Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Materials Science
Published in: Journal of Materials Science 7/2019

07-01-2019 | Ceramics

Mechanical properties of ferroelastic La0.6Sr0.4Co0.2Fe0.8O3−δ with various porosities and pore sizes

Authors: Md. Nurul Islam, Wakako Araki, Yoshio Arai

Published in: Journal of Materials Science | Issue 7/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

We have investigated the mechanical properties of porous La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) under uniaxial compression. Porous LSCF samples containing polymethyl methacrylate pore former with different diameters (0.4, 1.5 and 10 µm) were examined. The porosity increases with the increase in pore former content, and it also slightly increases with the increase in pore former size. The average pore size is constant for the same size pore former regardless of the porosity, and it is smaller than the original pore former diameter. X-ray diffraction confirms that all the samples have a rhombohedral crystal structure. The samples contain ferroelastic domains and exhibit clear mechanical behavior related to the ferroelasticity under uniaxial compression. The initial modulus, critical stress and compressive fracture strength of the porous sample decrease with the increase in porosity and pore size, where the dependence on the pore size is most clear for the fracture strength. An empirical equation to estimate the fracture strength of porous LSCF is proposed.
previous article Structure evolution and ferroelectric properties in stoichiometric Bi0.5+xNa0.5−xTi1−0.5xO3
next article Enhanced photocatalytic performance of nanostructured TiO2 thin films through combined effects of polymer conjugation and Mo-doping

