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Published in: Environmental Earth Sciences 10/2014

01-11-2014 | Original Article

Interpreting CO2–SIc relationship to estimate CO2 baseline in limestone aquifers

Authors: N. Peyraube, R. Lastennet, A. Denis, P. Malaurent, J. D. Villanueva

Published in: Environmental Earth Sciences | Issue 10/2014

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Abstract

Saturation index with respect to calcite (SIc) and equilibrium CO2 partial pressure are important parameters to study groundwater in limestone aquifers. Aside from their use in time series, CO2 and SIc are used to estimate the baseline of CO2 in the vadose zone. The objective of this paper is to present conceptual examples on the use of the CO2–SIc relationship to have new information from usual parameters. Case study was considered as an example of use from Cussac site, a limestone aquifer in southwest of France. The result showed that CO2 baseline in unsaturated zone is found close to 25,000 ± 1,000 ppm.

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Literature
go back to reference Bono P, Dreybrodt W, Errcole S, Percopo C, Vosbeck K (2001) Inorganic calcite precipitation in tartare karstic spring (Lazio, central Italy): field measurement and theoretical prediction on depositional rates. Environ Geol 41:305–313CrossRef Bono P, Dreybrodt W, Errcole S, Percopo C, Vosbeck K (2001) Inorganic calcite precipitation in tartare karstic spring (Lazio, central Italy): field measurement and theoretical prediction on depositional rates. Environ Geol 41:305–313CrossRef
go back to reference Drake J, Harmon RS (1973) Hydrochemical environments of carbonate terrains. Water Resour Res 9:949–957CrossRef Drake J, Harmon RS (1973) Hydrochemical environments of carbonate terrains. Water Resour Res 9:949–957CrossRef
go back to reference Dreybrodt W, Einsenlohr L, Madry B, Ringer S (1997) Precipitation kinetics of calcite in the system CaCO3–H2O–CO2: the conversion to CO2 by the slow process H+ + HCO3 − → CO2 + H2O as a limiting steps. Geochim Cosmochim Acta 61:3897–3904CrossRef Dreybrodt W, Einsenlohr L, Madry B, Ringer S (1997) Precipitation kinetics of calcite in the system CaCO3–H2O–CO2: the conversion to CO2 by the slow process H+ + HCO3  → CO2 + H2O as a limiting steps. Geochim Cosmochim Acta 61:3897–3904CrossRef
go back to reference Faimon J, Ličbinská M, Zajíček P (2012a) Relationship between carbon dioxide in Balcarka Cave and adjacent soils in the Moravian Karst region of the Czech Republic. Int J Speleol 41:17–28CrossRef Faimon J, Ličbinská M, Zajíček P (2012a) Relationship between carbon dioxide in Balcarka Cave and adjacent soils in the Moravian Karst region of the Czech Republic. Int J Speleol 41:17–28CrossRef
go back to reference Faimon J, Ličbinská M, Zajíček P, Sracek O (2012b) Partial pressures of Co2 in epikarstic zone deduced from hydrogeochemistry of permanent drips, the Moravian Karst, Czech Republic. Acta Carsologica 41:47–57 Faimon J, Ličbinská M, Zajíček P, Sracek O (2012b) Partial pressures of Co2 in epikarstic zone deduced from hydrogeochemistry of permanent drips, the Moravian Karst, Czech Republic. Acta Carsologica 41:47–57
go back to reference Fairchild IJ, Borsato A, Tooth AF, Frisia S, Hawkesworth CJ, Huang Y, McDermott F, Spiro B (2000) Controls on trace element Sr–Mg compositions of carbonate cave waters: implications for speleothem climatic records. Chem Geol 166:255–269CrossRef Fairchild IJ, Borsato A, Tooth AF, Frisia S, Hawkesworth CJ, Huang Y, McDermott F, Spiro B (2000) Controls on trace element Sr–Mg compositions of carbonate cave waters: implications for speleothem climatic records. Chem Geol 166:255–269CrossRef
go back to reference Ford D, Williams P (2007) Karst hydrogeology and geomorphology, 7th edn. Wiley, NY, p 562 ISBN:978-0-470-84997-2CrossRef Ford D, Williams P (2007) Karst hydrogeology and geomorphology, 7th edn. Wiley, NY, p 562 ISBN:978-0-470-84997-2CrossRef
