Top

Journal of Materials Science

Published in:

15-04-2021 | Electronic materials

Lead-free p-type Mn:Cs₃Cu₂I₅ perovskite with tunable dual-color emission through room-temperature grinding method

Authors: Junfeng Qu, Shuhong Xu, Fan Liu, Zhuyuan Wang, Haibao Shao, Yiping Cui, Chunlei Wang

Published in: Journal of Materials Science | Issue 21/2021

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Compared with widely studied lead halide perovskite, copper halide perovskite is toxic-free and combines better stability with comparable photoluminescence quantum yield. Cation doping has proven to be an effective way to manipulate optical and electronic properties of perovskite. Unlike lead halide perovskite able to act as the host of different kinds of dopant, copper halide perovskite acting as host material is still a great challenge. Herein, Mn was successfully doped into Cs\(_3\)Cu\(_2\)I\(_5\) under room temperature via solid-state reaction. In addition to original self-trapped emission of Cs\(_3\)Cu\(_2\)I\(_5\) at 445 nm, Mn dopant introduced characteristic emission at \(\sim \) 550 nm and realized dual color emission tuned by feeding ratio, extending chroma of Cs\(_3\)Cu\(_2\)I\(_5\) in blue region. Meanwhile, ultraviolet photo-electron spectra results confirmed that Mn\(^{2+}\) ion replacing Cu\(^+\) resulted in p-type doping in Cs\(_3\)Cu\(_2\)I\(_5\). The as-prepared Mn:Cs\(_3\)Cu\(_2\)I\(_5\) microcrystals show excellent stability with almost unchanged PL intensity within 15 days.

Graphical abstract

Synthesis of p-type Mn:Cs3Cu2I5 with dual-color emission through room-temperature grinding method.

previous article Improved stability of CdSeS/ZnS quantum dots against temperature, humidity, and UV-O3 by encapsulation in crosslinked polystyrene beads

next article Are activated carbon pore structure parameters linearly positively related to its mass-specific capacitance?

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Yang DD, Li XM, Zhou WH, Zhang SL, Meng CF, Wu Y, Wang Y, Zeng HB (2019) CsPbBr\(_3\) quantum dots 2.0: benzenesulfonic acid equivalent ligand awakens complete purification. Adv Mater 31(30):1900767CrossRef

Li XM, Cao F, Yu DJ, Chen J, Sun ZG, Shen YL, Zhu Y, Wang L, Wei Y, Wu Y, Zeng HB (2017) All inorganic halide perovskites nanosystem: synthesis, structural features, optical properties and optoelectronic applications. Small 13(9):1603996CrossRef

Wu Y, Wei CT, Li XM, Li YL, Qiu SC, Shen W, Cai B, Sun ZG, Yang DD, Deng ZT, Zeng HB (2018) In situ passivation of PbBr\(_6^{4-}\) octahedra toward blue luminescent CsPbBr\(_3\) nanoplatelets with near 100% absolute quantum yield. ACS Energy Lett 3(9):2030–2037CrossRef

Huang GG, Wang CL, Zhang H, Xu SH, Xu QY, Cui YP (2018) Post-healing of defects: an alternative way for passivation of carbon-based mesoscopic perovskite solar cells via hydrophobic ligand coordination. J Mater Chem A 6(6):2449–2455CrossRef

Zhang MJ, Wang LX, Meng LH, Wu XG, Tan QW, Chen YJ, Liang WY, Jiang F, Cai Y, Zhong HZ (2018) Perovskite quantum dots embedded composite films enhancing UV response of silicon photodetectors for broadband and solar-blind light detection. Adv Opt Mater 6(16):1800077CrossRef

Xu JK, Xu SH, Qi ZQ, Wang CL, Lu CG, Cui YP (2018) Size-tunable CsPbBr\(_3\) perovskite ring arrays for lasing. Nanoscale 10(22):10383–10388CrossRef

Wang AF, Guo YY, Zhou ZB, Niu XH, Wang YG, Muhammad F, Li HB, Zhang T, Wang JL, Nie SM, Deng ZT (2019) Aqueous acid-based synthesis of lead-free tin halide perovskites with near-unity photoluminescence quantum efficiency. Chem Sci 10(17):4573–4579CrossRef

Luo JJ, Hu MC, Niu GD, Tang J (2019) Lead-free halide perovskites and perovskite variants as phosphors toward light-emitting applications. ACS Appl Mater Interfaces 11(35):31575–31584CrossRef

Jun T, Sim K, Iimura S, Sasase M, Kamioka H, Kim J, Hosono H (2018) Lead-free highly efficient blue-emitting Cs\(_3\)Cu\(_2\)I\(_5\) with 0D electronic structure. Adv Mater 30(43):e1804547CrossRef

10.

Lin R, Zhu Q, Guo Q, Zhu Y, Zheng W, Huang F (2020) Dual self-trapped exciton emission with ultrahigh photoluminescence quantum yield in CsCu\(_2\)I\(_3\) and Cs\(_3\)Cu\(_2\)I\(_5\) perovskite single crystals. J Phys Chem C 124(37):20469–20476CrossRef

11.

Li S, Luo J, Liu J, Tang J (2019) Self-trapped excitons in all-inorganic halide perovskites: fundamentals, status, and potential applications. J Phys Chem C 10(8):1999–2007

12.

Huang GG, Wang CL, Xu SH, Zong SF, Lu J, Wang ZY, Lu CG, Cui YP (2017) Postsynthetic doping of MnCl\(_2\) molecules into preformed CsPbBr\(_3\) perovskite nanocrystals via a halide exchange-driven cation exchange. Adv Mater 29(29):1700095CrossRef

13.

