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Published in: Metals and Materials International 1/2024

26-06-2023

Influence of Mn on the Mechanical and Shape Memory Transformation Behaviours of Powder Metallurgy Processed Cu–Al–Ni SMAs

Authors: M. Muhamed Shafeeq, Hirshikesh, G. K. Gupta, D. P. Mondal

Published in: Metals and Materials International | Issue 1/2024

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Abstract

In this work, a novel powder metallurgy method comprising elemental powder mixing and hot vacuum compaction was used to produce fine-grained Cu–Al–Ni–Mn SMA successfully. The effects of Mn (0–3 wt%) addition and different Al concentrations on the mechanical and shape memory capabilities of powder-processed Cu–Al–Ni SMA were investigated. The formation of different martensitic and secondary phases is characterized by field emission scanning electron microscope, and X-ray diffraction. The addition of Mn improved ductility and decreased phase transformation temperature of the powder-processed SMA, which was confirmed using a three-point bending/tensile test and differential scanning calorimetry analysis.

Graphical Abstract

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Literature
1.
go back to reference A. Ölander, An electrochemical investigation of solid cadmium–gold alloys. J. Am. Chem. Soc. 54(10), 3819–3833 (1932)CrossRef A. Ölander, An electrochemical investigation of solid cadmium–gold alloys. J. Am. Chem. Soc. 54(10), 3819–3833 (1932)CrossRef
2.
go back to reference L. Delaey, Diffusionless Transformations (Wiley, Hoboken, 2013) L. Delaey, Diffusionless Transformations (Wiley, Hoboken, 2013)
3.
go back to reference A.B. Greninger, V.G. Mooradian, Strain transformation in metastable beta copper–zinc and beta copper–tin alloys. Trans. AIME 128, 337–368 (1938) A.B. Greninger, V.G. Mooradian, Strain transformation in metastable beta copper–zinc and beta copper–tin alloys. Trans. AIME 128, 337–368 (1938)
4.
go back to reference J.B. Simões, P.C. Sales da Silva, E.O.S. Montenegro, E.N.D. Grassi, C.J. de Araújo, NiTi shape memory alloy cellular meshes: manufacturing by investment casting and characterization. Smart Mater. Struct. 29, 125008 (2020)CrossRef J.B. Simões, P.C. Sales da Silva, E.O.S. Montenegro, E.N.D. Grassi, C.J. de Araújo, NiTi shape memory alloy cellular meshes: manufacturing by investment casting and characterization. Smart Mater. Struct. 29, 125008 (2020)CrossRef
5.
go back to reference Z. Li, Z.Y. Pan, N. Tang, Y.B. Jiang, N. Liu, M. Fang, F. Zheng, Cu–Al–Ni–Mn shape memory alloy processed by mechanical alloying and powder metallurgy. Mater. Sci. Eng. A 417(2), 225–229 (2006)CrossRef Z. Li, Z.Y. Pan, N. Tang, Y.B. Jiang, N. Liu, M. Fang, F. Zheng, Cu–Al–Ni–Mn shape memory alloy processed by mechanical alloying and powder metallurgy. Mater. Sci. Eng. A 417(2), 225–229 (2006)CrossRef
6.
go back to reference S. Hussain, A. Pandey, R. Dasgupta, Nano-CeO2 doped Cu–Al–Ni SMAs with enhanced mechanical as well as shape recovery characteristics. Metals Mater. Int. 27(6), 1478–1482 (2021)CrossRef S. Hussain, A. Pandey, R. Dasgupta, Nano-CeO2 doped Cu–Al–Ni SMAs with enhanced mechanical as well as shape recovery characteristics. Metals Mater. Int. 27(6), 1478–1482 (2021)CrossRef
7.
go back to reference J.M. Jani, M. Leary, A. Subic, M.A. Gibson, A review of shape memory alloy research, applications and opportunities. Mater. Des. 56, 1078–1113 (2014)CrossRef J.M. Jani, M. Leary, A. Subic, M.A. Gibson, A review of shape memory alloy research, applications and opportunities. Mater. Des. 56, 1078–1113 (2014)CrossRef
