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Published in: Journal of Polymer Research 10/2013

01-10-2013 | Original Paper

High performance thermosets based on multifunctional intermediates containing allyl, maleimide and benzoxazine groups

Authors: Constantin Gaina, Oana Ursache, Viorica Gaina, Valentina-Elena Musteata

Published in: Journal of Polymer Research | Issue 10/2013

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Abstract

High performance thermosets were prepared by thermally curing of multifunctional intermediates containing allyl, maleimide, furyl and benzoxazine rings. The multifunctional intermediates were obtained by cycloaddition reaction of 2,2′-bis(8-allyl-3-furfuryl-3,4-dihydro-2H-1,3-benzoxazinyl)isopropane or bis(3-furfuryl-3,4-dihydro-2H-1,3-benzoxazinyl)isopropane with 4,4′-bismaleimidodiphenylmethane in molar ratio of 1:1 and 1:2, in THF at reflux. The chemical structure of multifunctional intermediates was elucidated by FTIR and 1H-NMR spectroscopy and curing parameter by differential scanning calorimetry. The thermal analysis showed that decomposition of these materials takes place in two stages and DSC measurements of networks did not exhibit the glass transition temperature up to 300 °C.

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Metadata
Title
High performance thermosets based on multifunctional intermediates containing allyl, maleimide and benzoxazine groups
Authors
Constantin Gaina
Oana Ursache
Viorica Gaina
Valentina-Elena Musteata
Publication date
01-10-2013
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 10/2013
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-013-0263-9

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