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Journal of Materials Science
Published in: Journal of Materials Science 27/2020

18-06-2020 | Energy materials

Insights into the elevated electrochemical performance and kinetic characteristics of magnesium-substituted Na3V2−xMgx(PO4)3/C with superior rate capability and long lifespan

Authors: Yanjun Chen, Jun Cheng, Yanzhong Wang, Chao Wang, Zhenfeng He, Dan Li, Li Guo

Published in: Journal of Materials Science | Issue 27/2020

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Abstract

Na3V2(PO4)3 has been pursued to be a prospective cathode for SIBs because of its outstanding structural stability. Nevertheless, the extensive application of Na3V2(PO4)3 is impeded by its poor electronic conductivity and inferior Na+ migration ability. Herein, a promising Mg-doped Na3V2−xMgx(PO4)3/C composite is prepared by a facile carbon-thermal reduction route. The substitution of magnesium onto vanadium site downsizes the particle, providing shorter pathway for the migration of Na+ and electron. The introduction of Mg2+ generates beneficial holes to facilitate the electronic diffusion efficiently. A superior electrochemical performance of Na3V1.93Mg0.07(PO4)3/C sample can be achieved due to the multiple synergetic effects. It delivers a high specific capacity of 113.5 mAh g−1 at 0.1 C. A high reversible capacity of 95 mAh g−1 can be obtained at 10 C rate, and the retention is 84.6% after 1000 cycles. Moreover, a comprehensive GITT analysis is conducted to give a better understanding of the elevated electrochemical properties for Na3V1.93Mg0.07(PO4)3/C: The migration of Na+ suffers from the intense interactions arising from the phase transfer during the potential plateau (~ 3.4 V). The minimum values of DNa+ at ~ 3.4 V for Na3V1.93Mg0.07(PO4)3/C are one order magnitude higher than that of undoped sample, implying the improved kinetics from magnesium substitution.
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Appendix
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Metadata
Title
Insights into the elevated electrochemical performance and kinetic characteristics of magnesium-substituted Na3V2−xMgx(PO4)3/C with superior rate capability and long lifespan
Authors
Yanjun Chen
Jun Cheng
Yanzhong Wang
Chao Wang
Zhenfeng He
Dan Li
Li Guo
Publication date
18-06-2020
Publisher
Springer US
Published in
Journal of Materials Science / Issue 27/2020
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04962-3

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