2005 | OriginalPaper | Chapter
Humic Acids as Barriers in Actinide Migration in the Environment
Authors : S.N. Kalmykov, A.P. Novikov, A.B. Khasanova, N.S. Scherbina, Yu.A. Sapozhnikov
Published in: Use of Humic Substances to Remediate Polluted Environments: From Theory to Practice
Publisher: Springer Netherlands
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Humic acids (HAs) and fulvic acids (FAs) are the main components of natural waters that can influence the migration ability of cations. They form stable complex compounds with actinide elements that can change their solubility. In addition, HAs could be responsible for migration of colloidal species. The role of HAs in formation of geochemical barriers in actinide migration in the geosphere is discussed on the basis of results of laboratory experiments and speciation of plutonium and neptunium in field samples collected from the regions contaminated by human-made radionuclides.