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Polymer Science, Series C

Published in:

30-09-2023

Functionalized Oligoaryloxycyclotriphosphazenes and Noncombustible Binders Based on Them

Authors: Yu. V. Bilichenko, Pham Van Thuan, R. S. Borisov, A. A. Kolenchenko, V. V. Kireev

Published in: Polymer Science, Series C | Issue 2/2023

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Abstract

Carboxyl-containing aryloxycyclotriphosphazene (I) has been used for curing the ED-20 epoxy resin or a phosphazene-containing epoxy oligomer. In the case of ED-20, curing occurs in the range of 125‒220°C and is accompanied by an exothermic effect that increases from 26 to 50 J/g with an increase in the amount of aryloxycyclotriphosphazene (I) from 25 to 50%. The curing of the phosphazene-containing epoxy oligomer occurs in the temperature range of 140–240°C and is accompanied by an endothermic effect (−ΔH = 6.5–6.8 J/g). Cured compositions based on ED-20 + I are self-extinguishing (flammability class V‑1 according to UL-94), and phosphazene-containing epoxy oligomer + I compositions are noncombustible (class V-0 according to UL-94) regardless of the ratio of the initial components.

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Title: Functionalized Oligoaryloxycyclotriphosphazenes and Noncombustible Binders Based on Them
Authors: Yu. V. Bilichenko
Pham Van Thuan
R. S. Borisov
A. A. Kolenchenko
V. V. Kireev
Publication date: 30-09-2023
Publisher: Pleiades Publishing
Published in: Polymer Science, Series C / Issue 2/2023
Print ISSN: 1811-2382
Electronic ISSN: 1555-614X
DOI: https://doi.org/10.1134/S1811238223700364

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