8.
go back to reference S. Miyazaki, K. Otsuka, H. Funakuba, Shape Memory Alloys (Gordon & Breach Science, Philadelphia, 1989) S. Miyazaki, K. Otsuka, H. Funakuba, Shape Memory Alloys (Gordon & Breach Science, Philadelphia, 1989)
9.
go back to reference T. Gustmann, J.M. dos Santos, P. Gargarella, U. Kuhn, J. Van Humbeeck, S. Pauly, Properties of Cu-based shape-memory alloys prepared by selective laser melting. Shape Mem. Superelast. 3, 24–36 (2017)CrossRef T. Gustmann, J.M. dos Santos, P. Gargarella, U. Kuhn, J. Van Humbeeck, S. Pauly, Properties of Cu-based shape-memory alloys prepared by selective laser melting. Shape Mem. Superelast. 3, 24–36 (2017)CrossRef
10.
go back to reference U. Sari, Influence of 2.5 wt% Mn addition on the microstructure and mechanical properties of Cu–Al–Ni shape memory alloys. Int. J. Miner. Metall. Mater. 17, 192–198 (2010)CrossRef U. Sari, Influence of 2.5 wt% Mn addition on the microstructure and mechanical properties of Cu–Al–Ni shape memory alloys. Int. J. Miner. Metall. Mater. 17, 192–198 (2010)CrossRef
11.
go back to reference S.N. Saud, T.A.A. Bakar, E. Hamzah, M.K. Ibrahim, A. Bahador, Effect of quarterly element addition of cobalt on phase transformation characteristics of Cu–Al–Ni shape memory alloys. Metall. Mater. Trans. A 46, 3528–3542 (2015)CrossRef S.N. Saud, T.A.A. Bakar, E. Hamzah, M.K. Ibrahim, A. Bahador, Effect of quarterly element addition of cobalt on phase transformation characteristics of Cu–Al–Ni shape memory alloys. Metall. Mater. Trans. A 46, 3528–3542 (2015)CrossRef
12.
go back to reference R. Dasgupta, A.K. Jain, P. Kumar, S. Hussain, A. Pandey, Role of alloying additions on the properties of Cu–Al–Mn shape memory alloys. J. Alloys Compd. 620(1), 60–66 (2015)CrossRef R. Dasgupta, A.K. Jain, P. Kumar, S. Hussain, A. Pandey, Role of alloying additions on the properties of Cu–Al–Mn shape memory alloys. J. Alloys Compd. 620(1), 60–66 (2015)CrossRef
13.
go back to reference C.Y. Chung, K.L. Lai, W.H. Zou, C.W.H. Lam, Microstructural studies of a Cu–Zn–Al shape-memory alloy with manganese and zirconium addition. Metall. Mater. Trans. 29, 1865–1871 (1998)CrossRef C.Y. Chung, K.L. Lai, W.H. Zou, C.W.H. Lam, Microstructural studies of a Cu–Zn–Al shape-memory alloy with manganese and zirconium addition. Metall. Mater. Trans. 29, 1865–1871 (1998)CrossRef
14.
go back to reference R.A.G. Silva, A. Paganotti, S. Gama, A.T. Adorno, T.M. Carvalho, C.M.A. Santos, Investigation of thermal, mechanical and magnetic behaviors of the Cu-11%Al alloy with Ag and Mn additions. Mater. Charact. 75, 194–199 (2013) R.A.G. Silva, A. Paganotti, S. Gama, A.T. Adorno, T.M. Carvalho, C.M.A. Santos, Investigation of thermal, mechanical and magnetic behaviors of the Cu-11%Al alloy with Ag and Mn additions. Mater. Charact. 75, 194–199 (2013)
15.
go back to reference M.A. Morris, T. Lipe, Microstructural influence of Mn additions on thermoelastic and pseudoelastic properties of Cu–Al–Ni alloys. Acta Metall. Mater. 42, 1583–1594 (1994) M.A. Morris, T. Lipe, Microstructural influence of Mn additions on thermoelastic and pseudoelastic properties of Cu–Al–Ni alloys. Acta Metall. Mater. 42, 1583–1594 (1994)
16.
go back to reference S.N. Saud, E. Hamzah, T. Abubakar, H.R. Bakhsheshi-Rad, M. Zamri, M. Tanemura, Effects of Mn additions on the structure, mechanical properties, and corrosion behavior of Cu–Al–Ni shape memory alloys. J. Mater. Eng. Perform. 23, 3620–3629 (2014)CrossRef S.N. Saud, E. Hamzah, T. Abubakar, H.R. Bakhsheshi-Rad, M. Zamri, M. Tanemura, Effects of Mn additions on the structure, mechanical properties, and corrosion behavior of Cu–Al–Ni shape memory alloys. J. Mater. Eng. Perform. 23, 3620–3629 (2014)CrossRef
