Skip to main content
Top
Published in: Topics in Catalysis 1-4/2011

01-03-2011 | Original Paper

Model Studies in Catalysis

Authors: N. Nilius, T. Risse, S. Schauermann, S. Shaikhutdinov, M. Sterrer, H.-J. Freund

Published in: Topics in Catalysis | Issue 1-4/2011

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

We review our approach to model heterogeneous catalysts on the basis of four examples. It is shown that Pd nanoparticles in hydrogenation incorporate hydrogen which turns out to be crucial for the actual hydrogenation step. The second example correlates the structure of vanadia monolayer catalysts with its reactivity in methanol oxidation. Further examples refer to ultrathin oxide film catalysts where the oxide metal interface controls either the charge state of Au particles grown on the film (example 3), and, in the fourth example, the oxide film itself exhibits remarkable CO-oxidation activity which can be traced to a reactive intermediate structure of the ultrathin film.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Ertl G, Knözinger H, Schüth F, Weitkamp J (2008) In: Handbook of heterogeneous catalysis, vol 4. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Ertl G, Knözinger H, Schüth F, Weitkamp J (2008) In: Handbook of heterogeneous catalysis, vol 4. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
5.
6.
go back to reference Freund H-J, Goodman DW (2007) In: ErtlG, Knözinger H, Schüth F, Weitkamp J(eds) Handbook of heterogeneous catalysis, Wiley-VCH Verlagsgesellschaft mbH, Weinheim Freund H-J, Goodman DW (2007) In: ErtlG, Knözinger H, Schüth F, Weitkamp J(eds) Handbook of heterogeneous catalysis, Wiley-VCH Verlagsgesellschaft mbH, Weinheim
7.
go back to reference Brandt B, Ludwig W, Fischer J-H, Libuda J, Zaera F, Schauermann S (2009) J Catal 265:191–198CrossRef Brandt B, Ludwig W, Fischer J-H, Libuda J, Zaera F, Schauermann S (2009) J Catal 265:191–198CrossRef
8.
go back to reference Brandt B, Fischer J-H, Ludwig W, Libuda J, Zaera F, Schauermann S, Freund H-J (2008) J Phys Chem C 112:11408–11420CrossRef Brandt B, Fischer J-H, Ludwig W, Libuda J, Zaera F, Schauermann S, Freund H-J (2008) J Phys Chem C 112:11408–11420CrossRef
9.
go back to reference Wilde M, Fukutani K, Ludwig W, Brandt B, Fischer J-H, Schauermann S, Freund HJ (2008) Angew Chem Int Ed 47:9289–9293CrossRef Wilde M, Fukutani K, Ludwig W, Brandt B, Fischer J-H, Schauermann S, Freund HJ (2008) Angew Chem Int Ed 47:9289–9293CrossRef
10.
go back to reference Schauermann S, Neyman KM (2010) Angew Chem Int Ed (in press) Schauermann S, Neyman KM (2010) Angew Chem Int Ed (in press)
11.
go back to reference Ludwig W, Savara A, Schauermann S (2010) Dalton Trans (in press) Ludwig W, Savara A, Schauermann S (2010) Dalton Trans (in press)
12.
go back to reference Rupprechter G, Unterhalt H, Morkel M, Galletto P, Hu L, Freund H-J (2002) Surf Sci 502–503:109CrossRef Rupprechter G, Unterhalt H, Morkel M, Galletto P, Hu L, Freund H-J (2002) Surf Sci 502–503:109CrossRef
13.
go back to reference Meyer R, Shaikhutdinov S, Freund HJ (2004) Z Phys Chem 218:905–914 Meyer R, Shaikhutdinov S, Freund HJ (2004) Z Phys Chem 218:905–914
14.
