Top

Topics in Catalysis

Published in:

01-04-2009 | Original Paper

Influence of Preparation Parameters on the Performance of Colloid-derived Oxidic Palladium Catalysts for Selective Hydrogenation of C–C Triple Bonds

Authors: Florian Klasovsky, Peter Claus, Dorit Wolf

Published in: Topics in Catalysis | Issue 4/2009

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

(Hydr-) oxidic PdO_xH_y colloids were prepared by H₂PdCl₄ hydrolysis in presence of poly(vinylpyrrolidone) under pH control. After immobilization, the resulting catalysts show a high chemo- and stereo selectivity in the hydrogenation of C–C triple bonds. Systematic investigations of the preparation parameters indicate that the hydrolysis pH, the PVP amount and chainlength as well as the colloid aging time are of major importance for catalytic performance.

previous article Metal Nanocrystals Embedded within Polymeric Nanostructures: Effect of Polymer-Metal Compound Interactions

next article Reducibility of Platinum Supported on Nanostructured Carbons

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Schmidt F (2001) Appl Catal A Gen 221:15CrossRef

Lindlar H (1952) Helv Chim Acta 35:446CrossRef

Palczewska W, Jablonski A, Kaszkur Z, Zuba G, Wernisch J (1984) J Mole Catal 25:307CrossRef

Mallat T, Szabo S, Petro J (1987) Appl Catal 29:117CrossRef

Stachurski J, Thomas JM (1988) Catal Lett 1:67CrossRef

Bönnemann H et al (1997) Appl Organomet Chem 11:783CrossRef

Sobczak JW, Lesiak B, Jablónsi A, Kosinski A, Palczewska W (1995) Polish J Chem 69:1732

Mastalir A, Rac B, Kiraly Z, Molnar A (2007) J Mol Catal A Chem 264:170CrossRef

Mastalir A, Papp A, Molnar A (2005) Appl Catal A Gen 289:256CrossRef

10.

Heineke D, Schwab E, Fischer M, Schmid G, Baeumle M (1999) EP920912

11.

Bönnemann H, Brijoux W, Brinkmann R, Richter J (1996) DE4443705

12.

Hoffmann H et al (1976) DE2431929

13.

Kiwi-Minsker L, Semagina N, Renken A (2007) Chem Eng Sci 62:5344CrossRef

14.

Kiwi-Minsker L, Semagina N, Renken A (2007) J Phys Chem C 111:13933CrossRef

15.

Kiwi-Minsker L, Semagina N, Renken A, Laub D (2007) J Catal 246:308CrossRef

16.

L’Argentiere PC, Lederhos CR, Figoli NS (2005) Ind Eng Chem Res 44:1752CrossRef

17.

Sulman E et al (1999) Appl Catal A Gen 176:75CrossRef

18.

L’Argentiere PC, Cagnola EA, Quiroga ME, Liprandi DA (2002) Appl Catal A Gen 226:253CrossRef

19.

Teschner D et al (2006) J Catal 242:26CrossRef

20.

Ghosh AK, Krishnan K (1998) Tetrahedron Lett 39:947CrossRef

21.

Righi G, Rossi L (1996) Synth Commun 26:1321CrossRef

22.

Reddy PG, Pratap TV, Kumar GDK, Mohanty SK, Baskaran S (2002) Eur J Organ Chem 2002:3740CrossRef

23.

Adams R, Carothers W (1923) J Am Chem Soc 45:1071CrossRef

24.

Adams R, Tuley W (1925) J Am Chem Soc 47:3061CrossRef

25.

Adams R, Voorhees V (1922) J Am Chem Soc 44:1397CrossRef

26.

Caldararu M et al (2007) Appl Catal A Gen 316:250CrossRef

27.

Fisher JM (2005) WO2005123255

28.

Hasegawa K, Sakurai T (2002) EP1238700

29.

Hoflund GB, Oh S-H (2007) J Catal 245:35CrossRef

30.

Wada K, Yano K, Kondo T, Mitsudo T-a (2006) Catal Today 117:242CrossRef

31.

Blanco Alvarez J, Avila Garcia P, Chacon Larios C, Ramos Jimenez JM (2007) WO2007057496

32.

Kirkpatrick WJ (1941) US2259423

33.

Martin RW (1940) US2207868

34.

Bradley J (1994) In: Schmid G (ed) Clusters and colloids: from theory to applications. VCH, Weinheim, New York, pp 459–542CrossRef

35.

Bradley JS, Le Bars J, Specht U, Blackmond DG (1999) Langmuir 15:7621CrossRef

36.

