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Published in: Journal of Nanoparticle Research 11/2012

01-11-2012 | Research Paper

Inkjet-printed silver nanoparticles on nano-engineered cellulose films for electrically conducting structures and organic transistors: concept and challenges

Authors: Gary Chinga-Carrasco, Daniel Tobjörk, Ronald Österbacka

Published in: Journal of Nanoparticle Research | Issue 11/2012

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Abstract

This study explores the suitability of microfibrillated cellulose (MFC) films as a substrate for printing electrically conductive structures and multilayer electronic structures such as organic field effect transistors. Various MFC qualities were tested, including mechanically produced MFC, 2,2,6,6-tetramethylpiperidinyl-1-oxyl pre-treated MFC and carboxymethylated-MFC. The films differed significantly with respect to the surface structure. In addition, the carboxymethylated-MFC films were surface modified with hexamethyldisilazane (HMDS) to reduce the water-wettability of the films, and thus, improve the print resolution of the inkjet-printed silver (Ag) nanoparticles. The Ag-particles (diameter < 50 nm) were printed on the HMDS-modified films, which were mainly composed of nanofibrils with diameters <20 nm. The effect of surface roughness and surface chemical characteristics on the ink spreading and print resolution of the Ag-structures was explored. It was demonstrated that organic transistors operating at low voltages can be fabricated on nano-engineered MFC films.

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Literature
go back to reference Abe K, Yano H (2011) Formation of hydrogels from cellulose nanofibers. Carbohydr Polym 85:733–737CrossRef Abe K, Yano H (2011) Formation of hydrogels from cellulose nanofibers. Carbohydr Polym 85:733–737CrossRef
go back to reference Ahola S, Österberg M, Laine J (2008) Cellulose nanofibrils—adsorption with poly(amideamine) epichlorohydrin studied by QCM-D and application as a paper strength additive. Cellulose 15:303–314CrossRef Ahola S, Österberg M, Laine J (2008) Cellulose nanofibrils—adsorption with poly(amideamine) epichlorohydrin studied by QCM-D and application as a paper strength additive. Cellulose 15:303–314CrossRef
go back to reference Andersson P, Nilsson D, Svensson P-O, Chen M, Malmström A, Remonen T, Kugler T, Berggren M (2002) Active matrix displays based on all-organic electrochemical smart pixels printed on paper. Adv Mater 14:1460–1464CrossRef Andersson P, Nilsson D, Svensson P-O, Chen M, Malmström A, Remonen T, Kugler T, Berggren M (2002) Active matrix displays based on all-organic electrochemical smart pixels printed on paper. Adv Mater 14:1460–1464CrossRef
go back to reference Aulin C, Netrval J, Wågberg L, Lindström T (2010a) Aerogels from nanofibrillated cellulose with tunable oleophobicity. Soft Matter 6:3298–3305CrossRef Aulin C, Netrval J, Wågberg L, Lindström T (2010a) Aerogels from nanofibrillated cellulose with tunable oleophobicity. Soft Matter 6:3298–3305CrossRef
go back to reference Aulin C, Gällstedt M, Lindström T (2010b) Oxygen and oil barrier properties of microfibrillated cellulose films and coatings. Cellulose 17:559–574CrossRef Aulin C, Gällstedt M, Lindström T (2010b) Oxygen and oil barrier properties of microfibrillated cellulose films and coatings. Cellulose 17:559–574CrossRef
go back to reference Bacon WS (1968) Now they’re printing transistors on paper. Pop Sci 193:124–125 Bacon WS (1968) Now they’re printing transistors on paper. Pop Sci 193:124–125
go back to reference Barr MC, Rowehl JA, Lunt RR, Xu J, Wang A, Boyce CM, Gap Im S, Bulovic V, Gleason KK (2011) Direct monolithic integration of organic photovoltaic circuits on unmodified paper. Adv Mater 23:3500–3505CrossRef Barr MC, Rowehl JA, Lunt RR, Xu J, Wang A, Boyce CM, Gap Im S, Bulovic V, Gleason KK (2011) Direct monolithic integration of organic photovoltaic circuits on unmodified paper. Adv Mater 23:3500–3505CrossRef
