Skip to main content
Top
Published in: Journal of Nanoparticle Research 2/2017

01-02-2017 | Research Paper

GO@CuSilicate nano-needle arrays hierarchical structure: a new route to prepare high optical transparent, excellent self-cleaning and anticorrosion superhydrophobic surface

Authors: Ping Fan, Jingyi Chen, Jintao Yang, Feng Chen, Mingqiang Zhong

Published in: Journal of Nanoparticle Research | Issue 2/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Transparent superhydrophobic coatings, which are highly desired for the protection of material surfaces, have been limited to particular kinds of materials, e.g. silicon dioxide. In this work, a hybrid compound of graphene oxide and copper silicate with hierarchical structure was developed and was used to fabricate coatings. Due to the high transparency of graphene oxide and the nanoscopic roughness created by nanoneedles of CuSilicate, with very low compound loading (0.052 mg/cm2), the as-prepared coating was found not only showing superhydrophobic properties with a water contact angle (CA) of ∼152° and a near zero sliding angle (SA) of 0.5 but also showing high optical transparent (light transmittance is as high as 94.5 % at 500 nm). Furthermore, this surface also showed efficient anticorrosion properties and excellent self-cleaning ability. This study not only fabricated a new surface with transparency and surperhydrophobicity based on graphene materials, but also hopefully offers a method for the fabrication of multifunctional coatings.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Appendix
Available only for authorised users
Literature
go back to reference Ahmad YH, Tientong J, Nar M, D’Souza N, Mohamed AMA, Golden TD (2014) Characterization and corrosion resistance of electrodeposited Ni-Mo-silicate platelet nanocomposite coatings. Surf Coat Tech 259:517–525CrossRef Ahmad YH, Tientong J, Nar M, D’Souza N, Mohamed AMA, Golden TD (2014) Characterization and corrosion resistance of electrodeposited Ni-Mo-silicate platelet nanocomposite coatings. Surf Coat Tech 259:517–525CrossRef
go back to reference Bravo J, Zhai L, Wu ZZ, Cohen RE, Rubner MF (2007) Transparent superhydrophobic films based on silica nanoparticles. Langmuir 23:7293–7298CrossRef Bravo J, Zhai L, Wu ZZ, Cohen RE, Rubner MF (2007) Transparent superhydrophobic films based on silica nanoparticles. Langmuir 23:7293–7298CrossRef
go back to reference Calizo I, Balandin AA, Bao W, Miao F, Lau CN (2007) Temperature dependence of the raman spectra of graphene and graphene multilayers. Nano Lett 7:2645–2649CrossRef Calizo I, Balandin AA, Bao W, Miao F, Lau CN (2007) Temperature dependence of the raman spectra of graphene and graphene multilayers. Nano Lett 7:2645–2649CrossRef
go back to reference Chen W, Fadeev AY, Hsieh MC, Oner D, Youngblood J, McCarthy TJ (1999) Ultrahydrophobic and ultralyophobic surfaces: some comments and examples. Langmuir 15:3395–3399CrossRef Chen W, Fadeev AY, Hsieh MC, Oner D, Youngblood J, McCarthy TJ (1999) Ultrahydrophobic and ultralyophobic surfaces: some comments and examples. Langmuir 15:3395–3399CrossRef
go back to reference Choi BG, Park HS (2012) Superhydrophobic graphene/nafion nanohybrid films with hierarchical roughness. J Phys Chem C 116:3207–3211CrossRef Choi BG, Park HS (2012) Superhydrophobic graphene/nafion nanohybrid films with hierarchical roughness. J Phys Chem C 116:3207–3211CrossRef
