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Journal of Nanoparticle Research
Published in: Journal of Nanoparticle Research 2/2008

01-02-2008 | Research Paper

High temperature instability of hollow nanoparticles

Authors: F. D. Fischer, J. Svoboda

Published in: Journal of Nanoparticle Research | Issue 2/2008

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Abstract

The concept of the Gibbs energy balance is used to derive the evolution equation of both surfaces of a hollow nanosphere. The process is driven by reducing the surface energy and the elastic energy stored in the bulk. A semianalytical solution is provided for the time period during which a hollow nanosphere shrinks to a compact nanospherical particle. Comparison with recently reported results is performed.
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Literature
Gusak AM, Zaporozhets TV, Tu KN, Gösele U (2005) Kinetic analysis of the instability of hollow nanoparticles. Philos Mag 85:4445–4464CrossRef
Han C, Wu X, Lin Y., Gu G., Fu X., Hi Z. (2006) Preparation and characterization of Y2O3 hollow spheres. J Mater Sci 41:3679–3682CrossRef
Hartmann M, Weinkamer R, Fratzl P, Svoboda J, Fischer FD (2005) Onsager’s coefficients and diffusion laws – A Monte Carlo study. Philos Mag 85:1243–1260CrossRef
Svoboda J, Gamsjäger E, Fischer F.D. (2005a) Relaxation of the elastic strain energy of misfitting inclusions due to diffusion of vacancies. Philos Mag Lett 85:473–479CrossRef
Svoboda J, Turek I, Fischer FD (2005b) Application of the thermodynamic extremal principle to modeling of thermodynamic processes in material sciences. Philos Mag 85:3699–3707CrossRef
Svoboda J, Fischer FD, Fratzl P (2006) Diffusion and creep in multi-component alloys with non-ideal sources and sinks for vacancies. Acta Mater 54:3043–3053CrossRef
Yin Y, Rioux RM, Erdonmez CK, Hughes S, Somorjai GA, Alivisatos AP (2004) Formation of hollow nanocrystals through the nanoscale Kirkendall effect. Science 304:711–714CrossRef
Metadata
Title
High temperature instability of hollow nanoparticles
Authors
F. D. Fischer
J. Svoboda
Publication date
01-02-2008
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 2/2008
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-007-9242-6

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