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Topics in Catalysis
Published in: Topics in Catalysis 11/2013

01-08-2013 | Original Paper

Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials

Authors: Ilya V. Mishakov, Yuri I. Bauman, Denis V. Korneev, Aleksey A. Vedyagin

Published in: Topics in Catalysis | Issue 11/2013

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Abstract

The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 °C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.
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Metadata
Title
Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials
Authors
Ilya V. Mishakov
Yuri I. Bauman
Denis V. Korneev
Aleksey A. Vedyagin
Publication date
01-08-2013
Publisher
Springer US
Published in
Topics in Catalysis / Issue 11/2013
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-013-0066-6

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