go back to reference Herman J, Lorah M (1986) CO2 outgassing and calcite precipitation in falling Spring Creek, Virginia, USA. Chem Geol 62:251–262CrossRef Herman J, Lorah M (1986) CO2 outgassing and calcite precipitation in falling Spring Creek, Virginia, USA. Chem Geol 62:251–262CrossRef
go back to reference Johnson RH, DeWitt E, Arnold LR (2012) Using hydrogeology to identify the source of groundwater to Montezuma Well, a natural spring in Central Arizona, USA: part 1. Environ Earth Sci 67:1821–1835CrossRef Johnson RH, DeWitt E, Arnold LR (2012) Using hydrogeology to identify the source of groundwater to Montezuma Well, a natural spring in Central Arizona, USA: part 1. Environ Earth Sci 67:1821–1835CrossRef
go back to reference Karimi H, Raesi E, Bakalowicz M (2005) Characterising the main karst aquifers of the Alvand basin, northwest of Zagros, Iran, by a hydrogeochemical approach. Hydrogeol J 13:787–799CrossRef Karimi H, Raesi E, Bakalowicz M (2005) Characterising the main karst aquifers of the Alvand basin, northwest of Zagros, Iran, by a hydrogeochemical approach. Hydrogeol J 13:787–799CrossRef
go back to reference Langelier WF (1936) The analytical control of anti-corrosion water treatment. J Am Waterworks Assoc 28:1500–1521 Langelier WF (1936) The analytical control of anti-corrosion water treatment. J Am Waterworks Assoc 28:1500–1521
go back to reference Leybourne ML, Betcher RN, McRitchie WD, Kaszycki CA, Boyle DR (2009) Geochemistry and stable geochemistry and stable isotopic composition of tufa waters and precipitates from the Interlake Region, Manitoba, Canada: constraints on groundwater origin, calcitization, and tufa formation. Chem Geol 260:221–233CrossRef Leybourne ML, Betcher RN, McRitchie WD, Kaszycki CA, Boyle DR (2009) Geochemistry and stable geochemistry and stable isotopic composition of tufa waters and precipitates from the Interlake Region, Manitoba, Canada: constraints on groundwater origin, calcitization, and tufa formation. Chem Geol 260:221–233CrossRef
go back to reference Li Q, Sun H, Han J, Liu Z, Yu L (2008) High-resolution study on the hydrochemical variations caused by the dilution of precipitation in the epikarst spring: an example spring of Landiantang at Nongla, Mashan, China. Environ Geol 54:347–354CrossRef Li Q, Sun H, Han J, Liu Z, Yu L (2008) High-resolution study on the hydrochemical variations caused by the dilution of precipitation in the epikarst spring: an example spring of Landiantang at Nongla, Mashan, China. Environ Geol 54:347–354CrossRef
go back to reference Liu Z, Svensson U, Dreybrodt W, Daoxian Y, Buhmann D (1995) Hydrodynamic control of inorganic calcite precipitation in Huanglong Ravine, China: field measurements and theoretical prediction of deposition rates. Geochim Cosmochim Acta 59:3087–3097CrossRef Liu Z, Svensson U, Dreybrodt W, Daoxian Y, Buhmann D (1995) Hydrodynamic control of inorganic calcite precipitation in Huanglong Ravine, China: field measurements and theoretical prediction of deposition rates. Geochim Cosmochim Acta 59:3087–3097CrossRef
go back to reference Liu Z, Li Q, Sun H, Wang J (2007) Seasonal, diurnal and storm-scale hydrochemical variations of typical springs in subtropical karst areas of SW China: soil CO2 and dilution effects. J Hydrol 337:207–223CrossRef Liu Z, Li Q, Sun H, Wang J (2007) Seasonal, diurnal and storm-scale hydrochemical variations of typical springs in subtropical karst areas of SW China: soil CO2 and dilution effects. J Hydrol 337:207–223CrossRef
go back to reference Mattey DP, Fairchild IJ, Atkinson TC, Latin JP, Ainsworth M, Durell R (2010) Seasonal microclimate control of calcite fabrics, stable isotopes and trace elements in modern speleothem from St Michaels cave, Gibraltar. Geol Soc Lond 336:323–344CrossRef Mattey DP, Fairchild IJ, Atkinson TC, Latin JP, Ainsworth M, Durell R (2010) Seasonal microclimate control of calcite fabrics, stable isotopes and trace elements in modern speleothem from St Michaels cave, Gibraltar. Geol Soc Lond 336:323–344CrossRef
