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Published in: Environmental Earth Sciences 2/2013

01-09-2013 | Original Article

Identifying sources of salinization using hydrochemical and isotopic techniques, Konarsiah, Iran

Authors: Mehdi Zarei, Ezzat Raeisi, Broder J. Merkel, Nicolai-Alexeji Kummer

Published in: Environmental Earth Sciences | Issue 2/2013

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Abstract

Konarsiah salt diapir is situated in the Simply Folded Zone of the Zagros Mountain, south Iran. Eight small permanent brine springs emerge from the Konarsiah salt body, with average total dissolved solids of 326.7 g/L. There are numerous brackish to saline springs emerging from the alluvial and karst aquifers adjacent to the diapir. Concerning emergence of Konarsiah diapir in the study area, halite dissolution is the most probable source of salinity in the adjacent aquifers. However, other sources including evaporation and deep brines through deep Mangerak Fault are possible. The water samples of the study area were classified based on their water-type, salinity, and the trend of the ions concentration curves. The result of this classification is in agreement with the hydrogeological setting of the study area. The hydrochemical and isotopic evaluations show that the groundwater samples are the result of mixing of four end members; Gachsaran sulfate water, Sarvak and Asmari carbonate fresh waters, and diapir brine. The molar ratios of Na/Cl, Li/Cl, Br/Cl, and SO4/Cl; and isotopic signature of the mixed samples justify a groundwater mixing model for the aquifers adjacent to the salt diapir. The share of brine in each adjacent aquifer was calculated using Cl mass balance. In addition, concentrations of 34 trace elements were determined to characterize the diapir brine and to identify the possible tracers of salinity sources in the mixed water samples. B, Mn, Rb, Sr, Cs, Tl, and Te were identified as trace elements evidencing contact of groundwater with the salt diapir.

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Literature
go back to reference Aghdam JA, Zare M, Capaccioni B, Raeisi E, Forti P (2012) The Karun River waters in the Ambal ridge region (Zagros mountain Range, southwestern Iran): mixing calculation and hydrogeological implications. Carbonates Evap. doi:10.1007/s13146-012-0083-8 Aghdam JA, Zare M, Capaccioni B, Raeisi E, Forti P (2012) The Karun River waters in the Ambal ridge region (Zagros mountain Range, southwestern Iran): mixing calculation and hydrogeological implications. Carbonates Evap. doi:10.​1007/​s13146-012-0083-8
go back to reference Anderson NL, Brown RJ (1992) Dissolution and deformation of rock salt, Stetter Area, Southeastern Albert. Can J Explor Geophy 28(2):128–136 Anderson NL, Brown RJ (1992) Dissolution and deformation of rock salt, Stetter Area, Southeastern Albert. Can J Explor Geophy 28(2):128–136
go back to reference Ashjari J, Raeisi E (2006) Lithological control on water chemistry. Cave Karst Sci 33(3):111–118 Ashjari J, Raeisi E (2006) Lithological control on water chemistry. Cave Karst Sci 33(3):111–118
go back to reference Atapour H (2012) Geochemical baseline of major anions and heavy metals in groundwaters and drinking waters around the urban areas of Kerman city, southeastern Iran. Environ Earth Sci 67(7):2063–2076CrossRef Atapour H (2012) Geochemical baseline of major anions and heavy metals in groundwaters and drinking waters around the urban areas of Kerman city, southeastern Iran. Environ Earth Sci 67(7):2063–2076CrossRef
go back to reference Bahroudi A, Koyi HA (2004) Tectono-Sedimentary framework of the Gachsaran Formation in the Zagros foreland basin. Mar Pet Geol 21:1295–1310CrossRef Bahroudi A, Koyi HA (2004) Tectono-Sedimentary framework of the Gachsaran Formation in the Zagros foreland basin. Mar Pet Geol 21:1295–1310CrossRef
