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Topics in Catalysis

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01-03-2010 | Original Paper

Microwave Synthesized Mesoporous Vanadium-MFI Catalysts for Epoxidation of Styrene Using Molecular Oxygen

Authors: Krishna Mohan Jinka, Hari C. Bajaj, Raksh V. Jasra, Eko Adi Prasetyanto, Sang-Eon Park

Published in: Topics in Catalysis | Issue 3-4/2010

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Abstract

Carbon templated mesoporous vanadium MFI catalysts with different Si/V ratios were successfully synthesized using microwave irradiation. X-ray diffraction studies revealed the formation of more crystalline MFI structures. SEM and TEM imaging also showed well ordered zeolite single crystals having mesoporosity. The N₂ sorption isotherm showed the formation of bimodal mesoporous zeolites. FT-IR studies showed absorbance around 970 cm⁻¹ corresponding to Si–O–V stretching vibration and the UV–Vis studies revealed strong peaks in the range of 230–340 nm which is related to the presence of tetrahedral V⁵⁺ state. The catalytic activity of the microwave synthesized catalysts was evaluated for epoxidation of styrene using molecular oxygen. The catalysts exhibited 20–40% styrene conversion with 60–75% epoxide selectivity. With increasing Vanadium content, the conversion as well as the selectivity was observed to increase. The catalyst could be recycled for three cycles without a loss in activity.

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Title: Microwave Synthesized Mesoporous Vanadium-MFI Catalysts for Epoxidation of Styrene Using Molecular Oxygen
Authors: Krishna Mohan Jinka
Hari C. Bajaj
Raksh V. Jasra
Eko Adi Prasetyanto
Sang-Eon Park
Publication date: 01-03-2010
Publisher: Springer US
Published in: Topics in Catalysis / Issue 3-4/2010
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-009-9411-1

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Preface

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