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Alcock CB, Doshi RC, Shen Y (1992) Perovskite electrodes for sensors. Solid State Ion 51:281–289CrossRef
2.
Zeng Y, Lin YS, Swartz SL (1998) Perovskite-type ceramic membrane: synthesis, oxygen permeation and membrane reactor performance for oxidative coupling of methane. J Membr Sci 150:87–98CrossRef
3.
Pfaff I, Kather A (2009) Comparative thermodynamic analysis and integration issues of CCS steam power plants based on oxy-combustion with cryogenic or membrane based air separation. Energy Proc 1:495–502CrossRef
4.
Bouwmeester HJM (2003) Dense ceramic membranes for methane conversion. Catal Today 82:141–150CrossRef
5.
Olivier L, Haag S, Mirodatos C, Veen ACV (2009) Oxidative coupling of methane using catalyst modified dense perovskite membrane reactors. Catal Today 142:34–41CrossRef
6.
Akin FT, Lin YS (2002) Controlled oxidative coupling of methane by ionic conducting ceramic membrane. Catal Lett 78:239–242CrossRef
7.
Wegmann M, Michen B, Luxbacher T, Fritsch J, Graule T (2008) Modification of ceramic microfilters with colloidal zirconia to promote the adsorption of viruses from water. Water Res 42:1726–1734CrossRef
8.
Sunarso J, Baumann S, Serra JM, Meulenberg WA, Liu S, Lin YS, Costa JCDD (2008) Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation. J Membr Sci 320:13–41CrossRef
9.
Mizusaki J, Sasamoto T, Cannon WR, Bowen HK (1983) Electronic conductivity, Seebeck coefficient, and defect structure of La1−XSrXFeO3(x = 0.1,0.25). J Am Ceram Soc 66:247–252CrossRef
10.
Wang SR, Katsuki M, Dokiya M, Hashimoto T (2003) High temperature properties of La0.6Sr0.4Co0.8Fe0.2O3−δ phase structure and electrical conductivity. Solid State Ion 159:71–78CrossRef
11.
Tai LW, Nasrallah MM, Anderson HU, Sparlin DM, Sehlin SR (1995) Structure and electrical-properties of La1−xSrxCo1−yFeyO3. Part 1. The system La0.8Sr0.2Co1−yFeyO3. Solid State Ion 76:259–271CrossRef
12.
Tai LW, Nasrallah MM, Anderson HU, Sparlin DM, Sehlin SR (1995) Structure and electrical-properties of La1−xSrxCo1−yFeyO3. Part 2. The system La1−xSrxCo0.2Fe0.8O3. Solid State Ion 76:273–283CrossRef
13.
Teraoka Y, Zhang HM, Furukawa S, Yamazoe N (1985) Oxygen permeation through perovskite-type oxides. Chem Lett 11:1743–1746CrossRef
14.
Kharton VV, Kovalevsky AV, Tikhonovich VN, Naumovich EN, Viskup AP (1998) Mixed electronic and ionic conductivity of LaCo(M)O3 (M = Ga, Cr, Fe or Ni): II. Oxygen permeation through Cr- and Ni-substituted LaCoO3. Solid State Ion 110:53–60CrossRef
15.
Stevenson JW, Armstrong TR, Carneim RD, Pederson LR, Weber WJ (1996) Electrochemical properties of mixed conducting perovskites La1−xMxCo1−yFeyO3−δ (M = Sr, Ba, Ca). J Electrochem Soc 143:2722–2729CrossRef
16.
Li K, Tan X, Liu Y (2006) Single-step fabrication of ceramic hollow fibers for oxygen permeation. J Membr Sci 272:1–5CrossRef
17.
Mineshige A, Izutsu J, Nakamura M, Nigaki K, Abe J, Kobune M, Fujii S, Yazawa T (2005) Introduction of A-site deficiency into La0.6Sr0.4Co0.2Fe0.8O3−δ and its effect on structure and conductivity. Solid State Ion 176:1145–1149CrossRef
18.
Lai B, Kerman K, Ramanathan S (2011) Nanostructured La0.6Sr0.4Co0.8Fe0.2O3/Y0.08Zr0.92O1.96/La0.6Sr0.4Co0.8Fe0.2O3 symmetric thin film solid oxide fuel cells. J Power Sources 196:1826–1832CrossRef
19.
Serra JM, Julio GF, Baumann S, Schulze-Küppers F, Meulenberg WA (2013) Oxygen permeation through tape-cast asymmetric all-La0.6Sr0.4Co0.2Fe0.8O3−δ membranes. J Membr Sci 447:297–305CrossRef
20.
Araki W, Malzbender J (2013) Ferroelastic deformation of La0.58Sr0.4Co0.2Fe0.8O3−δ under uniaxial compressive loading. J Eur Ceram Soc 33:805–812CrossRef
21.
Zou Y, Araki W, Balaguer M, Malzbender J (2016) Elastic properties of freeze-cast La0.6Sr0.4Co0.2Fe0.8O3–δ. J Eur Ceram Soc 36:1651–1657CrossRef
22.
Huang BX, Steinbrech RW, Baumann S, Malzbender J (2012) Creep behavior and its correlation with defect chemistry of La0.58Sr0.4Co0.2Fe0.8O3−δ. Acta Mater 60:2479–2484CrossRef
23.
Zou Y, Schulze-Küppers F, Malzbende J (2015) Creep behavior of porous La0.6Sr0.4Co0.2Fe0.8O3−δ oxygen transport membrane supports. Ceram Int 41:4064–4069CrossRef
24.
Gibson LJ, Ashby MF (1997) Cellular solids: structure and properties. Cambridge University Press, CambridgeCrossRef
25.
26.
Scheffler M, Colombo P (2005) Cellular ceramics: structure, manufacturing, properties and applications. Wiley, WeinheimCrossRef
27.
Huang S, Zhang Y, Leung B et al (2013) Mechanical properties of nanoporous GaN and its application for separation and transfer of GaN thin films. ACS Appl Mater Interfaces 5:11074–11079CrossRef
28.
Ojos DE, Pellicer E, Sort J (2016) The influence of pore size on the indentation behavior of metallic nanoporous materials: a molecular dynamics study. Materials 9:355CrossRef
29.
Isobe T, Kameshima Y, Nakajima A, Okada K, Hotta Y (2007) Gas permeability and mechanical properties of porous alumina ceramics with unidirectionally aligned pores. J Eur Ceram Soc 27:53–59CrossRef
30.
31.
Hu L, Benitez R, Basu S, Karaman I (2012) Processing and characterization of porous Ti2AlC with controlled porosity and pore size. Acta Mater 60:6266–6277CrossRef
