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Published in: Tribology Letters 4/2022

01-12-2022 | Original Paper

High-Pressure Lubrication of Polyethylethylene by Molecular Dynamics Approach

Authors: Ryoichi Katsukawa, Le Van Sang, Eiji Tomiyama, Hitoshi Washizu

Published in: Tribology Letters | Issue 4/2022

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Abstract

Polyethylene (PE) and branched PE are common materials inserted inside contacts for medical and industrial applications. Consequently, their tribological properties have been extensively investigated in the past. This paper aims to determine the lubrication behavior of polyethylethylene (PEE) for iron contact and the two main factors of temperature and carbon chain length influencing the lubrication in the high-pressure lubrication regime by molecular dynamics simulations. Additionally, the influences of pressure and sliding velocity on the friction are also considered. These factors are found to be significantly influencing the lubricity. The obtained results mainly originated from shear and stretching of the PEE molecules, condensed situation of the lubricants, and adhesion between the lubricants and the iron surfaces. These observations are explained in detail.

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Literature
1.
go back to reference Rabinowitz, S., Ward, I.M., Parry, J.S.C.: The effect of hydrostatic pressure on the shear yield behaviour of polymers. J. Mater. Sci. 5, 29–39 (1970) Rabinowitz, S., Ward, I.M., Parry, J.S.C.: The effect of hydrostatic pressure on the shear yield behaviour of polymers. J. Mater. Sci. 5, 29–39 (1970)
2.
go back to reference Bowden, P.B., Jukes, J.A.: The plastic flow of isotropic polymers. J. Mater. Sci. 7, 52–63 (1972) Bowden, P.B., Jukes, J.A.: The plastic flow of isotropic polymers. J. Mater. Sci. 7, 52–63 (1972)
3.
go back to reference Aird, P.J., Cherry, B.W.: Frictional properties of branched polyethylene. I. The true area of contact. Wear 47, 231–241 (1978) Aird, P.J., Cherry, B.W.: Frictional properties of branched polyethylene. I. The true area of contact. Wear 47, 231–241 (1978)
4.
go back to reference Zhan, S., Xu, H., Duan, H., Pan, L., Jia, D., Tu, J., Liu, L., Li, J.: Molecular dynamics simulation of microscopic friction mechanisms of amorphous polyethylene. Soft Matter 15, 8827–8839 (2019) Zhan, S., Xu, H., Duan, H., Pan, L., Jia, D., Tu, J., Liu, L., Li, J.: Molecular dynamics simulation of microscopic friction mechanisms of amorphous polyethylene. Soft Matter 15, 8827–8839 (2019)
5.
go back to reference Washizu, H., Ohmori, T.: Molecular dynamics simulations of elastohydrodynamic lubrication oil film. Lubric. Sci. 22, 323–340 (2010) Washizu, H., Ohmori, T.: Molecular dynamics simulations of elastohydrodynamic lubrication oil film. Lubric. Sci. 22, 323–340 (2010)
6.
go back to reference Washizu, H., Ohmori, T., Suzuki, A.: Molecular origin of limiting shear stress of elastohydrodynamic lubrication oil film studied by molecular dynamics. Chem. Phys. Lett. 678, 1–4 (2017) Washizu, H., Ohmori, T., Suzuki, A.: Molecular origin of limiting shear stress of elastohydrodynamic lubrication oil film studied by molecular dynamics. Chem. Phys. Lett. 678, 1–4 (2017)
7.
go back to reference Zhang, H., Fukuda, M., Washizu, H., Kinjo, T., Yoshida, H., Fukuzawa, K., Itoh, S.: Shear thinning behavior of nanometer-thick perfluoropolyether films confined between corrugated solid surfaces: a coarse-grained molecular dynamics study. Tribol. Int. 93, 163–171 (2016) Zhang, H., Fukuda, M., Washizu, H., Kinjo, T., Yoshida, H., Fukuzawa, K., Itoh, S.: Shear thinning behavior of nanometer-thick perfluoropolyether films confined between corrugated solid surfaces: a coarse-grained molecular dynamics study. Tribol. Int. 93, 163–171 (2016)
8.
