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Topics in Catalysis
Published in: Topics in Catalysis 6-7/2009

01-06-2009 | Original Paper

Intercalation-induced Esterification over a Layered Transition Metal Oxide

Authors: Atsushi Takagaki, Ryo Sasaki, Caio Tagusagawa, Kazunari Domen

Published in: Topics in Catalysis | Issue 6-7/2009

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Abstract

The layered transition metal oxide HNbMoO6 is demonstrated to catalyze the esterification of lactic acid (a hydroxycarboxylic acid) with activity superior or comparable to conventional ion-exchange resins. Layered HNbMoO6 also catalyzes the esterification of propionic acid (a carboxylic acid) in the presence of lactic acid, despite exhibiting negligible activity for any carboxylic acid as the sole reactant. X-ray diffraction (XRD) measurements indicate that lactic acid is intercalated into the interlayer structure of the oxide whereas carboxylic acid is not. The intercalation mechanism thus greatly affects the catalytic activity of this layered catalyst.
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Sanz MT, Murga R, Beltrán S, Cabezas JL, Coca J (2002) Ind Eng Chem Res 41:512CrossRef
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Takagaki A, Tagusagawa C, Domen K (2008) Chem Commun 5363
Metadata
Title
Intercalation-induced Esterification over a Layered Transition Metal Oxide
Authors
Atsushi Takagaki
Ryo Sasaki
Caio Tagusagawa
Kazunari Domen
Publication date
01-06-2009
Publisher
Springer US
Published in
Topics in Catalysis / Issue 6-7/2009
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-009-9194-4

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