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Published in: Journal of Nanoparticle Research 1/2010

01-01-2010 | Research Paper

Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier

Authors: Anthony W. Musumeci, Zhi Ping Xu, Suzanne V. Smith, Rodney F. Minchin, Darren J. Martin

Published in: Journal of Nanoparticle Research | Issue 1/2010

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Abstract

Stable and non-invasive fluorescent probes for nanotoxicological investigations are greatly needed to track the fate of nanoparticles in biological systems. The potential for terbium (Tb) to act as a fluorescent probe and its effect on layered double hydroxide (LDH) nanoparticle morphology are presented in this study. Incorporation of Tb during synthesis offers a simple methodology to easily tailor LDH nanoparticle thickness. A three-fold reduction in the average crystallite thickness (from 13 to 4 nm) has been achieved, whilst preferential lateral growth of LDH nanoparticles in the a-b crystal plane has been observed with increasing Tb loadings. Remarkably, Tb–LDH nanoparticles have emitted green fluorescence with a fluorescence quantum yield of 0.044.

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Literature
go back to reference Adachi-Pagano M, Forano C, Besse J-P (2000) Delamination of layered double hydroxides by use of surfactants. Chem Commun (Camb) (1):91–92. doi:10.1039/a908251d Adachi-Pagano M, Forano C, Besse J-P (2000) Delamination of layered double hydroxides by use of surfactants. Chem Commun (Camb) (1):91–92. doi:10.​1039/​a908251d
go back to reference Baraton MI, Chen X, Gonsalves KE (1997) FTIR study of a nanostructured aluminium nitride powder surface: determination of the acidic/basic sites by CO, CO2 and acetic acid absorptions. Nanostruct Mater 8(4):435–445. doi:10.1016/S0965-9773(97)00189-X CrossRef Baraton MI, Chen X, Gonsalves KE (1997) FTIR study of a nanostructured aluminium nitride powder surface: determination of the acidic/basic sites by CO, CO2 and acetic acid absorptions. Nanostruct Mater 8(4):435–445. doi:10.​1016/​S0965-9773(97)00189-X CrossRef
go back to reference Braterman PS, Xu ZP, Yarberry F (2004) Layered double hydroxides (LDHs). In: Auerback SM, Carrado KA, Dutta PK (eds) Handbook of layered materials. Marcell Dekker, New York, pp 373–474 Braterman PS, Xu ZP, Yarberry F (2004) Layered double hydroxides (LDHs). In: Auerback SM, Carrado KA, Dutta PK (eds) Handbook of layered materials. Marcell Dekker, New York, pp 373–474
go back to reference Calvin S, Miller MM, Goswami R, Cheng SF, Mulvaney SP, Whitman LJ, Harris VG (2003) Determination of crystallite size in a magnetic nanocomposite using extended X-ray absorption fine structure. J Appl Phys 94(1):778–783. doi:10.1063/1.1581344 CrossRefADS Calvin S, Miller MM, Goswami R, Cheng SF, Mulvaney SP, Whitman LJ, Harris VG (2003) Determination of crystallite size in a magnetic nanocomposite using extended X-ray absorption fine structure. J Appl Phys 94(1):778–783. doi:10.​1063/​1.​1581344 CrossRefADS
go back to reference Choy J-H, Kwak S-Y, Jeong Y-J, Park J-S (2000) Inorganic layered double hydroxides as nonviral vectors. Angew Chem Int Ed 39(22):4042–4045. doi:10.1002/1521-3773(20001117)39:22<4041::AID-ANIE4041>3.0.CO;2-CCrossRef Choy J-H, Kwak S-Y, Jeong Y-J, Park J-S (2000) Inorganic layered double hydroxides as nonviral vectors. Angew Chem Int Ed 39(22):4042–4045. doi:10.1002/1521-3773(20001117)39:22<4041::AID-ANIE4041>3.0.CO;2-CCrossRef
go back to reference Greenwell HC, Bindley LA, Unwin PR, Holliman PJ, Jones W, Coveney PV, Barnes SL (2006) In situ monitoring of crystal growth and dissolution of oriented layered double-hydroxide crystals immobilized on silicon. J Cryst Growth 294(1):53–59. doi:10.1016/j.jcrysgro.2006.05.048 CrossRefADS Greenwell HC, Bindley LA, Unwin PR, Holliman PJ, Jones W, Coveney PV, Barnes SL (2006) In situ monitoring of crystal growth and dissolution of oriented layered double-hydroxide crystals immobilized on silicon. J Cryst Growth 294(1):53–59. doi:10.​1016/​j.​jcrysgro.​2006.​05.​048 CrossRefADS
go back to reference Hernandez-Moreno MJ, Uilbarri MA, Rendon JL, Serna CJ (1985) IR characteristics of hydrotalcite-like compounds. Phys Chem Miner 12:34–38ADS Hernandez-Moreno MJ, Uilbarri MA, Rendon JL, Serna CJ (1985) IR characteristics of hydrotalcite-like compounds. Phys Chem Miner 12:34–38ADS
go back to reference Iannou PC, Rusakova NV, Andrikopoulou DA, Glynou KM, Tzompanaki GM (1998) Spectrofluorimetric determination of anthranilic acid derivatives based on terbium sensitized fluorescence. Analyst (Lond) 123:2839–2843. doi:10.1039/a806093b CrossRefADS Iannou PC, Rusakova NV, Andrikopoulou DA, Glynou KM, Tzompanaki GM (1998) Spectrofluorimetric determination of anthranilic acid derivatives based on terbium sensitized fluorescence. Analyst (Lond) 123:2839–2843. doi:10.​1039/​a806093b CrossRefADS