go back to reference Ewen, J.P., Gattinoni, C., Zhang, J., Heyes, D.M., Spikes, H.A., Dini, D.: On the effect of confined fluid molecular structure on nonequilibrium phase behavior and friction. Phys. Chem. Chem. Phys. 19, 17883–17894 (2017) Ewen, J.P., Gattinoni, C., Zhang, J., Heyes, D.M., Spikes, H.A., Dini, D.: On the effect of confined fluid molecular structure on nonequilibrium phase behavior and friction. Phys. Chem. Chem. Phys. 19, 17883–17894 (2017)
9.
go back to reference Ewen, J.P., Gao, H., Mueser, M., Dini, D.: Shear heating, flow, and friction of confined molecular fluids at high pressure. Phys. Chem. Chem. Phys. 21, 5813–5823 (2019) Ewen, J.P., Gao, H., Mueser, M., Dini, D.: Shear heating, flow, and friction of confined molecular fluids at high pressure. Phys. Chem. Chem. Phys. 21, 5813–5823 (2019)
10.
go back to reference Moriguchi, S., Tsujimoto, T., Sasahara, A., Kokawa, R., Onishi, H.: Nanometer-scale distribution of a lubricant modifier on iron films: a frequency-modulation atomic force microscopy study combined with a friction test. ACS Omega 4, 17593–17599 (2019) Moriguchi, S., Tsujimoto, T., Sasahara, A., Kokawa, R., Onishi, H.: Nanometer-scale distribution of a lubricant modifier on iron films: a frequency-modulation atomic force microscopy study combined with a friction test. ACS Omega 4, 17593–17599 (2019)
11.
go back to reference Karuppiah, K.S.K., Bruck, A.L., Sundararajan, S., Wang, J., Lin, Z., Xu, Z.H., Li, X.: Friction and wear behavior of ultra-high molecular weight polyethylene as a function of polymer crystallinity. Acta Biomater. 4, 1401–1410 (2008) Karuppiah, K.S.K., Bruck, A.L., Sundararajan, S., Wang, J., Lin, Z., Xu, Z.H., Li, X.: Friction and wear behavior of ultra-high molecular weight polyethylene as a function of polymer crystallinity. Acta Biomater. 4, 1401–1410 (2008)
12.
go back to reference Cohen, S.C., Tabor, D.: The friction and lubrication of polymers. Proc. R. Soc. A Lond. Math. Phys. Sci. 291, 186–207 (1966) Cohen, S.C., Tabor, D.: The friction and lubrication of polymers. Proc. R. Soc. A Lond. Math. Phys. Sci. 291, 186–207 (1966)
13.
go back to reference Ludema, K.C., Tabor, D.: The friction and visco-elastic properties of polymeric solids. Wear 9, 329–348 (1966) Ludema, K.C., Tabor, D.: The friction and visco-elastic properties of polymeric solids. Wear 9, 329–348 (1966)
14.
go back to reference Bahadur, S., Ludema, K.C.: The viscoelastic nature of the sliding friction of polyethylene, polypropylene and copolymers. Wear 18, 109–128 (1971) Bahadur, S., Ludema, K.C.: The viscoelastic nature of the sliding friction of polyethylene, polypropylene and copolymers. Wear 18, 109–128 (1971)
15.
go back to reference Bahadur, S.: Dependence of polymer sliding friction on normal load and contact pressure. Wear 29, 323–336 (1974) Bahadur, S.: Dependence of polymer sliding friction on normal load and contact pressure. Wear 29, 323–336 (1974)
16.
go back to reference Briscoe, B.J., Tabor, D.: The effect of pressure on the frictional properties of polymers. Wear 34, 29–38 (1975) Briscoe, B.J., Tabor, D.: The effect of pressure on the frictional properties of polymers. Wear 34, 29–38 (1975)
17.
go back to reference Cho, D.H., Bhushan, B., Dyess, J.: Mechanisms of static and kinetic friction of polypropylene, polyethylene terephthalate, and high-density polyethylene pairs during sliding. Tribol. Int. 94, 165–175 (2016) Cho, D.H., Bhushan, B., Dyess, J.: Mechanisms of static and kinetic friction of polypropylene, polyethylene terephthalate, and high-density polyethylene pairs during sliding. Tribol. Int. 94, 165–175 (2016)
18.