17.
go back to reference J. Mentz, J. Frenzel, M.F.-X. Wagner, K. Neuking, G. Eggeler, H.P. Buchkremer, D. Stöver, Powder metallurgical processing of NiTi shape memory alloys with elevated transformation temperatures. Mater. Sci. Eng. A 491, 270–278 (2008) J. Mentz, J. Frenzel, M.F.-X. Wagner, K. Neuking, G. Eggeler, H.P. Buchkremer, D. Stöver, Powder metallurgical processing of NiTi shape memory alloys with elevated transformation temperatures. Mater. Sci. Eng. A 491, 270–278 (2008)
18.
go back to reference R.D. Jean, T.Y. Wu, S.S. Leu, The effect of powder metallurgy on Cu–Al–Ni shape memory alloys. Scr. Metall. Mater. 25, 883–888 (1991) R.D. Jean, T.Y. Wu, S.S. Leu, The effect of powder metallurgy on Cu–Al–Ni shape memory alloys. Scr. Metall. Mater. 25, 883–888 (1991)
19.
go back to reference S.M. Tang, C.Y. Chung, W.G. Liu, Preparation of CuAlNi-based shape memory alloys by mechanical alloying and powder metallurgy method. J. Mater. Process. Technol. 63, 307–312 (1997) S.M. Tang, C.Y. Chung, W.G. Liu, Preparation of CuAlNi-based shape memory alloys by mechanical alloying and powder metallurgy method. J. Mater. Process. Technol. 63, 307–312 (1997)
20.
go back to reference S.K. Vajpai, R.K. Dubey, S. Sangal, Processing and characterization of Cu–Al–Ni shape memory alloy strips prepared from prealloyed powder by hot densification rolling of powder preforms. Metall. Mater. Trans. A 42, 3178–3189 (2011)CrossRef S.K. Vajpai, R.K. Dubey, S. Sangal, Processing and characterization of Cu–Al–Ni shape memory alloy strips prepared from prealloyed powder by hot densification rolling of powder preforms. Metall. Mater. Trans. A 42, 3178–3189 (2011)CrossRef
21.
go back to reference L.J. Grossi, G. Reinke, T.C. da Silva, D.M. Rosa, P.V. Muterlle, Study of the influence of high-energy milling time on the Cu–13Al–4Ni alloy manufactured by powder metallurgy process. J. Braz. Soc. Mech. Sci. Eng. 43(1), 44 (2021)CrossRef L.J. Grossi, G. Reinke, T.C. da Silva, D.M. Rosa, P.V. Muterlle, Study of the influence of high-energy milling time on the Cu–13Al–4Ni alloy manufactured by powder metallurgy process. J. Braz. Soc. Mech. Sci. Eng. 43(1), 44 (2021)CrossRef
22.
go back to reference L.D. Gulay, B. Harbrecht, The crystal structure of \(\zeta\)1-Al3Cu4. J. Alloys Compd. 367(1–2), 103–108 (2004)CrossRef L.D. Gulay, B. Harbrecht, The crystal structure of \(\zeta\)1-Al3Cu4. J. Alloys Compd. 367(1–2), 103–108 (2004)CrossRef
23.
go back to reference U.S. Mallik, V. Sampath, Influence of aluminum and manganese concentration on the shape memory characteristics of Cu–Al–Mn shape memory alloys. J. Alloys Compd. 459(1–2), 142–147 (2008)CrossRef U.S. Mallik, V. Sampath, Influence of aluminum and manganese concentration on the shape memory characteristics of Cu–Al–Mn shape memory alloys. J. Alloys Compd. 459(1–2), 142–147 (2008)CrossRef
Metadata
Title
Influence of Mn on the Mechanical and Shape Memory Transformation Behaviours of Powder Metallurgy Processed Cu–Al–Ni SMAs
Authors
M. Muhamed Shafeeq
Hirshikesh
G. K. Gupta
D. P. Mondal
Publication date
26-06-2023
Publisher
The Korean Institute of Metals and Materials
Published in
Metals and Materials International / Issue 1/2024
Print ISSN: 1598-9623
Electronic ISSN: 2005-4149
DOI
https://doi.org/10.1007/s12540-023-01486-8

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