32.
33.
34.
Selçuk A, Atkinson A (1997) Elastic properties of ceramic oxides used in solid oxide fuel cells (SOFC). J Eur Ceram Soc 17:1523–1532CrossRef
35.
Mielle S, Lombardi M, Chevalier J, Montanaro L (2012) Mechanical properties of porous ceramics in compression: on the transition between elastic, brittle, and cellular behavior. J Eur Ceram Soc 32:3959–3976CrossRef
36.
Chen W, Miyamoto Y (2014) Fabrication of porous silicon carbide ceramics with high porosity and high strength. J Eur Ceram Soc 34:837–840CrossRef
37.
Ryshkewitch E (1953) Compression strength of porous sintered alumina and zirconia. J Am Ceram Soc 36:65–68CrossRef
38.
Pećanac G, Foghmoes S, Lipińska-Chwalek M, Baumann S, Beck T, Malzbender J (2013) Strength degradation and failure limits of dense and porous ceramic membrane materials. J Eur Ceram Soc 33:2689–2698CrossRef
39.
Chou YS, Stevenson JW, Armstrong TR, Pederson LR (2000) Mechanical properties of La1-xSrxCo0.2Fe0.8O3 Mixed-Conducting perovskites made by the combustion synthesis technique. J Am Ceram Soc 83:1457–1464CrossRef
40.
Islam MN, Araki W, Arai Y (2017) Mechanical behavior of ferroelastic porous La0.6Sr0.4Co0.2Fe0.8O3−δ prepared with different pore formers. Ceram Int 43:14989–14995CrossRef
41.
Araki W, Shionoya K, Arai Y (2016) Ferroelastic mechanical behaviour of porous La0.6Sr0.4Co0.2Fe0.8O3−δ. Ceram Int 42:14614–14617CrossRef
42.
Park YM, Kim JH, Kim H (2011) High-performance composite cathodes for solid oxide fuel cells. Int J Hydrogen Energy 36:9169–9179CrossRef
43.
Doorn RHEV, Bouwmeester HJM, Burggraaf AJ (1998) Kinetic decomposition of La0.3Sr0.7CoO3−δ perovskite membranes during oxygen permeation. Solid State Ion 111:263–272CrossRef
44.
Paul ND, Robin ER (2000) Ion transport membrane technology for oxygen separation and syngas production. Solid State Ion 134:21–33CrossRef
45.
Petric A, Huang P, Tietz F (2000) Evaluation of La–Sr–Co–Fe–O perovskites for solid oxide fuel cells and gas separation membranes. Solid State Ion 135:719–725CrossRef
46.
Liu R, Wang CA (2013) Effects of mono-dispersed PMMA micro-balls as pore-forming agent on the properties of porous YSZ ceramics. J Eur Ceram Soc 33:1859–1865CrossRef
47.
Vullum PE, Holmestad R, Lein HL, Mastin J, Einarsrud MA, Grande T (2007) Monoclinic ferroelastic domains in LaCoO3-based perovskites. Adv Mater 19:4399–4403CrossRef
48.
Araki W, Takeda K, Arai Y (2016) Mechanical behaviour of ferroelastic lanthanum metal oxides LaMO3 (M = Co, Al, Ga, Fe). J Eur Ceram Soc 36:4089–4094CrossRef
49.
Chen Z, Wang X, Bhakhri V, Giuliani F, Atkinson A (2013) Nanoindentation of porous bulk and thin films of La0.6Sr0.4Co0.2Fe0.8O3−δ. Acta Mater 61:5720–5734CrossRef
50.
Zhang J, Malzbender J (2015) Mechanical characterization of micro- and nano-porous alumina. Ceram Int 41:10725–10729CrossRef
51.
Huang BX, Steinbrech RW, Malzbender J (2012) Direct observation of ferroelastic domain effects in LSCF perovskites. Solid State Ionics 228:32–36CrossRef
52.
Liu DM (1997) Influence of porosity and pore size on the compressive strength of porous hydroxyapatite ceramic. Ceram Int 23:135–139CrossRef
53.
Huang BX, Malzbender J, Steinbrech RW, Singheiser L (2009) Mechanical properties of La0.58Sr0.4Co0.2Fe0.8O3-δ membranes. Solid State Ion 180:241–245CrossRef
54.
Knudsen FP (1959) Dependence of mechanical strength of brittle polycrystalline specimens on porosity and grain size. J Am Ceram Soc 42:376–387CrossRef
55.
Wen CE, Yamada Y, Shomojima K, Chino Y, Hosokawa H, Mabuchi M (2004) Compressibility of porous magnesium foam: dependency on porosity and pore size. Mater Lett 58:357–360CrossRef
56.
Li X, Wu P, Zhu D (2013) Properties of porous alumina ceramics prepared by technique combining cold-drying and sintering. Int J Refract Met Hard Mater 41:437–441CrossRef
Metadata
Title
Mechanical properties of ferroelastic La0.6Sr0.4Co0.2Fe0.8O3−δ with various porosities and pore sizes
Authors
Md. Nurul Islam
Wakako Araki
Yoshio Arai
Publication date
07-01-2019
Publisher
Springer US
Published in
Journal of Materials Science / Issue 7/2019
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-03268-9

Other articles of this Issue 7/2019

Journal of Materials Science 7/2019 Go to the issue

Polymers

Sandwich-type porous polyimide film with improved dielectric, water resistance and mechanical properties

Chemical routes to materials

Ultra-small amorphous carbon dots: preparation, photoluminescence properties, and their application as TiO2 photosensitizers

Energy materials

Nitrogen- and oxygen-rich dual-decorated carbon materials with porosity for high-performance supercapacitors

Computation and theory

Quantifying the role of interface atomic structure in the compressive response of Ti2AlN/TiAl composite using MD simulations

Electronic materials

Improved electrochemical performance of P2-type Na0.67Lix(Mn0.5Fe0.25Co0.25)1−xO2 cathode materials from Li ion substitution of the transition metal ions

Chemical routes to materials

Effect of phase transition stress on the photoluminescence of perovskite CH3NH3PbI3 microwires

Premium Partners

    Image Credits