go back to reference Towle, L.C.: Shear strength and friction measurement on thin layers under high pressure. J. Appl. Phys. 42, 2368–2376 (1971) Towle, L.C.: Shear strength and friction measurement on thin layers under high pressure. J. Appl. Phys. 42, 2368–2376 (1971)
19.
go back to reference Towle, L.C.: Shear strength and friction measurements on polyethylene under high pressure. J. Appl. Phys. 44, 1611–1616 (1973) Towle, L.C.: Shear strength and friction measurements on polyethylene under high pressure. J. Appl. Phys. 44, 1611–1616 (1973)
20.
go back to reference Zivica, F., Babica, M., Mitrovica, S., Adamovica, D., Pelemis, S.: Friction coefficient of UHMWPE during dry reciprocating sliding. Tribol. Ind. 36, 281–286 (2014) Zivica, F., Babica, M., Mitrovica, S., Adamovica, D., Pelemis, S.: Friction coefficient of UHMWPE during dry reciprocating sliding. Tribol. Ind. 36, 281–286 (2014)
21.
go back to reference Flom, D.G.: Rolling friction of polymeric materials. II. Thermoplastics. . J. Appl. Phys. 32, 1426–1437 (1961) Flom, D.G.: Rolling friction of polymeric materials. II. Thermoplastics. . J. Appl. Phys. 32, 1426–1437 (1961)
22.
go back to reference Wrobel, G., Szymiczek, M.: Influence of temperature on friction coefficient of low-density polyethylene. J. Achiev. Mater. Manufact. Eng. 28, 31–34 (2018) Wrobel, G., Szymiczek, M.: Influence of temperature on friction coefficient of low-density polyethylene. J. Achiev. Mater. Manufact. Eng. 28, 31–34 (2018)
23.
go back to reference Kinsella, M.E., Lilly, B., Gardner, B.E., Jacobs, N.J.: Experimental determination of friction coefficients between thermoplastics and rapid tooled injection mold materials. Rapid Prototyping J. 11, 167–173 (2005) Kinsella, M.E., Lilly, B., Gardner, B.E., Jacobs, N.J.: Experimental determination of friction coefficients between thermoplastics and rapid tooled injection mold materials. Rapid Prototyping J. 11, 167–173 (2005)
24.
go back to reference Rocha, M.C.G., Moraes, L.R.D.C., Cell, N.: Thermal and mechanical properties of vinyltrimethoxysilane (VTMOS) crosslinked high molecular weight polyethylene (HMWPE). Mater. Res. 20, 1332–1339 (2017) Rocha, M.C.G., Moraes, L.R.D.C., Cell, N.: Thermal and mechanical properties of vinyltrimethoxysilane (VTMOS) crosslinked high molecular weight polyethylene (HMWPE). Mater. Res. 20, 1332–1339 (2017)
25.
go back to reference Eman, S.M., Khashaba, M.I., Ali, W.I.: Friction coefficient and wear displayed by the scratch of polyethylene reinforced by steel wires. Int. J. Mater. Chem. Phys. 1, 378–383 (2015) Eman, S.M., Khashaba, M.I., Ali, W.I.: Friction coefficient and wear displayed by the scratch of polyethylene reinforced by steel wires. Int. J. Mater. Chem. Phys. 1, 378–383 (2015)
26.
go back to reference Yousif, B.F., Alsofyani, I.M., Yusaf, T.F.: Adhesive wear and frictional characteristics of UHMWPE and HDPE sliding against different counterfaces under dry contact condition. Tribol. Mater. Surf. Interfaces 4, 78–85 (2010) Yousif, B.F., Alsofyani, I.M., Yusaf, T.F.: Adhesive wear and frictional characteristics of UHMWPE and HDPE sliding against different counterfaces under dry contact condition. Tribol. Mater. Surf. Interfaces 4, 78–85 (2010)
27.
go back to reference Wang, A., Essner, A., Klein, R.: Effect of contact stress on friction and wear of ultra-high molecular weight polyethylene in total hip replacement. Proc. Inst. Mech. Eng. H 215, 133–139 (2001) Wang, A., Essner, A., Klein, R.: Effect of contact stress on friction and wear of ultra-high molecular weight polyethylene in total hip replacement. Proc. Inst. Mech. Eng. H 215, 133–139 (2001)
28.