go back to reference Bellon H, Bordet P, Montenat C (1983) Chronologie du magmatisme néogène des Cordillères bètiques (Espagne méridionale). Bulletin de la Société géologique de France 7:205–217 Bellon H, Bordet P, Montenat C (1983) Chronologie du magmatisme néogène des Cordillères bètiques (Espagne méridionale). Bulletin de la Société géologique de France 7:205–217
go back to reference Carrol D (1962) Rainwater as a chemical agent of geological processes. A review U. S., Geological Survey Water-Supply Paper. 1535-G Carrol D (1962) Rainwater as a chemical agent of geological processes. A review U. S., Geological Survey Water-Supply Paper. 1535-G
go back to reference Cartwright I, Weaver TR, Fifield LK (2006) Cl/Br ratios and environmental isotopes as indicators of recharge variability and groundwater flow: an example from the southeast Murray Basin, Australia. Chem Geol 231:38–56CrossRef Cartwright I, Weaver TR, Fifield LK (2006) Cl/Br ratios and environmental isotopes as indicators of recharge variability and groundwater flow: an example from the southeast Murray Basin, Australia. Chem Geol 231:38–56CrossRef
go back to reference Diaw M, Faye S, Stichler W, Maloszewski P (2012) Isotopic and geochemical characteristics of groundwater in the Senegal River delta aquifer: implication of recharge and flow regime. Environ Earth Sci 66:1011–1020CrossRef Diaw M, Faye S, Stichler W, Maloszewski P (2012) Isotopic and geochemical characteristics of groundwater in the Senegal River delta aquifer: implication of recharge and flow regime. Environ Earth Sci 66:1011–1020CrossRef
go back to reference Falcon NL (1967) The geology of the north-east margin of the Arabian basement shield. Adv Sci 24:1–12 Falcon NL (1967) The geology of the north-east margin of the Arabian basement shield. Adv Sci 24:1–12
go back to reference Faroughi A (2008) Characterizing isotopic signature of precipitation in Fars Province, Iran. Msc Dissertation, Shiraz University (in Persian) Faroughi A (2008) Characterizing isotopic signature of precipitation in Fars Province, Iran. Msc Dissertation, Shiraz University (in Persian)
go back to reference Gillespie JB, Hargadine GD (1981) Saline ground-water discharge to the Smoky Hill River between Salina and Abilene, Central Kansas. US. Geol Surv Water Resour Invest 81–43:72 Gillespie JB, Hargadine GD (1981) Saline ground-water discharge to the Smoky Hill River between Salina and Abilene, Central Kansas. US. Geol Surv Water Resour Invest 81–43:72
go back to reference Gustavson TC, Finley RJ, McGillis KA (1980) Regional dissolution of Permian salt in the Anadarko, Dalhart, and Palo Duro Basins of the Texas Panhandle. The University of Texas at Austin. Bureau of Economic Geology Report of Investigations 106, p 40 Gustavson TC, Finley RJ, McGillis KA (1980) Regional dissolution of Permian salt in the Anadarko, Dalhart, and Palo Duro Basins of the Texas Panhandle. The University of Texas at Austin. Bureau of Economic Geology Report of Investigations 106, p 40
go back to reference Hernandez J, de Larouzière FD, Bolze J, Bordet P (1987) Le magmatisme néogène bético-rifain et le couloir de décrochement trans-Alboran. Bulletin de la Société géologique de France 3:257–267 Hernandez J, de Larouzière FD, Bolze J, Bordet P (1987) Le magmatisme néogène bético-rifain et le couloir de décrochement trans-Alboran. Bulletin de la Société géologique de France 3:257–267
go back to reference Horita J, Gat JR (1989) Deuterium in the Dead Sea: remeasurement and implications for the isotope activity correction in brines. Geochim Cosmochim Acta 53:131–133CrossRef Horita J, Gat JR (1989) Deuterium in the Dead Sea: remeasurement and implications for the isotope activity correction in brines. Geochim Cosmochim Acta 53:131–133CrossRef