go back to reference Parkhurst DL (1995) User’s guide to PHREEQC A computer program for speciation, reaction-path, advective-transport, and inverse geochemical calculations. U.S. Geological Survey Water-Resources Investigations Report 95–4227 Parkhurst DL (1995) User’s guide to PHREEQC A computer program for speciation, reaction-path, advective-transport, and inverse geochemical calculations. U.S. Geological Survey Water-Resources Investigations Report 95–4227
go back to reference Pasvanoglu S, Gultekin F (2012) Hydrogeochemical study of the Terme and Karakurt thermal and mineralized waters from Kirsehir Area, central Turkey. Environ Earth Sci 66:169–182CrossRef Pasvanoglu S, Gultekin F (2012) Hydrogeochemical study of the Terme and Karakurt thermal and mineralized waters from Kirsehir Area, central Turkey. Environ Earth Sci 66:169–182CrossRef
go back to reference Peyraube N, Lastennet R, Denis A (2012) Geochemical evolution of groundwater in the unsaturated zone of a karstic massif, using the Pco2–SIc relationship. J Hydrol 430:13–24CrossRef Peyraube N, Lastennet R, Denis A (2012) Geochemical evolution of groundwater in the unsaturated zone of a karstic massif, using the Pco2–SIc relationship. J Hydrol 430:13–24CrossRef
go back to reference Peyraube N, Lastennet R, Denis A, Malaurent P (2013) Estimation of epikarst air Pco2 using measurements of water D13CTDIC, cave air Pco2 and D13Cco2. Geochim Cosmochim Acta 118:1–17CrossRef Peyraube N, Lastennet R, Denis A, Malaurent P (2013) Estimation of epikarst air Pco2 using measurements of water D13CTDIC, cave air Pco2 and D13Cco2. Geochim Cosmochim Acta 118:1–17CrossRef
go back to reference Plummer LN, Busenberg E (1982) The solubility of calcite, aragonite and waterite in CO2–H2O solutions between 0 and 90 °C, and evaluation of the aqueous model of the system CaCO3–CO2–H2O. Geochim Cosmochim Acta 46:1011–1040CrossRef Plummer LN, Busenberg E (1982) The solubility of calcite, aragonite and waterite in CO2–H2O solutions between 0 and 90 °C, and evaluation of the aqueous model of the system CaCO3–CO2–H2O. Geochim Cosmochim Acta 46:1011–1040CrossRef
go back to reference Plummer LN, Parkhurst DL, Kosiur DR (1975) MIX2, a computer program for modeling chemical reactions in natural waters. U.S. Geological Survey Water-Resources Investigations Report 61 Plummer LN, Parkhurst DL, Kosiur DR (1975) MIX2, a computer program for modeling chemical reactions in natural waters. U.S. Geological Survey Water-Resources Investigations Report 61
go back to reference Riechelmann DFC, Schröder-Ritzrau A, Scholz D, Fohlmeister J, Spötl C, Richter DK, Mangini A (2011) Monitoring Bunker Cave (NW Germany): a prerequisite to interpret geochemical proxy data of speleothems from this site. J Hydrol 409:682–695CrossRef Riechelmann DFC, Schröder-Ritzrau A, Scholz D, Fohlmeister J, Spötl C, Richter DK, Mangini A (2011) Monitoring Bunker Cave (NW Germany): a prerequisite to interpret geochemical proxy data of speleothems from this site. J Hydrol 409:682–695CrossRef
go back to reference Roberge J (1989) Géomorphologie du karst de la Haute-Saumons, île d’Anticosti, Quebec. Thesis, Université McMaster Roberge J (1989) Géomorphologie du karst de la Haute-Saumons, île d’Anticosti, Quebec. Thesis, Université McMaster
go back to reference Shuster ET, White WB (1971) Seasonal fluctuations in the chemistry of limestone spring: a possible means for characterizing carbonate aquifers. J Hydrol 14:93–128CrossRef Shuster ET, White WB (1971) Seasonal fluctuations in the chemistry of limestone spring: a possible means for characterizing carbonate aquifers. J Hydrol 14:93–128CrossRef
