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Journal of Materials Science
Published in: Journal of Materials Science 20/2017

11-07-2017 | Composites

Mechanical and thermal properties of carbon-nanotube-reinforced self-healing polyurethanes

Authors: Piotr Szatkowski, Kinga Pielichowska, Stanislaw Blazewicz

Published in: Journal of Materials Science | Issue 20/2017

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Abstract

The study was conducted to synthesize self-healing polyurethanes (PUs) in the presence of multiwalled carbon nanotubes (CNTs). Measurements of the self-healing ability of PUs synthesized from N3300 isocyanate and polytetrahydrofuran with various contents of CNTs were taken. The mechanical and thermal properties were studied to analyse healing efficiency in experimentally damaged composite samples. The addition of CNTs results in a slight decrease in the self-healing efficiency of nanocomposites as compared to pure PUs. PU samples containing 40% content of soft segments self-healed much better than the samples with 50% content of soft segments. Functionalized carbon nanotubes CNT-OH due to presence of surface functional groups interact with PU chains, which results in an increase in the healing efficiency of mechanical strength and thermal conductivity of nanocomposites.
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Literature
1.
Cho JW, Kim JW, Jung YC, Goo NC (2005) Electroactive shape-memory polyurethane composites incorporating carbon nanotubes. Macromol Rapid Commun 26:412–416CrossRef
2.
Park KY, Lee SE, Kim CG, Han JH (2006) Fabrication and electromagnetic characteristics of electromagnetic wave absorbing sandwich structures. Compos Sci Technol 66:576–584CrossRef
3.
Chen W, Tao X, Liu Y (2006) Carbon nanotube-reinforced polyurethane composite fibers. Compos Sci Technol 66:3029–3034CrossRef
4.
Raja M, Ryu SH, Shanmugharaj AM (2014) Influence of surface modified multiwalled carbon nanotubes on the mechanical and electroactive shape memory properties of polyurethane (PU)/poly(vinylidene diflouride) (PVDF) composites. Colloids Surf A 450:59–66CrossRef
5.
Shokry SA, El Morsi AK, Sabaa MS, Mohamed RR, Sorogy HE (2015) Synthesis and characterization of polyurethane based on hydroxyl terminated polybutadiene and reinforced by carbon nanotubes. Egypt J Pet 24:145–154CrossRef
6.
Ho CT (1996) Reactive two-part polyurethane compositions and optionally self-healable and scratch-resistant coatings prepared therefrom. No. CA2200216A1, USA
7.
Yuan C, Rong MZ, Zhang MQ (2014) Self-healing polyurethane elastomer with thermally reversible alkoxyamines as crosslinkages. Polym J 55:1782–1791CrossRef
8.
Ashby MF (2011) Chapter 3—engineering materials and their properties. In: Materials selection in mechanical design. Elsevier, Butterworth-Heinemann, Oxford, p 27–44
9.
Manchado MAL, Valentini L, Biagiotti J, Kenny JM (2005) Thermal and mechanical properties of single-walled carbon nanotubes–polypropylene composites prepared by melt processing. Carbon 43:1499–1505CrossRef
10.
Ashby MF (2011) Chapter 5: materials selection—the basics. In: Materials selection in mechanical design. Elsevier, Butterworth-Heinemann, Oxford, p 79–104
11.
Nesterova T, Dam-Johansen K, Pedersen LT, Kiil S (2012) Microcapsule-based self-healing anticorrosive coatings: capsule size, coating formulation, and exposure testing. Prog Org Coat 75:309–318CrossRef
12.
Querat E, Tighzert L, Pascault JP, Dušek K (1996) Blocked isocyanate. Reaction and thermal behaviour of the toluene 2,4-diisocyanate dimer. Angew Makromol Chem 242:1–36CrossRef
13.
Yang J, Keller MW, Moore JS, White SR, Sottos NR (2008) Microencapsulation of isocyanates for self-healing polymers. Macromolecules 41:9650–9655CrossRef
14.
Koh E, Kim NK, Shin J, Kim YW (2014) Polyurethane microcapsules for self-healing paint coatings. RSC Adv 4:16214–16223CrossRef
15.
Huang M, Yang J (2011) Facile microencapsulation of HDI for self-healing anticorrosion coatings. J Mater Chem 21:11123–11130CrossRef
16.
Keledi G, Hari J, Pukanszky B (2012) Polymer nanocomposites: structure, interaction, and functionality. Nanoscale 4:1919–1938CrossRef
17.
Yamaguchi M, Ono S, Terano M (2007) Self-repairing property of polymer network with dangling chains. Mater Lett 61:1396–1399CrossRef
18.
Outwater JO, Gerry DJ (1969) On the fracture energy, rehealing velocity and refracture energy of cast epoxy resin. J Adhes 1:290–298CrossRef
19.
Chian W, Timm DC (2004) Kinetic reaction analysis of an anhydride-cured thermoplastic epoxy: PGE/NMA/BDMA. Macromolecules 37:8091–8097CrossRef
20.
Wu DY, Meure S, Solomon D (2008) Self-healing polymer materials: a review of recent developments. Prog Polym Sci 33:479–522CrossRef
21.
Blaiszik BJ, Kramer SLB, Olugebefola SC, More JS, Sottos NR, White SR (2010) Self-healing polymer and composites. Annu Rev Mater Res 40:179–211CrossRef
22.
Yamaguchi M, Ono S, Okamoto K (2009) Interdiffusion of dangling chains in weak gel and its application to self-repairing material. Mater Sci Eng B 162:189–194CrossRef
23.
Güney A, Hasirci N (2014) Properties and phase segregation of crosslinked PCL-based polyurethanes. J Appl Polym Sci 131:564–578CrossRef
24.
Pielichowska K, Glowinkowski S, Lekki J, Binias D, Pielichowski K, Jenczyk J (2008) PEO/fatty acid blends for thermal energy storage materials, Structural/morphological features and hydrogen interactions. Eur Polym J 44:3344–3360CrossRef
25.
Ji T, Feng Y, Qin M, Feng W (2016) Thermal conducting properties of aligned carbon nanotubes and their polymer composites. Compos A 91:351–369CrossRef
26.
Stodolak-Zych E, Benko A, Szatkowski P, Dlugon E, Nocun M, Paluszkiewicz C, Blazewicz M (2016) Spectroscopic studies of the influence of CNTs on the thermal conversion of PAN fibrous membranes to carbon nanofibers. J Mol Struct 1126:94–102CrossRef
27.
Zhang Y, Yuan S, Zhou W, Xu J, Li Y (2007) Spectroscopic evidence and molecular simulation investigation of the pi–pi interaction between pyrene molecules and carbon nanotubes. J Nanosci Nanotechnol 7:2366–2375CrossRef
28.
Li M, Chen Q (2003) Interactions between fullerene(C60) and poly(ethylene oxide) in their complexes as revealed by high-resolution solid-state 13C NMR spectroscopy. Polymer 44:2793–2798CrossRef
29.
Gayner C, Kar KK (2016) Recent advances in thermoelectric materials. Prog Mater Sci 83:330–382CrossRef
Metadata
Title
Mechanical and thermal properties of carbon-nanotube-reinforced self-healing polyurethanes
Authors
Piotr Szatkowski
Kinga Pielichowska
Stanislaw Blazewicz
Publication date
11-07-2017
Publisher
Springer US
Published in
Journal of Materials Science / Issue 20/2017
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1353-6

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