Song L, Gong X (2013) Effect of rare earth hypophosphite salts on the fire performance of biobased polylactide composites. Ind Eng Chem Res 52:7362–7372CrossRef Tang G, Wang X, Zhang R, Wang B, Hong N, Hu Y, Song L, Gong X (2013) Effect of rare earth hypophosphite salts on the fire performance of biobased polylactide composites. Ind Eng Chem Res 52:7362–7372CrossRef
67.
go back to reference Gallo E, Schartel B, Acierno D, Russo P (2011) Flame retardant biocomposites: synergism between phosphinate and nanometric metal oxides. Eur Polym J 47:1390–1401CrossRef Gallo E, Schartel B, Acierno D, Russo P (2011) Flame retardant biocomposites: synergism between phosphinate and nanometric metal oxides. Eur Polym J 47:1390–1401CrossRef
68.
go back to reference Bocz K, Szolnoki B, Wladyka-Przybylak M, Bujnowicz K, Harakaly G, Bodzay B (2013) Flame retardancy of biocomposites based on thermoplastic starch. Polimery 58:385–394CrossRef Bocz K, Szolnoki B, Wladyka-Przybylak M, Bujnowicz K, Harakaly G, Bodzay B (2013) Flame retardancy of biocomposites based on thermoplastic starch. Polimery 58:385–394CrossRef
69.
go back to reference Negrell C, Frenehard O, Sonnier R, Dumazert L, Briffaud T, Flat JJ (2016) Self-extinguishing bio-based polyamides. Polym Degrad Stab 134:10–18CrossRef Negrell C, Frenehard O, Sonnier R, Dumazert L, Briffaud T, Flat JJ (2016) Self-extinguishing bio-based polyamides. Polym Degrad Stab 134:10–18CrossRef
70.
go back to reference Lligadas G, Ronda JC, Galia M, Cadiz V (2006) Synthesis and Properties of thermosetting polymers from a phosphorus containing fatty acids derivative. J Polym Sci Part A: Polym Chem 44:5630–5644CrossRef Lligadas G, Ronda JC, Galia M, Cadiz V (2006) Synthesis and Properties of thermosetting polymers from a phosphorus containing fatty acids derivative. J Polym Sci Part A: Polym Chem 44:5630–5644CrossRef
71.
go back to reference Lligadas G, Ronda JC, Galia M, Cadiz V (2006) Synthesis and Properties of thermosetting polymers from a phosphorus containing fatty acids derivative. J Polym Sci Part A: Polym Chem 44:6717–6727CrossRef Lligadas G, Ronda JC, Galia M, Cadiz V (2006) Synthesis and Properties of thermosetting polymers from a phosphorus containing fatty acids derivative. J Polym Sci Part A: Polym Chem 44:6717–6727CrossRef
72.
go back to reference Montero de Espinoza L, Ronda JC, Galia M, Cadiz V (2009) A straightforward strategies for the efficient synthesis of acrylate and phosphine oxide-containing vegetable oils and their crosslinked materials. J Polym Sci Part A Polym Chem 47:4051–4063CrossRef Montero de Espinoza L, Ronda JC, Galia M, Cadiz V (2009) A straightforward strategies for the efficient synthesis of acrylate and phosphine oxide-containing vegetable oils and their crosslinked materials. J Polym Sci Part A Polym Chem 47:4051–4063CrossRef
73.
go back to reference Zhang L, Zhang M, Zhou Y, Hu L (2013) The study of mechanical behavior and flame retardancy of castor oil phosphate-based rigid polyurethane foam composites containing expanded graphite and triethyl phosphate. Polym Degrad Stab 98:2784–2794CrossRef Zhang L, Zhang M, Zhou Y, Hu L (2013) The study of mechanical behavior and flame retardancy of castor oil phosphate-based rigid polyurethane foam composites containing expanded graphite and triethyl phosphate. Polym Degrad Stab 98:2784–2794CrossRef
74.
go back to reference Liu XQ, Wang DY, Wang XL, Chen L, Wang YZ (2013) Synthesis of functionalized α-zirconium phosphate modified with intumescent flame retardant and its application in poly(lactic acid). Polym Degrad Stab 98:1731–1737CrossRef Liu XQ, Wang DY, Wang XL, Chen L, Wang YZ (2013) Synthesis of functionalized α-zirconium phosphate modified with intumescent flame retardant and its application in poly(lactic acid). Polym Degrad Stab 98:1731–1737CrossRef
75.
go back to reference Ding P, Kang B, Zhang J, Yang J, Song N, Tang S, Shi L (2015) Phosphorus-containing flame retardant modified layered double hydroxides and their applications on polylactide film with good transparency. J Coll Interf Sci 440:46–52CrossRef Ding P, Kang B, Zhang J, Yang J, Song N, Tang S, Shi L (2015) Phosphorus-containing flame retardant modified layered double hydroxides and their applications on polylactide film with good transparency. J Coll Interf Sci 440:46–52CrossRef
76.
go back to reference Hu Y, Xu P, Gui H, Wang X, Ding Y (2015) Effect of imidazolium phosphate and multiwalled carbon nanotubes on thermal stability and flame retardancy of polylactide. Compos A 77:147–153CrossRef Hu Y, Xu P, Gui H, Wang X, Ding Y (2015) Effect of imidazolium phosphate and multiwalled carbon nanotubes on thermal stability and flame retardancy of polylactide. Compos A 77:147–153CrossRef
77.