go back to reference Shuster ET, White WB (1972) Source areas and climatic effects in carbonate groundwaters determinated by saturation indices and carbon dioxide pressure. Water Resour Res 8:1067–1073CrossRef Shuster ET, White WB (1972) Source areas and climatic effects in carbonate groundwaters determinated by saturation indices and carbon dioxide pressure. Water Resour Res 8:1067–1073CrossRef
go back to reference Spötl C, Fairchild IJ, Tooth AF (2005) Cave air control on dripwater geochemistry, Obir Caves (Austria): implications for speleothem deposition in dynamically ventilated caves. Geochim Cosmochim Acta 69:2451–2468CrossRef Spötl C, Fairchild IJ, Tooth AF (2005) Cave air control on dripwater geochemistry, Obir Caves (Austria): implications for speleothem deposition in dynamically ventilated caves. Geochim Cosmochim Acta 69:2451–2468CrossRef
go back to reference Thrailkill J, Robl TL (1981) Carbonate geochemistry of vadose water recharging limestone aquifers. J Hydrol 54:195–208CrossRef Thrailkill J, Robl TL (1981) Carbonate geochemistry of vadose water recharging limestone aquifers. J Hydrol 54:195–208CrossRef
go back to reference Tooth A, Fairchild IJ (2003) Soil and karst aquifer hydrological controls on the geochemical evolution of speleothem-forming drip water, Crag Cave, southwest Ireland. J Hydrol 273:51–68CrossRef Tooth A, Fairchild IJ (2003) Soil and karst aquifer hydrological controls on the geochemical evolution of speleothem-forming drip water, Crag Cave, southwest Ireland. J Hydrol 273:51–68CrossRef
go back to reference Troester JW, White WB (1984) Seasonal fluctuations in the dioxide partial pressure in a cave atmosphère. Water Resour Res 20:53–156 Troester JW, White WB (1984) Seasonal fluctuations in the dioxide partial pressure in a cave atmosphère. Water Resour Res 20:53–156
go back to reference Unger-Lindig Y, Merkel B, Schipek M (2010) Carbon dioxide treatment of low density sludge: a new remediation strategy for acidic mining lakes? Environ Earth Sci 60:1711–1722CrossRef Unger-Lindig Y, Merkel B, Schipek M (2010) Carbon dioxide treatment of low density sludge: a new remediation strategy for acidic mining lakes? Environ Earth Sci 60:1711–1722CrossRef
go back to reference Vesper DJ, White WB (2004) Storm pulse chemographs of saturation index and carbon dioxide pressure: implications for shifting recharge sources during storm events in the karst aquifer at Fort Campbell, Kentucky/Tennessee, USA. Hydrogeol J 12:135–143CrossRef Vesper DJ, White WB (2004) Storm pulse chemographs of saturation index and carbon dioxide pressure: implications for shifting recharge sources during storm events in the karst aquifer at Fort Campbell, Kentucky/Tennessee, USA. Hydrogeol J 12:135–143CrossRef
go back to reference White WB (1997) Thermodynamic equilibrium, kinetics, activation barriers, and reaction mechanisms for chemical reactions in Karst Terrains. Environ Geol 30:46–58CrossRef White WB (1997) Thermodynamic equilibrium, kinetics, activation barriers, and reaction mechanisms for chemical reactions in Karst Terrains. Environ Geol 30:46–58CrossRef
go back to reference Zhao M, Zeng C, Liu Z, Wang S (2010) Effect of different land use/land cover on karst hydrogeochemistry: a paired catchments study of Chenqi and Dengzhanhe, Punding, Guizhou, SW China. J Hydrol 388:121–130CrossRef Zhao M, Zeng C, Liu Z, Wang S (2010) Effect of different land use/land cover on karst hydrogeochemistry: a paired catchments study of Chenqi and Dengzhanhe, Punding, Guizhou, SW China. J Hydrol 388:121–130CrossRef
Metadata
Title
Interpreting CO2–SIc relationship to estimate CO2 baseline in limestone aquifers
Authors
N. Peyraube
R. Lastennet
A. Denis
P. Malaurent
J. D. Villanueva
Publication date
01-11-2014
Publisher
Springer Berlin Heidelberg
Published in
Environmental Earth Sciences / Issue 10/2014
Print ISSN: 1866-6280
Electronic ISSN: 1866-6299
DOI
https://doi.org/10.1007/s12665-014-3316-4

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