go back to reference Bollström R, Määttänen A, Tobjörk D, Ihalainen P, Kaihovirta N, Österbacka R, Peltonen J, Toivakka M (2009) A multilayer coated fiber-based substrate suitable for printed functionality. Org Electron 10:1020–1023CrossRef Bollström R, Määttänen A, Tobjörk D, Ihalainen P, Kaihovirta N, Österbacka R, Peltonen J, Toivakka M (2009) A multilayer coated fiber-based substrate suitable for printed functionality. Org Electron 10:1020–1023CrossRef
go back to reference Chinga-Carrasco G (2011) Cellulose fibres, nanofibrils and microfibrils: the morphological sequence of MFC components from a plant physiology and fibre technology point of view. Nanoscale Res Lett 6:417CrossRef Chinga-Carrasco G (2011) Cellulose fibres, nanofibrils and microfibrils: the morphological sequence of MFC components from a plant physiology and fibre technology point of view. Nanoscale Res Lett 6:417CrossRef
go back to reference Chinga-Carrasco G, Syverud K (2010) Computer-assisted quantification of the multiscale structure of films made of nanofibrillated cellulose. J Nanopart Res 12(3):841–851CrossRef Chinga-Carrasco G, Syverud K (2010) Computer-assisted quantification of the multiscale structure of films made of nanofibrillated cellulose. J Nanopart Res 12(3):841–851CrossRef
go back to reference Chinga-Carrasco G, Syverud K (2012) On the structure and oxygen transmission rate of biodegradable cellulose nanobarriers. Nanoscale Res Lett 7:192CrossRef Chinga-Carrasco G, Syverud K (2012) On the structure and oxygen transmission rate of biodegradable cellulose nanobarriers. Nanoscale Res Lett 7:192CrossRef
go back to reference Chinga-Carrasco G, Yu Y, Diserud O (2011) Quantitative electron microscopy of cellulose nanofibril structures from Eucalyptus and Pinus radiata kraft pulp fibres. Microsc Microanal 17:563–571CrossRef Chinga-Carrasco G, Yu Y, Diserud O (2011) Quantitative electron microscopy of cellulose nanofibril structures from Eucalyptus and Pinus radiata kraft pulp fibres. Microsc Microanal 17:563–571CrossRef
go back to reference Chinga-Carrasco G, Kuznetsova N, Garaeva M, Leirset I, Galiullina G, Kostochko A, Syverud K (2012) Bleached and unbleached MFC nanobarriers—properties and hydrophobization with hexamethyldisilazane. J Nanopart Res (Revision being processed) Chinga-Carrasco G, Kuznetsova N, Garaeva M, Leirset I, Galiullina G, Kostochko A, Syverud K (2012) Bleached and unbleached MFC nanobarriers—properties and hydrophobization with hexamethyldisilazane. J Nanopart Res (Revision being processed)
go back to reference Eeder F, Klauk H, Halik M, Zschieschang U, Schmid G, Dehm C (2004) Organic electronics on paper. Appl Phys Lett 84:2673CrossRef Eeder F, Klauk H, Halik M, Zschieschang U, Schmid G, Dehm C (2004) Organic electronics on paper. Appl Phys Lett 84:2673CrossRef
go back to reference Eichhorn SJ, Dufresne A, Aranguren M, Marcovich NE, Capadona JR, Rowan SS, Weder C, Thielemans W, Roman M, Renneckar S, Gindl W, Veigel S, Keckes J, Yano H, Abe K, Nogi M, Nakagaito AN, Mangalam A, Simonsen J, Benight AS, Bismark A, Berglund LA, Peijs T (2010) Review: current international research into cellulose nanofibres and nanocomposites. J Mater Sci 45(1):1–33CrossRef Eichhorn SJ, Dufresne A, Aranguren M, Marcovich NE, Capadona JR, Rowan SS, Weder C, Thielemans W, Roman M, Renneckar S, Gindl W, Veigel S, Keckes J, Yano H, Abe K, Nogi M, Nakagaito AN, Mangalam A, Simonsen J, Benight AS, Bismark A, Berglund LA, Peijs T (2010) Review: current international research into cellulose nanofibres and nanocomposites. J Mater Sci 45(1):1–33CrossRef
go back to reference Eriksen Ø, Syverud K, Gregersen Ø (2008) The use of microfibrillated cellulose produced from kraft pulp as a strength enhancer in TMP paper. Nord Pulp Pap Res J 23(3):299–304CrossRef Eriksen Ø, Syverud K, Gregersen Ø (2008) The use of microfibrillated cellulose produced from kraft pulp as a strength enhancer in TMP paper. Nord Pulp Pap Res J 23(3):299–304CrossRef
go back to reference Frey-Wyssling A (1954) The fine structure of cellulose microfibrils. Science 119:80–82CrossRef Frey-Wyssling A (1954) The fine structure of cellulose microfibrils. Science 119:80–82CrossRef