go back to reference Cote LJ, Kim F, Huang JX (2009) Langmuir-Blodgett assembly of graphite oxide single layers. J Am Chem Soc 131:1043–1049CrossRef Cote LJ, Kim F, Huang JX (2009) Langmuir-Blodgett assembly of graphite oxide single layers. J Am Chem Soc 131:1043–1049CrossRef
go back to reference Duch MC, Budinger GRS, Liang YT, Soberanes S, Urich D, Chiarella SE, Campochiaro LA, Gonzalez A, Chandel NS, Hersam MC, Mutlu GM (2011) Minimizing oxidation and stable nanoscale dispersion improves the biocompatibility of graphene in the lung. Nano Lett 11:5201–5207CrossRef Duch MC, Budinger GRS, Liang YT, Soberanes S, Urich D, Chiarella SE, Campochiaro LA, Gonzalez A, Chandel NS, Hersam MC, Mutlu GM (2011) Minimizing oxidation and stable nanoscale dispersion improves the biocompatibility of graphene in the lung. Nano Lett 11:5201–5207CrossRef
go back to reference Fang QL, Xuan SH, Jiang WQ, Gong XL (2011) Yolk-like micro/nanoparticles with superparamagnetic iron oxide cores and hierarchical nickel silicate shells. Adv Funct Mater 21:1902–1909CrossRef Fang QL, Xuan SH, Jiang WQ, Gong XL (2011) Yolk-like micro/nanoparticles with superparamagnetic iron oxide cores and hierarchical nickel silicate shells. Adv Funct Mater 21:1902–1909CrossRef
go back to reference Feng L, Li SH, Li YS, Li HJ, Zhang LJ, Zhai J, Song YL, Liu BQ, Jiang L, Zhu DB (2002) Super-hydrophobic surfaces: from natural to artificial. Adv Mater 14:1857–1860CrossRef Feng L, Li SH, Li YS, Li HJ, Zhang LJ, Zhai J, Song YL, Liu BQ, Jiang L, Zhu DB (2002) Super-hydrophobic surfaces: from natural to artificial. Adv Mater 14:1857–1860CrossRef
go back to reference Feng L, Song YL, Zhai J, Liu BQ, Xu J, Jiang L, Zhu DB (2003) Creation of a superhydrophobic surface from an amphiphilic polymer. Angew Chem Int Edit 42:800–802CrossRef Feng L, Song YL, Zhai J, Liu BQ, Xu J, Jiang L, Zhu DB (2003) Creation of a superhydrophobic surface from an amphiphilic polymer. Angew Chem Int Edit 42:800–802CrossRef
go back to reference Gomez-Navarro C, Burghard M, Kern K (2008) Elastic properties of chemically derived single graphene sheets. Nano Lett 8:2045–2049CrossRef Gomez-Navarro C, Burghard M, Kern K (2008) Elastic properties of chemically derived single graphene sheets. Nano Lett 8:2045–2049CrossRef
go back to reference Gong MG, Yang Z, Xu XL, Jasion D, Mou S, Zhang HD, Long YZ, Ren SQ (2014) Superhydrophobicity of hierarchical ZnO nanowire coatings. J Mater Chem A 2:6180–6184CrossRef Gong MG, Yang Z, Xu XL, Jasion D, Mou S, Zhang HD, Long YZ, Ren SQ (2014) Superhydrophobicity of hierarchical ZnO nanowire coatings. J Mater Chem A 2:6180–6184CrossRef
go back to reference Goswami D, Medda SK, De G (2011) Superhydrophobic films on glass surface derived from trimethylsilanized silica gel nanoparticles. ACS Appl Mater Inter 3:3440–3447CrossRef Goswami D, Medda SK, De G (2011) Superhydrophobic films on glass surface derived from trimethylsilanized silica gel nanoparticles. ACS Appl Mater Inter 3:3440–3447CrossRef
go back to reference Gould P (2003) Smart, clean surfaces. Materials Today 6:44–48 Gould P (2003) Smart, clean surfaces. Materials Today 6:44–48
go back to reference Hamdy AS (2006) Corrosion protection of aluminum composites by silicate/cerate conversion coating. Surf Coat Tech 200:3786–3792CrossRef Hamdy AS (2006) Corrosion protection of aluminum composites by silicate/cerate conversion coating. Surf Coat Tech 200:3786–3792CrossRef