go back to reference James GA, Wynd JG (1965) Stratigraphic nomenclature of Iranian oil consortium agreement area. Am Assoc Petrol Geol Bull 49(12):2188–2245 James GA, Wynd JG (1965) Stratigraphic nomenclature of Iranian oil consortium agreement area. Am Assoc Petrol Geol Bull 49(12):2188–2245
go back to reference Johnson KS (1997) Evaporite karst in the United States. Carbonates Evap 12:2–14CrossRef Johnson KS (1997) Evaporite karst in the United States. Carbonates Evap 12:2–14CrossRef
go back to reference Karimi H, Moore F (2008) The source and heating mechanism for the Ahram, Mirahmad and Garu thermal springs, Zagros Mountains. Iran Geotherm 37:84–100CrossRef Karimi H, Moore F (2008) The source and heating mechanism for the Ahram, Mirahmad and Garu thermal springs, Zagros Mountains. Iran Geotherm 37:84–100CrossRef
go back to reference Kelly WP (1948) Cation exchange in soils. Reinhold Publishing Corp, New York, p 114 Kelly WP (1948) Cation exchange in soils. Reinhold Publishing Corp, New York, p 114
go back to reference Kent PE (1979) The emergent Hormuz salt plugs of southern Iran. J Petrol Geol 2:117–144CrossRef Kent PE (1979) The emergent Hormuz salt plugs of southern Iran. J Petrol Geol 2:117–144CrossRef
go back to reference Kharroubi A, Tlahigue F, Agoubi B, Azri C, Bouri S (2012) Hydrochemical and statistical studies of the groundwater salinization in Mediterranean arid zones: case of the Jerba coastal aquifer in southeast Tunisia. Environ Earth Sci 67(7):2089–2100CrossRef Kharroubi A, Tlahigue F, Agoubi B, Azri C, Bouri S (2012) Hydrochemical and statistical studies of the groundwater salinization in Mediterranean arid zones: case of the Jerba coastal aquifer in southeast Tunisia. Environ Earth Sci 67(7):2089–2100CrossRef
go back to reference Kloppmann W, Négrel PH, Casanova J, Klinge H, Schelkes K, Guerrot C (2001) Halite dissolution derived brines in the vicinity of a Permian salt dome (N German Basin), Evidence from boron, strontium, oxygen, and hydrogen isotopes. Geochim Cosmochim Acta 65(22):4087–4101CrossRef Kloppmann W, Négrel PH, Casanova J, Klinge H, Schelkes K, Guerrot C (2001) Halite dissolution derived brines in the vicinity of a Permian salt dome (N German Basin), Evidence from boron, strontium, oxygen, and hydrogen isotopes. Geochim Cosmochim Acta 65(22):4087–4101CrossRef
go back to reference Kompani-Zare M, Moore F (2001) Chemical thermometry and origin of the Dalaki mineral springs, Boshehr Province, Iran. J Hydrol (NZ) 40:189–204 Kompani-Zare M, Moore F (2001) Chemical thermometry and origin of the Dalaki mineral springs, Boshehr Province, Iran. J Hydrol (NZ) 40:189–204
go back to reference Kreitler CW, Chapman JB, Knauth LP (1984) Chemical and isotopical composition of waters from the Salina Ometepec, Baja California. The University of Texas at Austin, Bureau of Economic Geology Open-File Report OF-WTWI-1984-41, p 13 Kreitler CW, Chapman JB, Knauth LP (1984) Chemical and isotopical composition of waters from the Salina Ometepec, Baja California. The University of Texas at Austin, Bureau of Economic Geology Open-File Report OF-WTWI-1984-41, p 13
go back to reference Kreitler CW, Akhter MS, Donnelly ACA (1990) Hydrologic-hydrochemical characterization of Texas Frio Formation that is used for deep-well injection of chemical wastes. J Environ Geol Water Sci 16(2):107–120CrossRef Kreitler CW, Akhter MS, Donnelly ACA (1990) Hydrologic-hydrochemical characterization of Texas Frio Formation that is used for deep-well injection of chemical wastes. J Environ Geol Water Sci 16(2):107–120CrossRef