Thiebault B (2004) Platinum Met Rev 48:62

37.

Yu WW, Liu H (2006) J Mol Catal A Chem 243:120CrossRef

38.

Corain B et al (2005) J Mol Catal A Chem 225:189CrossRef

39.

Beletskaya IP et al (2006) Organometallics 25:154CrossRef

40.

Bronstein LM et al (2000) Langmuir 16:3626CrossRef

41.

Antonietti M et al (1997) J Am Chem Soc 119:10116CrossRef

42.

Fan QH et al (2006) Org Lett 8:3605CrossRef

43.

El-Sayed MA, Li Y (2001) J Phys Chem B 105:8938CrossRef

44.

Crooks RM, Ye H, Scott RWJ (2004) Langmuir 20:2915CrossRef

45.

Swihart M, Yong K, Sahoo Y, Prasad P (2006) Adv Mater 18:1978CrossRef

46.

Toshima N et al (2001) Appl Organomet Chem 15:178CrossRef

47.

Stenius P, Kizling J, Boutonnet-Kizling M, Touroude R, Maire G (1992) In: Mackay RA, Texter J (eds) Electrochemistry in colloids and dispersion. VCH Publishers, Inc, New York, pp 333–344

48.

Reetz M, Lopez M (2003) DE10211701 A1

49.

Reetz M, Lopez M (2003) WO03/078056 A1

50.

Reetz MT, Koch MG (1999) J Am Chem Soc 121:7933CrossRef

51.

Reetz MT, Koch MG (2000) DE19852547

52.

Reetz MT, Lopez M (2003) WO2003078056

53.

Koch M (1999) Dissertation

54.

Lopez M (2001) Dissertation, Ruhr-Universität

55.

Krein M (2002) Ruhr-Universität

56.

Brunauer S, Emmett PH, Teller E (1938) J Am Chem Soc 60:309CrossRef

57.

Barrett E, Joyner L, Halenda P (1951) J Am Chem Soc 73:373CrossRef

58.

Wagner CD (1990) In: Briggs D, Seah MP (eds) Practical surface analysis, vol 1. Wiley, Chichester, p 597

59.

Pal T et al (2005) Langmuir 21:10405CrossRef

60.

Didillon B, Merlen E, Pages T, Uzio D (1998) Stud Surf Sci Catal 118:41CrossRef

61.

Liu H, He B, Ha Y, Wang K, Liew KY (2007) J Colloid Interface Sci 308:105CrossRef

62.

Xia Y, Washio I, Xiong Y, Yin Y (2006) Adv Mater 18:1745CrossRef

63.

Bogatyrev VM, Borisenko NV, Pokrovskii VA (2001) Russ J Appl Chem 74:839CrossRef

64.

Germer LH, White AH (1941) Phys Rev 60:447CrossRef

65.

Debye P (1915) Ann Phys 46:809CrossRef

66.

Shaoping X, Chunlan L, Yixiong G, Shuqin L, Changhou L (2005) Carbon 43:2295CrossRef

67.

Du YK, Yang P, Mou ZG, Hua NP, Jiang L (2006) J Appl Polym Sci 99:23CrossRef

68.

NIST X-ray photoelectron spectroscopy database 20, version 3.4

69.

Maier WF, Ulan JG, Kuo E, Rai RS, Thomas G (1987) J Org Chem 52:3126CrossRef

70.

Bradley JS et al (1999) Langmuir 15:5333CrossRef

Title: Influence of Preparation Parameters on the Performance of Colloid-derived Oxidic Palladium Catalysts for Selective Hydrogenation of C–C Triple Bonds
Authors: Florian Klasovsky
Peter Claus
Dorit Wolf
Publication date: 01-04-2009
Publisher: Springer US
Published in: Topics in Catalysis / Issue 4/2009
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-008-9173-1

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 4/2009

Molecular-Level Characterization of Heterogeneous Catalytic Systems by Algorithmic Time Dependent Monte Carlo

Synthesis of Ru-modified MCM-41 Mesoporous Material, Y and Beta Zeolite Catalysts for Ring Opening of Decalin

X-Ray Photoelectron Spectroscopy Investigation of Pd-Beta Zeolite Catalysts with Different Acidities

Reducibility of Platinum Supported on Nanostructured Carbons

Interplay Between the Active Phase and Support: Preparation, Characterization and Catalytic Performance

Structural and Kinetic DFT Characterization of Materials to Rationalize Catalytic Performance

Premium Partners