go back to reference Han JT, Kim SY, Woo JS, Lee GW (2008) Transparent, conductive, and superhydrophobic films from stabilized carbon nanotube/silane sol mixture solution. Adv Mater 20:3724–3727CrossRef Han JT, Kim SY, Woo JS, Lee GW (2008) Transparent, conductive, and superhydrophobic films from stabilized carbon nanotube/silane sol mixture solution. Adv Mater 20:3724–3727CrossRef
go back to reference Honeychuck RV, Tai H, Wynne KJ, Nissan RA (2002) Preparation and characterization of polyurethanes based on a series of fluorinated diols. Chem Mater 5:1299–1306CrossRef Honeychuck RV, Tai H, Wynne KJ, Nissan RA (2002) Preparation and characterization of polyurethanes based on a series of fluorinated diols. Chem Mater 5:1299–1306CrossRef
go back to reference Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRef Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRef
go back to reference Karunakaran RG, Lu CH, Zhang ZH, Yang S (2011) Highly transparent superhydrophobic surfaces from the coassembly of nanoparticles (≤ 100 nm). Langmuir 27:4594–4602CrossRef Karunakaran RG, Lu CH, Zhang ZH, Yang S (2011) Highly transparent superhydrophobic surfaces from the coassembly of nanoparticles (≤ 100 nm). Langmuir 27:4594–4602CrossRef
go back to reference Li JA, Liu XH, Ye YP, Zhou HD, Chen JM (2011) Fabrication of superhydrophobic cuo surfaces with tunable water adhesion. J Phys Chem C 115:4726–4729CrossRef Li JA, Liu XH, Ye YP, Zhou HD, Chen JM (2011) Fabrication of superhydrophobic cuo surfaces with tunable water adhesion. J Phys Chem C 115:4726–4729CrossRef
go back to reference Li F, Du M, Zheng Z, Song YH, Zheng Q (2015) A facile, multifunctional, transparent, and superhydrophobic coating based on a nanoscale porous structure spontaneously assembled from branched silica nanoparticles. Adv Mater Interfaces 2:1500201CrossRef Li F, Du M, Zheng Z, Song YH, Zheng Q (2015) A facile, multifunctional, transparent, and superhydrophobic coating based on a nanoscale porous structure spontaneously assembled from branched silica nanoparticles. Adv Mater Interfaces 2:1500201CrossRef
go back to reference Lin ZY, Liu Y, Wong CP (2010) Facile fabrication of superhydrophobic octadecylamine-functionalized graphite oxide film. Langmuir 26:16110–16114CrossRef Lin ZY, Liu Y, Wong CP (2010) Facile fabrication of superhydrophobic octadecylamine-functionalized graphite oxide film. Langmuir 26:16110–16114CrossRef
go back to reference Liu J, Kim GH, Xue YH, Kim JY, Baek JB, Durstock M, Dai LM (2014) Graphene oxide nanoribbon as hole extraction layer to enhance efficiency and stability of polymer solar cells. Adv Mater 26:786–790CrossRef Liu J, Kim GH, Xue YH, Kim JY, Baek JB, Durstock M, Dai LM (2014) Graphene oxide nanoribbon as hole extraction layer to enhance efficiency and stability of polymer solar cells. Adv Mater 26:786–790CrossRef
go back to reference Meyer JC, Geim AK, Katsnelson MI, Novoselov KS, Booth TJ, Roth S (2007) The structure of suspended graphene sheets. Nature 446:60–63CrossRef Meyer JC, Geim AK, Katsnelson MI, Novoselov KS, Booth TJ, Roth S (2007) The structure of suspended graphene sheets. Nature 446:60–63CrossRef
