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2016 | OriginalPaper | Chapter

2. Literature Review

Author : Diana Iruretagoyena Ferrer

Published in: Supported Layered Double Hydroxides as CO2 Adsorbents for Sorption-enhanced H2 Production

Publisher: Springer International Publishing

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Abstract

In this chapter relevant background for the present work is reviewed covering some principles of gas-solid adsorption and the characteristics of promising groups of CO2 adsorbents for carbon capture and storage. The CO2 adsorption properties of layered double hydroxides (LDHs) and their derivatives produced upon thermal treatment (layered double oxides) are described in more detail. Additionally, the strategies reported so far to improve the adsorption performance of LDHs are discussed. The last part of the chapter focuses on hydrogen production highlighting the importance of process intensification by sorption-enhancement.

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Footnotes
1
The dependence of k and n on temperature is complex so they should not be extrapolated outside their range of validity. Usually \(\ln (k)\) and \(1/n\) depend linearly on temperature (Huang and Cho [14]).
 
2
In Eq. (2.17) the adsorbate accumulation in the gas phase, \(\varepsilon_{p} \partial c_{{i_{pore} }} /\partial t\) (where εp is the pellet porosity), has been neglected otherwise it appears on the right-hand side.
 
3
The term mass transfer zone (MTZ) refers to the section of the column where active adsorption takes place and it is commonly used to classify adsorption systems and to select appropriate models to describe their behaviour [3].
 
4
In post-combustion CO2 capture technologies CO2 is separated from a flue gas after the combustion of a fossil fuel (e.g. the removal of CO2 from coal-fired power plants). Pre-combustion CO2 capture refers to processes where CO2 is removed before the combustion of the fossil fuel (e.g. the fuel is converted to syngas and subsequently to a H2-rich stream from which CO2 is captured).
 
5
Metal nitrate and chloride salts are commonly used due to the low selectivity of LDHs towards these anions [59].
 
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Metadata
Title
Literature Review
Author
Diana Iruretagoyena Ferrer
Copyright Year
2016
Book
Supported Layered Double Hydroxides as CO2 Adsorbents for Sorption-enhanced H2 Production

Print ISBN: 978-3-319-41275-7

Electronic ISBN: 978-3-319-41276-4

Copyright Year: 2016

DOI
https://doi.org/10.1007/978-3-319-41276-4_2