go back to reference Li L, Ma R, Iyi N, Ebina Y, Takada K, Sasaki T (2006b) Hollow nanoshell of layered double hydroxide. Chem Commun (Camb) (29):3125–3127. doi:10.1039/b605889b Li L, Ma R, Iyi N, Ebina Y, Takada K, Sasaki T (2006b) Hollow nanoshell of layered double hydroxide. Chem Commun (Camb) (29):3125–3127. doi:10.​1039/​b605889b
go back to reference Mohmel S, Kurzawski I, Uecker D, Muller D, Gessner W (2002) The influence of a hydrothermal treatment using microwave heating on the crystallinity of layered double hydroxides. Cryst Res Technol 37(4):359–369. doi:10.1002/1521-4079(200204)37:4<359::AID-CRAT359>3.0.CO;2-ICrossRef Mohmel S, Kurzawski I, Uecker D, Muller D, Gessner W (2002) The influence of a hydrothermal treatment using microwave heating on the crystallinity of layered double hydroxides. Cryst Res Technol 37(4):359–369. doi:10.1002/1521-4079(200204)37:4<359::AID-CRAT359>3.0.CO;2-ICrossRef
go back to reference Stumpf T, Curtius H, Walther C, Dardenne K, Ufer K, Fanghael T (2007) Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study. Environ Sci Technol 41:3186–3191. doi:10.1021/es0624873 CrossRefPubMed Stumpf T, Curtius H, Walther C, Dardenne K, Ufer K, Fanghael T (2007) Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study. Environ Sci Technol 41:3186–3191. doi:10.​1021/​es0624873 CrossRefPubMed
go back to reference Thomas GS, Kamath PV (2006) Line broadening in the PXRD patterns of layered hydroxides: the relative effects of crystallite size and structural disorder. J Chem Sci 118(1):127–133. doi:10.1007/BF02708774 CrossRef Thomas GS, Kamath PV (2006) Line broadening in the PXRD patterns of layered hydroxides: the relative effects of crystallite size and structural disorder. J Chem Sci 118(1):127–133. doi:10.​1007/​BF02708774 CrossRef
go back to reference Trifiro F, Vaccari A (1996) Comprehensive supramolecular chemistry, solid state supramolecular chemistry: two and three-dimensional inorganic networks. Pergamon Press, Oxford Trifiro F, Vaccari A (1996) Comprehensive supramolecular chemistry, solid state supramolecular chemistry: two and three-dimensional inorganic networks. Pergamon Press, Oxford
go back to reference Wu Q, Sjastad AO, Vistad OB, Knudsen KD, Roots J, Pedersen JS, Norby P (2007) Characterization of exfoliated (LDH, Mg/Al = 3) nanosheets at high concentrations in formamide. J Mater Chem 17(10):965–971. doi:10.1039/b612389a CrossRef Wu Q, Sjastad AO, Vistad OB, Knudsen KD, Roots J, Pedersen JS, Norby P (2007) Characterization of exfoliated (LDH, Mg/Al = 3) nanosheets at high concentrations in formamide. J Mater Chem 17(10):965–971. doi:10.​1039/​b612389a CrossRef
go back to reference Xu ZP, Zeng HC (2001) Abrupt structural transformation in hydrotalcite-like compounds Mg1-xAlx(OH)2(NO3)x · nH2O as a continuous function of nitrate anions. J Phys Chem B 105:1743–1749. doi:10.1021/jp0029257 CrossRef Xu ZP, Zeng HC (2001) Abrupt structural transformation in hydrotalcite-like compounds Mg1-xAlx(OH)2(NO3)x · nH2O as a continuous function of nitrate anions. J Phys Chem B 105:1743–1749. doi:10.​1021/​jp0029257 CrossRef
go back to reference Xu ZP, Lu GQ (Max) (2005) (WO/2006/066341) Preparation of Suspensions PCT Patent WO 20006066341 Patent Number: 2004908326, 29 June 2006 Xu ZP, Lu GQ (Max) (2005) (WO/2006/066341) Preparation of Suspensions PCT Patent WO 20006066341 Patent Number: 2004908326, 29 June 2006
go back to reference Xu ZP, Stevenson GS, Lu C-Q, Lu GQ, Bartlett PF, Gray PP (2006b) Stable suspension of layered double hydroxide nanoparticles in aqueous solution. J Am Chem Soc 128(1):36–37. doi:10.1021/ja056652a CrossRefPubMed Xu ZP, Stevenson GS, Lu C-Q, Lu GQ, Bartlett PF, Gray PP (2006b) Stable suspension of layered double hydroxide nanoparticles in aqueous solution. J Am Chem Soc 128(1):36–37. doi:10.​1021/​ja056652a CrossRefPubMed
go back to reference Xu ZP, Kurniawan ND, Bartlett PF, Lu GQ (2007) Enhancement of relaxivity rates of Gd-DTPA complexes by intercalation into layered double hydroxide nanoparticles. Chem Eur J 13:2824–2830. doi:10.1002/chem.200600571 CrossRef Xu ZP, Kurniawan ND, Bartlett PF, Lu GQ (2007) Enhancement of relaxivity rates of Gd-DTPA complexes by intercalation into layered double hydroxide nanoparticles. Chem Eur J 13:2824–2830. doi:10.​1002/​chem.​200600571 CrossRef
Metadata
Title
Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier
Authors
Anthony W. Musumeci
Zhi Ping Xu
Suzanne V. Smith
Rodney F. Minchin
Darren J. Martin
Publication date
01-01-2010
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 1/2010
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-008-9583-9

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