go back to reference Leonard AR, Ward PE (1962) Use of Na/CI ratios to distinguish oil-field from salt-spring brines in Western Oklahoma: U.S. Geological Survey Professional Paper 450-B. p. B126-8127 Leonard AR, Ward PE (1962) Use of Na/CI ratios to distinguish oil-field from salt-spring brines in Western Oklahoma: U.S. Geological Survey Professional Paper 450-B. p. B126-8127
go back to reference Mace RE, Davidson SC, Angle SA, Mullican WF (2006) Aquifers of the Gulf Coast of Texas. Texas Water Development Board, USA Report 365 Mace RE, Davidson SC, Angle SA, Mullican WF (2006) Aquifers of the Gulf Coast of Texas. Texas Water Development Board, USA Report 365
go back to reference Morton AB (1986) Effects of brine on the chemical quality of water in parts of Creek, Lincoln, Okfuskee, Payne, Pottawatomie, and Seminole Counties, Oklahoma. Oklahoma Geol Sur Circul 89:37p Morton AB (1986) Effects of brine on the chemical quality of water in parts of Creek, Lincoln, Okfuskee, Payne, Pottawatomie, and Seminole Counties, Oklahoma. Oklahoma Geol Sur Circul 89:37p
go back to reference Raeisi E, Moore F (1993) Hydrochemistry of Karst spring form two carbonatic units in Zagrosides of Iran. J Sci 4:302–307 Raeisi E, Moore F (1993) Hydrochemistry of Karst spring form two carbonatic units in Zagrosides of Iran. J Sci 4:302–307
go back to reference Raeisi E, Rezaei M (1999) The source of salinity in the Korbal Aquifer, South of Iran. Proceedings of the Water Joint Congress (Brisbane- Australia) 1082–1087 Raeisi E, Rezaei M (1999) The source of salinity in the Korbal Aquifer, South of Iran. Proceedings of the Water Joint Congress (Brisbane- Australia) 1082–1087
go back to reference Riberio L, Macedo ME (1995) Application of multivariate statistics, trend- and cluster analysis to groundwater quality in the Tejo and Sado aquifer. Groundwater Quality: Remediation and Protection (Proceedings of the Prague Conference. 225: 39–47 Riberio L, Macedo ME (1995) Application of multivariate statistics, trend- and cluster analysis to groundwater quality in the Tejo and Sado aquifer. Groundwater Quality: Remediation and Protection (Proceedings of the Prague Conference. 225: 39–47
go back to reference Richter BC, Kreitler CW (1986a) Geochemistry of salt water beneath the Rolling Plains, North-Central Texas. Groundwater 24:735–742CrossRef Richter BC, Kreitler CW (1986a) Geochemistry of salt water beneath the Rolling Plains, North-Central Texas. Groundwater 24:735–742CrossRef
go back to reference Richter BC, Kreitler CW (1986b) Geochemistry of salt-spring and shallow subsurface brines in the Rolling Plains of Texas and southwestern Oklahoma. The University of Texas at Austin, Bureau of Economic Geology Report of Investigations No. 155, p 47 Richter BC, Kreitler CW (1986b) Geochemistry of salt-spring and shallow subsurface brines in the Rolling Plains of Texas and southwestern Oklahoma. The University of Texas at Austin, Bureau of Economic Geology Report of Investigations No. 155, p 47
go back to reference Richter BC, Kreitler CW (1993) Geochemical Techniques for identifying sources of ground-water salinization. CRN Press Inc, Florida Richter BC, Kreitler CW (1993) Geochemical Techniques for identifying sources of ground-water salinization. CRN Press Inc, Florida
go back to reference Richter BC, Dutton AR, Kreitler CW (1990) Identification of sources and mechanisms of saltwater pollution affecting ground-water quality-a case study, West Texas. The University of Texas at Austin, Bureau of Economic Geology Report of Investigations No. 191, p 43 Richter BC, Dutton AR, Kreitler CW (1990) Identification of sources and mechanisms of saltwater pollution affecting ground-water quality-a case study, West Texas. The University of Texas at Austin, Bureau of Economic Geology Report of Investigations No. 191, p 43