go back to reference Fukuzumi H, Saito T, Iwata T, Kumamoto Y, Isogai A (2009) Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation. Biomacromolecules 10(1):162–165CrossRef Fukuzumi H, Saito T, Iwata T, Kumamoto Y, Isogai A (2009) Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation. Biomacromolecules 10(1):162–165CrossRef
go back to reference Henriksson M, Berglund LA, Isaksson P, Lindström T, Nishino T (2008) Cellulose nanopaper structures of high toughness. Biomacromolecules 9(6):1579–1585CrossRef Henriksson M, Berglund LA, Isaksson P, Lindström T, Nishino T (2008) Cellulose nanopaper structures of high toughness. Biomacromolecules 9(6):1579–1585CrossRef
go back to reference Hübler A, Trnovec B, Zillger T, Ali M, Wetzold N, Mingebach M, Wagenpfahl A, Deibel C, Dyakonov V (2011) Printed paper photovoltaic cells. Adv Energy Mater 1(6):1018–1022CrossRef Hübler A, Trnovec B, Zillger T, Ali M, Wetzold N, Mingebach M, Wagenpfahl A, Deibel C, Dyakonov V (2011) Printed paper photovoltaic cells. Adv Energy Mater 1(6):1018–1022CrossRef
go back to reference Khan MA, Bhansali US, Alshareef HN (2012) High-performance non-volatile organic ferroelectric memory on banknotes. Adv Mater 24:2165–2170CrossRef Khan MA, Bhansali US, Alshareef HN (2012) High-performance non-volatile organic ferroelectric memory on banknotes. Adv Mater 24:2165–2170CrossRef
go back to reference Kim D-H, Kim Y-S, Wu J, Liu Z, Song J, Kim H-S, Huang YY, Hwang K-C, Rogers JA (2009) Ultrathin silicon circuits with strain-isolation layers and mesh layouts for high-performance electronics on fabric, vinyl, leather, and paper. Adv Mater 21:3703–3707CrossRef Kim D-H, Kim Y-S, Wu J, Liu Z, Song J, Kim H-S, Huang YY, Hwang K-C, Rogers JA (2009) Ultrathin silicon circuits with strain-isolation layers and mesh layouts for high-performance electronics on fabric, vinyl, leather, and paper. Adv Mater 21:3703–3707CrossRef
go back to reference Lif A, Stenstad P, Syverud K, Nydén M, Holmberg K (2010) Fischer–Tropsch diesel emulsions stabilised by microfibrillated cellulose. J Colloid Int Sci 352(2):585–592CrossRef Lif A, Stenstad P, Syverud K, Nydén M, Holmberg K (2010) Fischer–Tropsch diesel emulsions stabilised by microfibrillated cellulose. J Colloid Int Sci 352(2):585–592CrossRef
go back to reference Lindblad M, Root A (1998) Atomically controlled preparation of silica on alumina. Stud Surf Sci Catal 118:817CrossRef Lindblad M, Root A (1998) Atomically controlled preparation of silica on alumina. Stud Surf Sci Catal 118:817CrossRef
go back to reference Martins R, Nathan A, Barros R, Pereira L, Barquinha P, Correia N, Ahnood A, Ferreira I, Fortunato E (2011) Complementary metal oxide semi-conductor technology with and on paper. Adv Mater 23:4491–4496CrossRef Martins R, Nathan A, Barros R, Pereira L, Barquinha P, Correia N, Ahnood A, Ferreira I, Fortunato E (2011) Complementary metal oxide semi-conductor technology with and on paper. Adv Mater 23:4491–4496CrossRef
go back to reference Meier H (1962) Chemical and morphological aspects of the fine structure of wood. Pure Appl Chem 5:37–52CrossRef Meier H (1962) Chemical and morphological aspects of the fine structure of wood. Pure Appl Chem 5:37–52CrossRef
go back to reference Mörseburg K, Chinga-Carrasco G (2009) Assessing the combined benefits of clay and nanofibrillated cellulose in layered TMP-based sheets. Cellulose 16(5):795–806CrossRef Mörseburg K, Chinga-Carrasco G (2009) Assessing the combined benefits of clay and nanofibrillated cellulose in layered TMP-based sheets. Cellulose 16(5):795–806CrossRef
go back to reference Pääkkö M, Ankefors M, Kosonen H, Nykänen A, Ahola S, Österberg M, Ruokolainen J, Laine J, Larsson PT, Ikkala O, Lindström T (2007) Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. Biomacromolecules 8(6):1934–1941CrossRef Pääkkö M, Ankefors M, Kosonen H, Nykänen A, Ahola S, Österberg M, Ruokolainen J, Laine J, Larsson PT, Ikkala O, Lindström T (2007) Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. Biomacromolecules 8(6):1934–1941CrossRef
