Skip to main content
Top

2018 | OriginalPaper | Chapter

Intermetallic Phase Characteristics in the Mg–Nd–Zn System

Authors : Domonkos Tolnai, Samuel A. Hill, Serge Gavras, Tungky Subroto, Ricardo Buzolin, Norbert Hort

Published in: Magnesium Technology 2018

Publisher: Springer International Publishing

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Neodymium, a Rare Earth with low solid solubility in Mg is an ideal alloying element to improve the yield strength and creep resistance cost effectively. The addition of Zn achieves a further improvement; however, its influence on the intermetallic phases in the Mg–Nd–Zn ternary system is not yet fully understood. A Mg-5Nd alloy modified with 3, 5 and 7 wt% of Zn was investigated with in situ synchrotron radiation diffraction during cooling from the molten state to 200 °C in order to investigate the phase-formation and -transformation characteristics of the alloys. The synchrotron diffraction results have been complemented with TEM investigations on the as-solidified samples. The results suggest that Zn has a strong effect on the microstructure by stabilizing the Mg3Nd phase and accelerating the precipitation formation. The experimental results do not fully comply with the theoretical calculations, indicating the necessity of improving the thermodynamic databank for this alloy system.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference M. Pekguleryuz, K. Kainer, A. Kaya, Fundamentals of magnesium alloy metallurgy, first ed. Woodhead, Philadelphia, 2013. M. Pekguleryuz, K. Kainer, A. Kaya, Fundamentals of magnesium alloy metallurgy, first ed. Woodhead, Philadelphia, 2013.
2.
go back to reference M.M. Avedesian, H. Baker, Magnesium and magnesium alloys, ASM Speciality Handbook, ASM International, United States of America, 1999. M.M. Avedesian, H. Baker, Magnesium and magnesium alloys, ASM Speciality Handbook, ASM International, United States of America, 1999.
3.
go back to reference M.H. Yoo, J.R. Morris, K.M. Ho, S.R. Agnew, Metall. Mater. Trans. A 41 (2002) 813–822. M.H. Yoo, J.R. Morris, K.M. Ho, S.R. Agnew, Metall. Mater. Trans. A 41 (2002) 813–822.
4.
go back to reference H. Hermawan, D. Dubé, D. Mantovani, “Developments in metallic biodegradable stents” Acta Biomaterialia 6 (2010) 1693–1697. H. Hermawan, D. Dubé, D. Mantovani, “Developments in metallic biodegradable stents” Acta Biomaterialia 6 (2010) 1693–1697.
5.
go back to reference T. Itoi et al.: Microstructure and mechanical properties of Mg-Zn-Y alloy sheet prepared by hot-rolling, Mater Sci Eng A, 560 (2013) 216–223. T. Itoi et al.: Microstructure and mechanical properties of Mg-Zn-Y alloy sheet prepared by hot-rolling, Mater Sci Eng A, 560 (2013) 216–223.
6.
go back to reference J. F. Nie et al.: Enhanced age hardening response and creep resistance of Mg–Gd alloys containing Zn: Scr. Mater., 53, (2005) 1049–1053. J. F. Nie et al.: Enhanced age hardening response and creep resistance of Mg–Gd alloys containing Zn: Scr. Mater., 53, (2005) 1049–1053.
7.
go back to reference T. T. Sasaki et al.: Enhanced age hardening response by the addition of Zn in Mg–Sn alloys, Scripta. Mater., 55, (2006). 251–254. T. T. Sasaki et al.: Enhanced age hardening response by the addition of Zn in Mg–Sn alloys, Scripta. Mater., 55, (2006). 251–254.
8.
go back to reference Q. Li, et al.: Effect of Nd and Y addition on microstructure and mechanical properties of as-cast Mg–Zn–Zr alloy, J. Alloys Compd., 427, (2007) 115–123. Q. Li, et al.: Effect of Nd and Y addition on microstructure and mechanical properties of as-cast Mg–Zn–Zr alloy, J. Alloys Compd., 427, (2007) 115–123.
9.
go back to reference N. Stanford et al.: Effect of microalloying with rare-earth elements on the texture of extruded magnesium-based alloys Scripta. Mater., 59, (2008) 772–775. N. Stanford et al.: Effect of microalloying with rare-earth elements on the texture of extruded magnesium-based alloys Scripta. Mater., 59, (2008) 772–775.
10.
go back to reference B. Langelier et al.: Improving microstructure and ductility in the Mg–Zn alloy system by combinational Ce–Ca microalloyingMat. Sci. Eng. A, 620, (2015) 76–84. B. Langelier et al.: Improving microstructure and ductility in the Mg–Zn alloy system by combinational Ce–Ca microalloyingMat. Sci. Eng. A, 620, (2015) 76–84.
11.
go back to reference D. Tolnai et al., “In situ synchrotron tomographic investigation of the solidification of an AlMg4.7Si8 alloy” Acta Materialia 60 (2012) 2568–2577. D. Tolnai et al., “In situ synchrotron tomographic investigation of the solidification of an AlMg4.7Si8 alloy” Acta Materialia 60 (2012) 2568–2577.
12.
go back to reference S. Terzi et al., “In situ study of nucleation and growth of the irregular α-Al/β-Al5FeSi eutectic by 3-D synchrotron X-ray microtomography” Acta Materialia 58 (2010) 5370–5380. S. Terzi et al., “In situ study of nucleation and growth of the irregular α-Al/β-Al5FeSi eutectic by 3-D synchrotron X-ray microtomography” Acta Materialia 58 (2010) 5370–5380.
13.
go back to reference D. Tolnai et al., “Sub-micrometre holotomographic characterisation of the effects of solution heat treatment on an AlMg7.3Si3.5 alloy” Materials Science and Engineering A 550 (2012) 214–221. D. Tolnai et al., “Sub-micrometre holotomographic characterisation of the effects of solution heat treatment on an AlMg7.3Si3.5 alloy” Materials Science and Engineering A 550 (2012) 214–221.
14.
go back to reference O. Shuleshova et al., “In situ observations of solidification in Ti–Al–Ta alloys by synchrotron radiation” Intermetallics 19 (2011) 688–692. O. Shuleshova et al., “In situ observations of solidification in Ti–Al–Ta alloys by synchrotron radiation” Intermetallics 19 (2011) 688–692.
15.
go back to reference D. Tolnai et al., “In situ synchrotron diffraction of the solidification of Mg4Y3Nd” Materials Letters 102–103 (2013) 62-64. D. Tolnai et al., “In situ synchrotron diffraction of the solidification of Mg4Y3Nd” Materials Letters 102–103 (2013) 62-64.
16.
go back to reference F.R. Elsayed et al., Magnesium permanent mold Castings optimization Materials Science Forum 690 (2011) 65–68. F.R. Elsayed et al., Magnesium permanent mold Castings optimization Materials Science Forum 690 (2011) 65–68.
17.
go back to reference J.F. Nie, “Precipitation and hardening in magnesium alloys” Metallurgical and Materials Transactions A 43(11) (2012) 3891–3939. J.F. Nie, “Precipitation and hardening in magnesium alloys” Metallurgical and Materials Transactions A 43(11) (2012) 3891–3939.
Metadata
Title
Intermetallic Phase Characteristics in the Mg–Nd–Zn System
Authors
Domonkos Tolnai
Samuel A. Hill
Serge Gavras
Tungky Subroto
Ricardo Buzolin
Norbert Hort
Copyright Year
2018
DOI
https://doi.org/10.1007/978-3-319-72332-7_61

Premium Partners