go back to reference Miwa M, Nakajima A, Fujishima A, Hashimoto K, Watanabe T (2000) Effects of the surface roughness on sliding angles of water droplets on superhydrophobic surfaces. Langmuir 16:5754–5760CrossRef Miwa M, Nakajima A, Fujishima A, Hashimoto K, Watanabe T (2000) Effects of the surface roughness on sliding angles of water droplets on superhydrophobic surfaces. Langmuir 16:5754–5760CrossRef
go back to reference Nishino T, Meguro M, Nakamae K, Matsushita M, Ueda Y (1999) The lowest surface free energy based on –CF3 alignment. Langmuir 15:4321–4323CrossRef Nishino T, Meguro M, Nakamae K, Matsushita M, Ueda Y (1999) The lowest surface free energy based on –CF3 alignment. Langmuir 15:4321–4323CrossRef
go back to reference Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless dirac fermions in graphene. Nature 438:197–200CrossRef Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless dirac fermions in graphene. Nature 438:197–200CrossRef
go back to reference Oner D, McCarthy TJ (2000) Ultrahydrophobic surfaces. Effects of topography length scales on wettability Langmuir 16:7777–7782 Oner D, McCarthy TJ (2000) Ultrahydrophobic surfaces. Effects of topography length scales on wettability Langmuir 16:7777–7782
go back to reference Patankar NA (2003) On the modeling of hydrophobic contact angles on rough surfaces. Langmuir 19:1249–1253CrossRef Patankar NA (2003) On the modeling of hydrophobic contact angles on rough surfaces. Langmuir 19:1249–1253CrossRef
go back to reference Qi DP, Lu N, Xu HB, Yang BJ, Huang CY, Xu MJ, Gao LG, Wang ZX, Chi LF (2009) Simple approach to wafer-scale self-cleaning antireflective silicon surfaces. Langmuir 25:7769–7772CrossRef Qi DP, Lu N, Xu HB, Yang BJ, Huang CY, Xu MJ, Gao LG, Wang ZX, Chi LF (2009) Simple approach to wafer-scale self-cleaning antireflective silicon surfaces. Langmuir 25:7769–7772CrossRef
go back to reference Qian ZS, Shan XY, Chai LJ, Ma JJ, Chen JR, Feng H (2014) A universal fluorescence sensing strategy based on biocompatible graphene quantum dots and graphene oxide for the detection of DNA. Nanoscale 6:5671–5674CrossRef Qian ZS, Shan XY, Chai LJ, Ma JJ, Chen JR, Feng H (2014) A universal fluorescence sensing strategy based on biocompatible graphene quantum dots and graphene oxide for the detection of DNA. Nanoscale 6:5671–5674CrossRef
go back to reference Rafiee J, Rafiee MA, Yu ZZ, Koratkar N (2010) Superhydrophobic to superhydrophilic wetting control in graphene films. Adv Mater 22:2151–2154CrossRef Rafiee J, Rafiee MA, Yu ZZ, Koratkar N (2010) Superhydrophobic to superhydrophilic wetting control in graphene films. Adv Mater 22:2151–2154CrossRef
go back to reference Rahmawan Y, Xu LB, Yang S (2013) Self-assembly of nanostructures towards transparent, superhydrophobic surfaces. J Mater Chem A 1:2955–2969CrossRef Rahmawan Y, Xu LB, Yang S (2013) Self-assembly of nanostructures towards transparent, superhydrophobic surfaces. J Mater Chem A 1:2955–2969CrossRef
go back to reference Sheng Y, Zeng HC (2015) Structured assemblages of single-walled 3d transition metal silicate nanotubes as precursors for composition-tailorable catalysts. Chem Mater 27:658–667CrossRef Sheng Y, Zeng HC (2015) Structured assemblages of single-walled 3d transition metal silicate nanotubes as precursors for composition-tailorable catalysts. Chem Mater 27:658–667CrossRef