go back to reference Sivebaek, I.M., Samoilov, V.N., Persson, B.N.J.: Frictional properties of confined polymers. Eur. Phys. J. E 27, 37–46 (2008) Sivebaek, I.M., Samoilov, V.N., Persson, B.N.J.: Frictional properties of confined polymers. Eur. Phys. J. E 27, 37–46 (2008)
29.
go back to reference Heo, S.J., Jang, I., Barry, P.R., Phillpot, S.R., Perry, S.S., Sawyer, W.G., Sinnott, S.B.: Effect of the sliding orientation on the tribological properties of polyethylene in molecular dynamics simulations. J. Appl. Phys. 103, 083502 (2008) Heo, S.J., Jang, I., Barry, P.R., Phillpot, S.R., Perry, S.S., Sawyer, W.G., Sinnott, S.B.: Effect of the sliding orientation on the tribological properties of polyethylene in molecular dynamics simulations. J. Appl. Phys. 103, 083502 (2008)
30.
go back to reference Qiang, Y., Wu, W., Lu, J., Jiang, B., Ziegmann, G.: Progressive molecular rearrangement and heat generation of amorphous polyethene under sliding friction: Insight from the united-atom molecular dynamics simulations. Langmuir 36, 11303–11315 (2020) Qiang, Y., Wu, W., Lu, J., Jiang, B., Ziegmann, G.: Progressive molecular rearrangement and heat generation of amorphous polyethene under sliding friction: Insight from the united-atom molecular dynamics simulations. Langmuir 36, 11303–11315 (2020)
31.
go back to reference Sawyer, W.G., Perry, S.S., Phillpot, S.R., Sinnott, S.B.: Integrating experimental and simulation length and time scales in mechanistic studies of friction. J. Phys. Condens. Matter 20, 354012 (2008) Sawyer, W.G., Perry, S.S., Phillpot, S.R., Sinnott, S.B.: Integrating experimental and simulation length and time scales in mechanistic studies of friction. J. Phys. Condens. Matter 20, 354012 (2008)
32.
go back to reference Chiu, P.Y., Barry, P.R., Perry, S.S., Sinnott, S.B.: Influence of the molecular level structure of polyethylene and polytetrafluoroethylene on their tribological response. Tribol. Lett. 43, 193–201 (2011) Chiu, P.Y., Barry, P.R., Perry, S.S., Sinnott, S.B.: Influence of the molecular level structure of polyethylene and polytetrafluoroethylene on their tribological response. Tribol. Lett. 43, 193–201 (2011)
33.
go back to reference Zheng, T., Wang, S., Zhou, L., Li, X., Zhang, H.: The disentanglement and shear properties of amorphous polyethylene during friction: insights from molecular dynamics simulations. Appl. Surf. Sci. 580, 152301 (2022) Zheng, T., Wang, S., Zhou, L., Li, X., Zhang, H.: The disentanglement and shear properties of amorphous polyethylene during friction: insights from molecular dynamics simulations. Appl. Surf. Sci. 580, 152301 (2022)
34.
go back to reference Dai, L., Satyanarayana, M.N., Sinha, S.K., Tan, V.B.C.: Identifying the mechanisms of polymer friction through molecular dynamics simulation. Langmuir 27, 14861–14867 (2011) Dai, L., Satyanarayana, M.N., Sinha, S.K., Tan, V.B.C.: Identifying the mechanisms of polymer friction through molecular dynamics simulation. Langmuir 27, 14861–14867 (2011)
35.
go back to reference Washizu, H., Hyodo, S., Ohmori, S., Nishino, N., Suzuki, A.: Macroscopic no-slip boundary condition confirmed in full atomistic simulation of oil film. Tribol. Online 9, 45–50 (2014) Washizu, H., Hyodo, S., Ohmori, S., Nishino, N., Suzuki, A.: Macroscopic no-slip boundary condition confirmed in full atomistic simulation of oil film. Tribol. Online 9, 45–50 (2014)
36.
go back to reference Washizu, H., Sanda, S., Hyodo, S., Ohmori, T., Nishino, N., Suzuki, A.: Molecular dynamics simulations of elasto-hydrodynamic lubrication and boundary lubrication for automotive tribology. J. Phys. Conf. Ser. 89, 012009–012016 (2007) Washizu, H., Sanda, S., Hyodo, S., Ohmori, T., Nishino, N., Suzuki, A.: Molecular dynamics simulations of elasto-hydrodynamic lubrication and boundary lubrication for automotive tribology. J. Phys. Conf. Ser. 89, 012009–012016 (2007)
37.