Wang HR, Dou YJ, Shen PY, Kong LM, Yuan H, Luo Y, Zhang XY, Yang XY (2020) Molecule-induced p-doping in perovskite nanocrystals enables efficient color-saturated red light-emitting diodes. Small 16(20):e2001062CrossRef

14.

Vashishtha P, Nutan GV, Griffith BE, Fang YA, Giovanni D, Jagadeeswararao M, Sum TC, Mathews N, Mhaisalkar SG, Hanna JV, White T (2019) Cesium copper iodide tailored nanoplates and nanorods for blue, yellow, and white emission. Chem Mater 31(21):9003–9011CrossRef

15.

Lin RC, Guo QL, Zhu Q, Zhu YM, Zheng W (2019) All-inorganic CsCu\(_2\)I\(_3\) single crystal with high-PLQY (approximate to 15.7%) intrinsic white-light emission via strongly localized 1D excitonic recombination. Adv Mater 31(46):1905079CrossRef

16.

Jun T, Sim K, Iimura S, Sasase M, Kamioka H, Kim J, Hosono H (2019a) Lead-free highly efficient blue-emitting Cs\(_3\)Cu\(_2\)I\(_5\) with 0D electronic structure. Adv Mater 30(43):1804547CrossRef

17.

Jun T, Handa T, Sim K, Iimura S, Sasase M, Kim J, Kanemitsu Y, Hosono H (2019b) One-step solution synthesis of white-light-emitting films via dimensionality control of the Cs–Cu–I system. APL Mater 7(11):111113CrossRef

18.

Li Q, Chen ZW, Yang B, Tan L, Xu B, Han J, Zhao YS, Tang J, Quan ZW (2020) Pressure-induced remarkable enhancement of self-trapped exciton emission in one-dimensional CsCu\(_2\)I\(_3\) with tetrahedral units. J Am Chem Soc 142(4):1786–1791CrossRef

19.

Zhang F, Zhao ZH, Chen BK, Zheng H, Huang LL, Liu Y, Wang YT, Rogach AL (2020) Strongly emissive lead-free 0D Cs\(_3\)Cu\(_2\)I\(_5\) perovskites synthesized by a room temperature solvent evaporation crystallization for down-conversion light-emitting devices and fluorescent inks. Adv Opt Mater 8(8):1901723CrossRef

20.

Das Adhikari S, Guria AK, Pradhan N (2019) Insights of doping and the photoluminescence properties of Mn-doped perovskite nanocrystals. J Phys Chem Lett 10(9):2250–2257CrossRef

21.

Liu HW, Wu ZN, Shao JR, Yao D, Gao H, Liu Y, Yu WL, Zhang H, Yang B (2017) CsPb\(_x\)Mn\(_{1-x}\)Cl\(_3\) perovskite quantum dots with high Mn substitution ratio. ACS Nano 11(2):2239–2247CrossRef

22.

Martinez-Sarti L, Palazon F, Sessolo M, Bolink HJ (2020) Dry mechanochemical synthesis of highly luminescent, blue and green hybrid perovskite solids. Adv Opt Mater 8(4):1901494CrossRef

23.

Halcrow MA (2013) Jahn–Teller distortions in transition metal compounds, and their importance in functional molecular and inorganic materials. Chem Soc Rev 42:1784–1795CrossRef

24.

Zeng FJ, Guo YY, Hu W, Tan YQ, Zhang XM, Yang J, Lin QQ, Peng Y, Tang XS, Liu ZZ, Yao ZQ, Du J (2020) Green anti-solvent assisted crystallization strategy for air-stable uniform Cs\(_3\)Cu\(_2\)I\(_5\) perovskite films with highly efficient blue photoluminescence. J Lumin 223:117178CrossRef

25.

Hills-Kimball KM, Perez MJ, Nagaoka Y, Cai T, Yang HJ, Davis AH, Zheng WW, Chen O (2020) Ligand engineering for Mn\(^{2+}\) doping control in CsPbCl\(_3\) perovskite nanocrystals via a quasi-solid–solid cation exchange reaction. Chem Mater 32(6):2489–2500CrossRef

26.

Luo J, Wang X, Li S, Liu J, Guo Y, Niu G, Yao L, Fu Y, Gao L, Dong Q, Zhao C, Leng M, Ma F, Liang W, Wang L, Jin S, Han J, Zhang L, Etheridge J, Wang J, Yan Y, Sargent EH, Tang J (2018) Efficient and stable emission of warm-white light from lead-free halide double perovskites. Nature 563(7732):541–545CrossRef

Title: Lead-free p-type Mn:Cs3Cu2I5 perovskite with tunable dual-color emission through room-temperature grinding method
Authors: Junfeng Qu
Shuhong Xu
Fan Liu
Zhuyuan Wang
Haibao Shao
Yiping Cui
Chunlei Wang
Publication date: 15-04-2021
Publisher: Springer US
Published in: Journal of Materials Science / Issue 21/2021
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-06077-9

Springer Professional

Abstract

Graphical abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 21/2021

A phase-field study of the solidification process coupled with deformation

Preparation of 3-D porous PVDF/TPU composite foam with superoleophilic/hydrophobicity for the efficient separation of oils and organics from water

Are activated carbon pore structure parameters linearly positively related to its mass-specific capacitance?

Affixing poly(methyl methacrylate-co-acrylic acid) nanospheres with trimethoxyvinylsilane on silicon solar module to enhance its power conversion efficiency

Enhanced thermal stability and large piezoelectric properties of Sm-doped Pb(Sc1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 multifunctional ceramics

A review of the design of high-entropy aluminum alloys: a pathway for novel Al alloys

Premium Partners