go back to reference Costes L, Laoutid F, Aguedo M, Richel A, Brohez S, Delvosalle C, Dubois P (2016) Phosphorus and nitrogen derivatization as efficient route for improvement of lignin flame retardant action in PLA. Eur Polym J 84:652–667CrossRef Costes L, Laoutid F, Aguedo M, Richel A, Brohez S, Delvosalle C, Dubois P (2016) Phosphorus and nitrogen derivatization as efficient route for improvement of lignin flame retardant action in PLA. Eur Polym J 84:652–667CrossRef
78.
go back to reference Costes L, Laoutid F, Khelifa F, Rose G, Brohez S, Delvosalle C, Dubois P (2016) Cellulose/phosphorus combinations for sustainable fire retarded polylactide. Eur Polym J 74:218–228CrossRef Costes L, Laoutid F, Khelifa F, Rose G, Brohez S, Delvosalle C, Dubois P (2016) Cellulose/phosphorus combinations for sustainable fire retarded polylactide. Eur Polym J 74:218–228CrossRef
79.
go back to reference Costes L, Laoutid F, Dumazert L, Lopez-Cuesta JM, Brohez S, Delvosalle C, Dubois P (2015) Metallic phytates as efficient bio-based phosphorous flame retardant additives for poly(lactic acid). Polym Degrad Stab 119:217–227CrossRef Costes L, Laoutid F, Dumazert L, Lopez-Cuesta JM, Brohez S, Delvosalle C, Dubois P (2015) Metallic phytates as efficient bio-based phosphorous flame retardant additives for poly(lactic acid). Polym Degrad Stab 119:217–227CrossRef
80.
go back to reference González A, Dasari A, Herrero B, Plancher E, Santarén J, Esteban A, Lim SH (2012) Fire retardancy behavior of PLA based nanocomposites. Polym Degrad Stab 97:248–256CrossRef González A, Dasari A, Herrero B, Plancher E, Santarén J, Esteban A, Lim SH (2012) Fire retardancy behavior of PLA based nanocomposites. Polym Degrad Stab 97:248–256CrossRef
81.
go back to reference Dhanushka Hapuarachchi T, Peijs T (2010) Multiwalled carbon nanotubes and sepiolite nanoclays as flame retardants for polylactide and its natural fibre reinforced composites. Compos A 41:954–963CrossRef Dhanushka Hapuarachchi T, Peijs T (2010) Multiwalled carbon nanotubes and sepiolite nanoclays as flame retardants for polylactide and its natural fibre reinforced composites. Compos A 41:954–963CrossRef
82.
go back to reference Ferry L, Gaudon P, Leroy E, Lopez-Cuesta JM (2005) Fire retardancy of polymers: new applications of mineral fillers. In: Le Bras M, Wilkie C, Bourbigot S, Duquesne S, Jama C (eds) Intumescence in ethylene-vinyl acetate copolymer filled with magnesium hydroxide and organoclays. The Royal Society of Chemistry, Oxford, pp 302–312 (chapter 22) Ferry L, Gaudon P, Leroy E, Lopez-Cuesta JM (2005) Fire retardancy of polymers: new applications of mineral fillers. In: Le Bras M, Wilkie C, Bourbigot S, Duquesne S, Jama C (eds) Intumescence in ethylene-vinyl acetate copolymer filled with magnesium hydroxide and organoclays. The Royal Society of Chemistry, Oxford, pp 302–312 (chapter 22)
83.
go back to reference Cheng KC, Yu C-B, Guo W, Wang SF, Chuang TH, Lin Y-H (2012) Thermal properties and flammability of polylactide nanocomposites with aluminum trihydrate and organoclay. Carbohydr Polym 87:1119–1123CrossRef Cheng KC, Yu C-B, Guo W, Wang SF, Chuang TH, Lin Y-H (2012) Thermal properties and flammability of polylactide nanocomposites with aluminum trihydrate and organoclay. Carbohydr Polym 87:1119–1123CrossRef
84.
go back to reference Cheng KC, Chang SC, Lin YH, Wang CC (2015) Mechanical and flame retardant properties of polylactide composites with hyperbranched polymers. Compos Sci Technol 118:186–192CrossRef Cheng KC, Chang SC, Lin YH, Wang CC (2015) Mechanical and flame retardant properties of polylactide composites with hyperbranched polymers. Compos Sci Technol 118:186–192CrossRef
85.
go back to reference Kiuchi Y, Iji M, Yanagisawa T, Shukichi T (2014) Flame-retarding polylactic-acid composite formed by dual use of aluminum hydroxide and phenol resin. Polym Degrad Stab 109:336–342CrossRef Kiuchi Y, Iji M, Yanagisawa T, Shukichi T (2014) Flame-retarding polylactic-acid composite formed by dual use of aluminum hydroxide and phenol resin. Polym Degrad Stab 109:336–342CrossRef
Metadata
Title
Flame Retardant Biobased Polymers
Authors
Rodolphe Sonnier
Aurélie Taguet
Laurent Ferry
José-Marie Lopez-Cuesta
Copyright Year
2018
DOI
https://doi.org/10.1007/978-3-319-67083-6_1

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