go back to reference Aryanpour, M., Duin, A.C.T.V., Kubicki, J.D.: Development of a reactive force field for iron-oxyhydroxide systems. J. Phys. Chem. A 114, 6298–6307 (2010) Aryanpour, M., Duin, A.C.T.V., Kubicki, J.D.: Development of a reactive force field for iron-oxyhydroxide systems. J. Phys. Chem. A 114, 6298–6307 (2010)
38.
go back to reference Plimpton, S.: Fast parallel algorithms for short-range molecular dynamics. J. Comput. Phys. 119, 1–19 (1995) Plimpton, S.: Fast parallel algorithms for short-range molecular dynamics. J. Comput. Phys. 119, 1–19 (1995)
39.
go back to reference Khare, R., de Pablo, J., Yethiraj, A.: Molecular simulation and continuum mechanics study of simple fluids in non-isothermal planar Couette flows. J. Chem. Phys. 107, 2589 (1997) Khare, R., de Pablo, J., Yethiraj, A.: Molecular simulation and continuum mechanics study of simple fluids in non-isothermal planar Couette flows. J. Chem. Phys. 107, 2589 (1997)
40.
go back to reference Nose, S.: A unified formulation of the constant temperature molecular dynamics methods. J. Chem. Phys. 81, 511–519 (1984) Nose, S.: A unified formulation of the constant temperature molecular dynamics methods. J. Chem. Phys. 81, 511–519 (1984)
41.
go back to reference Hoover, W.G.: Canonical dynamics: equilibrium phase-space distributions. Phys. Rev. A 31, 1695–1697 (1985) Hoover, W.G.: Canonical dynamics: equilibrium phase-space distributions. Phys. Rev. A 31, 1695–1697 (1985)
42.
go back to reference Nakamura, K., Ookawa, R., Yasuda, S.: Solidification of the Lennard–Jones fluid near a wall in thermohydrodynamic lubrication. Phys. Rev. E 100, 033109–033117 (2019) Nakamura, K., Ookawa, R., Yasuda, S.: Solidification of the Lennard–Jones fluid near a wall in thermohydrodynamic lubrication. Phys. Rev. E 100, 033109–033117 (2019)
43.
go back to reference Makhnovskii, Y., Ovchinnikov, Y.K., Ovchinnikov, A.A.: The radial distribution function as a means of structural analysis for a polyethylene melt. Polym. Sci. 22, 2801–2807 (1980) Makhnovskii, Y., Ovchinnikov, Y.K., Ovchinnikov, A.A.: The radial distribution function as a means of structural analysis for a polyethylene melt. Polym. Sci. 22, 2801–2807 (1980)
44.
go back to reference Teraoka, I.: Polymer Solutions: An Introduction to Physical Properties. John Wiley & Sons Inc., New York (2002) Teraoka, I.: Polymer Solutions: An Introduction to Physical Properties. John Wiley & Sons Inc., New York (2002)
45.
go back to reference Sang, L.V., Sugimura, N., Washizu, H.: Graphene as solid lubricant vertically buried into iron contact surface by annealing for superlubricity. Tribol. Int. 165, 107288 (2022) Sang, L.V., Sugimura, N., Washizu, H.: Graphene as solid lubricant vertically buried into iron contact surface by annealing for superlubricity. Tribol. Int. 165, 107288 (2022)
46.
go back to reference Sang, L.V., Sugimura, N., Kosar, K., Washizu, H.: Solid lubricants of combined graphene and iron nanoparticles for study of friction and stability. Langmuir 38, 1860–1868 (2022) Sang, L.V., Sugimura, N., Kosar, K., Washizu, H.: Solid lubricants of combined graphene and iron nanoparticles for study of friction and stability. Langmuir 38, 1860–1868 (2022)
Metadata
Title
High-Pressure Lubrication of Polyethylethylene by Molecular Dynamics Approach
Authors
Ryoichi Katsukawa
Le Van Sang
Eiji Tomiyama
Hitoshi Washizu
Publication date
01-12-2022
Publisher
Springer US
Published in
Tribology Letters / Issue 4/2022
Print ISSN: 1023-8883
Electronic ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-022-01638-8

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