go back to reference Rodionova G, Lenes M, Eriksen Ø, Gregersen Ø (2011) Surface chemical modification of microfibrillated cellulose: improvement of barrier properties for packaging applications. Cellulose 18(1):127–134CrossRef Rodionova G, Lenes M, Eriksen Ø, Gregersen Ø (2011) Surface chemical modification of microfibrillated cellulose: improvement of barrier properties for packaging applications. Cellulose 18(1):127–134CrossRef
go back to reference Saito T, Nishiyama Y, Putaux JL, Vignon M, Isogai A (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules 7(6):1687–1691CrossRef Saito T, Nishiyama Y, Putaux JL, Vignon M, Isogai A (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules 7(6):1687–1691CrossRef
go back to reference Saito T, Hirota M, Tamura N, Kimura S, Fukuzumi H, Heux L, Isogai A (2009) Individualization of nano-sized plant cellulose fibrils by direct surface carboxylation using TEMPO catalyst under neutral conditions. Biomacromolecules 10(6):1992–1996CrossRef Saito T, Hirota M, Tamura N, Kimura S, Fukuzumi H, Heux L, Isogai A (2009) Individualization of nano-sized plant cellulose fibrils by direct surface carboxylation using TEMPO catalyst under neutral conditions. Biomacromolecules 10(6):1992–1996CrossRef
go back to reference Siegel AC, Phillips ST, Dickey MD, Lu N, Suo Z, Whitesides GM (2010) Foldable printed circuit boards on paper substrates. Adv Funct Mater 20:28–35CrossRef Siegel AC, Phillips ST, Dickey MD, Lu N, Suo Z, Whitesides GM (2010) Foldable printed circuit boards on paper substrates. Adv Funct Mater 20:28–35CrossRef
go back to reference Singh M, Haverinen HM, Dhagat P, Jabbour GE (2010) Inkjet printing—process and its applications. Adv Mater 22:673–685CrossRef Singh M, Haverinen HM, Dhagat P, Jabbour GE (2010) Inkjet printing—process and its applications. Adv Mater 22:673–685CrossRef
go back to reference Siró I, Plackett D (2010) Microfibrillated cellulose and new nanocomposite materials: a review. Cellulose 17(3):459–494CrossRef Siró I, Plackett D (2010) Microfibrillated cellulose and new nanocomposite materials: a review. Cellulose 17(3):459–494CrossRef
go back to reference Siró I, Plackett D, Hedenqvist M, Ankerfors M, Lindström T (2011) Highly transparent films from carboxymethylated microfibrillated cellulose: the effect of multiple homogenization steps on key properties. J Appl Polym Sci 119(5):2652–2660CrossRef Siró I, Plackett D, Hedenqvist M, Ankerfors M, Lindström T (2011) Highly transparent films from carboxymethylated microfibrillated cellulose: the effect of multiple homogenization steps on key properties. J Appl Polym Sci 119(5):2652–2660CrossRef
go back to reference Sirringhaus H, Kawase T, Friend RH, Shimoda T, Inbasekaran M, Wu W, Woo EP (2000) High-resolution inkjet printing of all-polymer transistor circuits. Science 290:2123–2126CrossRef Sirringhaus H, Kawase T, Friend RH, Shimoda T, Inbasekaran M, Wu W, Woo EP (2000) High-resolution inkjet printing of all-polymer transistor circuits. Science 290:2123–2126CrossRef
go back to reference Soltman D, Subramanian V (2008) Inkjet-printed line morphologies and temperature control of the coffee ring effect. Langmuir 24:2224–2231CrossRef Soltman D, Subramanian V (2008) Inkjet-printed line morphologies and temperature control of the coffee ring effect. Langmuir 24:2224–2231CrossRef
go back to reference Syverud K, Stenius P (2009) Strength and barrier properties of MFC films. Cellulose 16(1):75–85CrossRef Syverud K, Stenius P (2009) Strength and barrier properties of MFC films. Cellulose 16(1):75–85CrossRef
go back to reference Syverud K, Chinga-Carrasco G, Toledo J, Toledo P (2010) A comparative study of Eucalyptus and Pinus radiata pulp fibres as raw materials for production of cellulose nanofibrils. Carbohydr Polym 84(3):1033–1038CrossRef Syverud K, Chinga-Carrasco G, Toledo J, Toledo P (2010) A comparative study of Eucalyptus and Pinus radiata pulp fibres as raw materials for production of cellulose nanofibrils. Carbohydr Polym 84(3):1033–1038CrossRef