go back to reference Rittenhouse G (1967) Bromine in oil-field waters and its use in determining possibilities of origin of these waters. Am Assoc Petr Geol Bull 51:2430–2440 Rittenhouse G (1967) Bromine in oil-field waters and its use in determining possibilities of origin of these waters. Am Assoc Petr Geol Bull 51:2430–2440
go back to reference Sanders LL (1991) Geochemistry of formation waters from the Lower Silurian Clinton formation (lbian, Sandstone), Eastern Ohio. Am Assoc Pet Geol Bull 75:1593–1608 Sanders LL (1991) Geochemistry of formation waters from the Lower Silurian Clinton formation (lbian, Sandstone), Eastern Ohio. Am Assoc Pet Geol Bull 75:1593–1608
go back to reference Sneath PH, Sokal RR (1973) Numerical Taxonomy. W.H.Freeman and Company, San Francisco Sneath PH, Sokal RR (1973) Numerical Taxonomy. W.H.Freeman and Company, San Francisco
go back to reference Sofer Z, Gat JR (1972) Activities and concentrations of oxygen-18 in concentrated aqueous salt solutions: analytical and geophysical implications. Earth Planet Sci Lett 15:232–238CrossRef Sofer Z, Gat JR (1972) Activities and concentrations of oxygen-18 in concentrated aqueous salt solutions: analytical and geophysical implications. Earth Planet Sci Lett 15:232–238CrossRef
go back to reference Stöklin J (1968) Salt deposits of the Middle East. Geol Soc Am Spacial Paper 88:158–181 Stöklin J (1968) Salt deposits of the Middle East. Geol Soc Am Spacial Paper 88:158–181
go back to reference Talbot CJ, Alavi M (1996) The Past of a Future Syntaxis Across the Zagros. Geological Society London Special Publications 100: 89–109 Talbot CJ, Alavi M (1996) The Past of a Future Syntaxis Across the Zagros. Geological Society London Special Publications 100: 89–109
go back to reference Whittemore DO, Pollock LM (1979) Determination of salinity sources in water resources of Kansas by minor alkali metal and halide chemistry. Kansas Water Resources Research Institute, Consultant’s report to Office of Water Research and Technology, U.S; Department of the Interior, Washington, D.C., p 37 Whittemore DO, Pollock LM (1979) Determination of salinity sources in water resources of Kansas by minor alkali metal and halide chemistry. Kansas Water Resources Research Institute, Consultant’s report to Office of Water Research and Technology, U.S; Department of the Interior, Washington, D.C., p 37
go back to reference Zarei M, Raeisi E (2010a) Karst development and hydrogeology of Konarsiah salt diapir, South of Iran. Carbonate Evaporite 25:217–229CrossRef Zarei M, Raeisi E (2010a) Karst development and hydrogeology of Konarsiah salt diapir, South of Iran. Carbonate Evaporite 25:217–229CrossRef
go back to reference Zarei M, Raeisi E (2010b) Conceptual modeling of brine flow into aquifers adjacent to the Konarsiah salt diapir Iran. Cave Karst Sci 37:37–44 Zarei M, Raeisi E (2010b) Conceptual modeling of brine flow into aquifers adjacent to the Konarsiah salt diapir Iran. Cave Karst Sci 37:37–44
go back to reference Zherebtsova II, Volkova NN (1966) Experimental study of behavior of trace elements in the process of natural solar evaporation of Black Sea Water and Sasyk-Sivash brine. Geochem Int 3:656–670 Zherebtsova II, Volkova NN (1966) Experimental study of behavior of trace elements in the process of natural solar evaporation of Black Sea Water and Sasyk-Sivash brine. Geochem Int 3:656–670
Metadata
Title
Identifying sources of salinization using hydrochemical and isotopic techniques, Konarsiah, Iran
Authors
Mehdi Zarei
Ezzat Raeisi
Broder J. Merkel
Nicolai-Alexeji Kummer
Publication date
01-09-2013
Publisher
Springer Berlin Heidelberg
Published in
Environmental Earth Sciences / Issue 2/2013
Print ISSN: 1866-6280
Electronic ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-012-2143-8

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