go back to reference Stober W, Fink A (1968) Controlled growth of monodispersed spheres in the micron size range. J Colloid Interf Sci 26:62–69CrossRef Stober W, Fink A (1968) Controlled growth of monodispersed spheres in the micron size range. J Colloid Interf Sci 26:62–69CrossRef
go back to reference Sun TL, Tan H, Han D, Fu Q, Jiang L (2005) No platelet can adhere-largely improved blood compatibility on nanostructured superhydrophobic surfaces. Small 1:959–963CrossRef Sun TL, Tan H, Han D, Fu Q, Jiang L (2005) No platelet can adhere-largely improved blood compatibility on nanostructured superhydrophobic surfaces. Small 1:959–963CrossRef
go back to reference Tian Y, Su B, Jiang L (2014) Interfacial material system exhibiting superwettability. Adv Mater 26:6872–6897CrossRef Tian Y, Su B, Jiang L (2014) Interfacial material system exhibiting superwettability. Adv Mater 26:6872–6897CrossRef
go back to reference Tuvshindorj U, Yildirim A, Ozturk FE, Bayindir M (2014) Robust cassie state of wetting in transparent superhydrophobic coatings. ACS Appl Mater Inter 6:9680–9688CrossRef Tuvshindorj U, Yildirim A, Ozturk FE, Bayindir M (2014) Robust cassie state of wetting in transparent superhydrophobic coatings. ACS Appl Mater Inter 6:9680–9688CrossRef
go back to reference Wang YQ, Wang GZ, Wang HQ, Cai WP, Zhang LD (2008) One-pot synthesis of nanotube-based hierarchical copper silicate hollow spheres. Chem Commun 48:6555–6557CrossRef Wang YQ, Wang GZ, Wang HQ, Cai WP, Zhang LD (2008) One-pot synthesis of nanotube-based hierarchical copper silicate hollow spheres. Chem Commun 48:6555–6557CrossRef
go back to reference Wang J, Zhou W, Du Y (2012) Effect of sodium silicate pretreatment on phosphate layer: morphology and corrosion resistance behavior. Mater Corros 63:317–322CrossRef Wang J, Zhou W, Du Y (2012) Effect of sodium silicate pretreatment on phosphate layer: morphology and corrosion resistance behavior. Mater Corros 63:317–322CrossRef
go back to reference Wu YP, Zhou ZH, Tuo YF, Wang K, Huang M, Huang Y, Shen S (2015) A transparent CNTs/TiO2 composite film with superhydrophobic and photocatalytic functions self-assembled by liquid-phase deposition. Mater Chem Phys 149:522–529CrossRef Wu YP, Zhou ZH, Tuo YF, Wang K, Huang M, Huang Y, Shen S (2015) A transparent CNTs/TiO2 composite film with superhydrophobic and photocatalytic functions self-assembled by liquid-phase deposition. Mater Chem Phys 149:522–529CrossRef
go back to reference Xu QF, Wang JN, Sanderson KD (2010) Organic-inorganic composite nanocoatings with superhydrophobicity, good transparency, and thermal stability. ACS Nano 4:2201–2209CrossRef Xu QF, Wang JN, Sanderson KD (2010) Organic-inorganic composite nanocoatings with superhydrophobicity, good transparency, and thermal stability. ACS Nano 4:2201–2209CrossRef
go back to reference Xue YH, Liu Y, Lu F, Qu J, Chen H, Dai LM (2012) Functionalization of graphene oxide with polyhedral oligomeric silsesquioxane (POSS) for multifunctional applications. J Phys Chem Lett 3:1607–1612CrossRef Xue YH, Liu Y, Lu F, Qu J, Chen H, Dai LM (2012) Functionalization of graphene oxide with polyhedral oligomeric silsesquioxane (POSS) for multifunctional applications. J Phys Chem Lett 3:1607–1612CrossRef
go back to reference Yoshimitsu Z, Nakajima A, Watanabe T, Hashimoto K (2002) Effects of surface structure on the hydrophobicity and sliding behavior of water droplets. Langmuir 18:5818–5822CrossRef Yoshimitsu Z, Nakajima A, Watanabe T, Hashimoto K (2002) Effects of surface structure on the hydrophobicity and sliding behavior of water droplets. Langmuir 18:5818–5822CrossRef