go back to reference Syverud K, Kirsebom H, Hajizadeh S, Chinga-Carrasco G (2011) Cross-linking cellulose nanofibrils for potential elastic cryo-structured gels. Nanoscale Res Lett 6:626CrossRef Syverud K, Kirsebom H, Hajizadeh S, Chinga-Carrasco G (2011) Cross-linking cellulose nanofibrils for potential elastic cryo-structured gels. Nanoscale Res Lett 6:626CrossRef
go back to reference Tanaka R, Saito T, Isogai A (2012) Cellulose nanofibrils prepared from softwood cellulose by TEMPO/NaClO/NaClO(2) systems in water at pH 4.8 or 6.8. Int J Biol Macromol 51(3):228–234CrossRef Tanaka R, Saito T, Isogai A (2012) Cellulose nanofibrils prepared from softwood cellulose by TEMPO/NaClO/NaClO(2) systems in water at pH 4.8 or 6.8. Int J Biol Macromol 51(3):228–234CrossRef
go back to reference Tasaltin N, Sanli D, Jonáš A, Kiraz A, Erkey C (2011) Preparation and characterization of superhydrophobic surfaces based on hexamethyldisilazane-modified nanoporous alumina. Nanoscale Res Lett 6:487CrossRef Tasaltin N, Sanli D, Jonáš A, Kiraz A, Erkey C (2011) Preparation and characterization of superhydrophobic surfaces based on hexamethyldisilazane-modified nanoporous alumina. Nanoscale Res Lett 6:487CrossRef
go back to reference Tekin E, Smith PJ, Schubert US (2008) Inkjet printing as a deposition and patterning tool for polymers and inorganic particles. Soft Matter 4:703–713CrossRef Tekin E, Smith PJ, Schubert US (2008) Inkjet printing as a deposition and patterning tool for polymers and inorganic particles. Soft Matter 4:703–713CrossRef
go back to reference Tobjörk D, Österbacka R (2011) Paper electronics. Adv Mater 23:1935–1961CrossRef Tobjörk D, Österbacka R (2011) Paper electronics. Adv Mater 23:1935–1961CrossRef
go back to reference Trnovec B, Stanel M, Hahn U, Hübler AC, Kempa H, Sangl R, Forster M (2009) Coated paper for printed electronics. Prof Papermak 6:48–51 Trnovec B, Stanel M, Hahn U, Hübler AC, Kempa H, Sangl R, Forster M (2009) Coated paper for printed electronics. Prof Papermak 6:48–51
go back to reference van Osch THJ, Perelaer J, De Laat AWM, Schubert US (2008) Inkjet printing of narrow conductive tracks on untreated polymeric substrates. Adv Mater 20:343–345CrossRef van Osch THJ, Perelaer J, De Laat AWM, Schubert US (2008) Inkjet printing of narrow conductive tracks on untreated polymeric substrates. Adv Mater 20:343–345CrossRef
go back to reference Wågberg L, Decher G, Norgren M, Lindström T, Ankerfors M, Axnäs K (2008) The build-up of polyelectrolyte multilayers of microfibrillated cellulose and cationic polyelectrolytes. Langmuir 24(3):784–795CrossRef Wågberg L, Decher G, Norgren M, Lindström T, Ankerfors M, Axnäs K (2008) The build-up of polyelectrolyte multilayers of microfibrillated cellulose and cationic polyelectrolytes. Langmuir 24(3):784–795CrossRef
go back to reference Xhanari K, Syverud K, Stenius P (2011) Emulsions stabilized by microfibrillated cellulose: the effect of hydrophobization, concentration and o/w ratio. J Dispers Sci Technol 32(3):447–452CrossRef Xhanari K, Syverud K, Stenius P (2011) Emulsions stabilized by microfibrillated cellulose: the effect of hydrophobization, concentration and o/w ratio. J Dispers Sci Technol 32(3):447–452CrossRef
go back to reference Zschieschang U, Yamamoto T, Takimiya K, Kuwabara H, Ikeda M, Sekitani T, Someya T, Klauk H (2011) Organic electronics on banknotes. Adv Mater 23:654–658CrossRef Zschieschang U, Yamamoto T, Takimiya K, Kuwabara H, Ikeda M, Sekitani T, Someya T, Klauk H (2011) Organic electronics on banknotes. Adv Mater 23:654–658CrossRef
Metadata
Title
Inkjet-printed silver nanoparticles on nano-engineered cellulose films for electrically conducting structures and organic transistors: concept and challenges
Authors
Gary Chinga-Carrasco
Daniel Tobjörk
Ronald Österbacka
Publication date
01-11-2012
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 11/2012
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-012-1213-x

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