go back to reference Youngblood JP, McCarthy TJ (1999) Ultrahydrophobic polymer surfaces prepared by simultaneous ablation of polypropylene and sputtering of poly(tetrafluoroethylene) using radio frequency plasma. Macromolecules 32:6800–6806CrossRef Youngblood JP, McCarthy TJ (1999) Ultrahydrophobic polymer surfaces prepared by simultaneous ablation of polypropylene and sputtering of poly(tetrafluoroethylene) using radio frequency plasma. Macromolecules 32:6800–6806CrossRef
go back to reference Zhang X, Shi F, Yu X, Liu H, Fu Y, Wang ZQ, Jiang L, Li XY (2004) Polyelectrolyte multilayer as matrix for electrochemical deposition of gold clusters: toward super-hydrophobic surface. J Am Chem Soc 126:3064–3065CrossRef Zhang X, Shi F, Yu X, Liu H, Fu Y, Wang ZQ, Jiang L, Li XY (2004) Polyelectrolyte multilayer as matrix for electrochemical deposition of gold clusters: toward super-hydrophobic surface. J Am Chem Soc 126:3064–3065CrossRef
go back to reference Zhang YB, Tan YW, Stormer HL, Kim P (2005) Experimental observation of the quantum hall effect and Berry’s phase in graphene. Nature 438:201–204CrossRef Zhang YB, Tan YW, Stormer HL, Kim P (2005) Experimental observation of the quantum hall effect and Berry’s phase in graphene. Nature 438:201–204CrossRef
go back to reference Zhang S, Li Q, Chen B, Yang X (2010) Preparation and corrosion resistance studies of nanometric sol-gel-based CeO2 film with a chromium-free pretreatment on AZ91D magnesium alloy. Electrochim Acta 55:870–877CrossRef Zhang S, Li Q, Chen B, Yang X (2010) Preparation and corrosion resistance studies of nanometric sol-gel-based CeO2 film with a chromium-free pretreatment on AZ91D magnesium alloy. Electrochim Acta 55:870–877CrossRef
go back to reference Zhang XQ, Wan SH, Pu JB, Wang LP, Liu XQ (2011) Highly hydrophobic and adhesive performance of graphene films. J Mater Chem 21:12251–12258CrossRef Zhang XQ, Wan SH, Pu JB, Wang LP, Liu XQ (2011) Highly hydrophobic and adhesive performance of graphene films. J Mater Chem 21:12251–12258CrossRef
go back to reference Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS (2010) Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater 22:3906–3924CrossRef Zhu YW, Murali S, Cai WW, Li XS, Suk JW, Potts JR, Ruoff RS (2010) Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater 22:3906–3924CrossRef
go back to reference Zhu T, Wang ZY, Ding SJ, Chen JS, Lou XW (2011) Hierarchical nickel sulfide hollow spheres for high performance supercapacitors. RSC Adv 1:397–400CrossRef Zhu T, Wang ZY, Ding SJ, Chen JS, Lou XW (2011) Hierarchical nickel sulfide hollow spheres for high performance supercapacitors. RSC Adv 1:397–400CrossRef
Metadata
Title
GO@CuSilicate nano-needle arrays hierarchical structure: a new route to prepare high optical transparent, excellent self-cleaning and anticorrosion superhydrophobic surface
Authors
Ping Fan
Jingyi Chen
Jintao Yang
Feng Chen
Mingqiang Zhong
Publication date
01-02-2017
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 2/2017
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-016-3676-7

Other articles of this Issue 2/2017

Journal of Nanoparticle Research 2/2017 Go to the issue

Premium Partners