go back to reference Hansen KH, Worren T, Stempel S, Lægsgaard E, Bäumer M, Freund HJ, Besenbacher F, Stensgaard I (1999) Phys Rev Lett 83:4120CrossRef Hansen KH, Worren T, Stempel S, Lægsgaard E, Bäumer M, Freund HJ, Besenbacher F, Stensgaard I (1999) Phys Rev Lett 83:4120CrossRef
15.
16.
go back to reference Somorjai GA (1994) Introduction to surface chemistry and catalysis. John Wiley & Sons, Inc, New York Somorjai GA (1994) Introduction to surface chemistry and catalysis. John Wiley & Sons, Inc, New York
17.
go back to reference Doyle AM, Shaikhutdinov S, Jackson SD, Freund H-J (2003) Angew Chem Intern Ed 42:5240CrossRef Doyle AM, Shaikhutdinov S, Jackson SD, Freund H-J (2003) Angew Chem Intern Ed 42:5240CrossRef
18.
19.
go back to reference Schalow T, Laurin M, Brandt B, Schauermann S, Guimond S, Kuhlenbeck H, Starr D, Shaikhutdinov S, Libuda J, Freund HJ (2005) Angew Chem 117:7773–7777CrossRef Schalow T, Laurin M, Brandt B, Schauermann S, Guimond S, Kuhlenbeck H, Starr D, Shaikhutdinov S, Libuda J, Freund HJ (2005) Angew Chem 117:7773–7777CrossRef
20.
go back to reference Teschner D, Borsodi J, Wootsch A, Révay Z, Hävecker M, Knop-Gericke A, Jackson SD, Schlögl R (2008) Science 320:86–89CrossRef Teschner D, Borsodi J, Wootsch A, Révay Z, Hävecker M, Knop-Gericke A, Jackson SD, Schlögl R (2008) Science 320:86–89CrossRef
21.
go back to reference Ludwig W, Savara A, Schauermann S, Freund HJ (2010) Chem Phys Chem submitted Ludwig W, Savara A, Schauermann S, Freund HJ (2010) Chem Phys Chem submitted
22.
go back to reference Dumasic JA, Rudd DF, Aparicio LM (1993) The microkinetics of heterogeneous catalysis. ACS, Washington Dumasic JA, Rudd DF, Aparicio LM (1993) The microkinetics of heterogeneous catalysis. ACS, Washington
29.
31.
go back to reference Magg N, Giorgi JB, Schroeder T, Bäumer M, Freund HJ (2002) J Phys Chem B 106:8756–8761CrossRef Magg N, Giorgi JB, Schroeder T, Bäumer M, Freund HJ (2002) J Phys Chem B 106:8756–8761CrossRef
32.
go back to reference Magg N, Immaraporn B, Giorgi J, Schroeder T, Bäumer M, Döbler J, Wu Z, Kondratenko E, Cherian M, Baerns M, Stair PC, Sauer J, Freund H-J (2004) J Catal 226:88–100CrossRef Magg N, Immaraporn B, Giorgi J, Schroeder T, Bäumer M, Döbler J, Wu Z, Kondratenko E, Cherian M, Baerns M, Stair PC, Sauer J, Freund H-J (2004) J Catal 226:88–100CrossRef
33.
go back to reference Guimond S, Abu Haija M, Kaya S, Lu J, Weissenrieder J, Shaikhutdinov S, Kuhlenbeck H, Freund H-J, Döbler J, Sauer J (2006) Top Catal 38:117–125CrossRef Guimond S, Abu Haija M, Kaya S, Lu J, Weissenrieder J, Shaikhutdinov S, Kuhlenbeck H, Freund H-J, Döbler J, Sauer J (2006) Top Catal 38:117–125CrossRef
34.
go back to reference Kaya S, Sun YN, Weissenrieder J, Stacchiola D, Shaikhutdinov S, Freund HJ (2007) J Phys Chem C 111:5337–5344CrossRef Kaya S, Sun YN, Weissenrieder J, Stacchiola D, Shaikhutdinov S, Freund HJ (2007) J Phys Chem C 111:5337–5344CrossRef
35.
go back to reference Guimond S, Sturm JM, Göbke D, Romanyshyn Y, Naschitzki M, Kuhlenbeck H, Freund H-J (2008) J Phys Chem C 112:11835–11846CrossRef Guimond S, Sturm JM, Göbke D, Romanyshyn Y, Naschitzki M, Kuhlenbeck H, Freund H-J (2008) J Phys Chem C 112:11835–11846CrossRef
36.
go back to reference Romanyshyn Y, Guimond S, Kuhlenbeck H, Kaya S, Blum RP, Niehus H, Shaikhutdinov S, Simic-Milosevic M, Nilius N, Freund HJ, Ganduglia-Pirovano MV, Fortrie R, Döbler J, Sauer J (2008) Top Catal 50:106–115CrossRef Romanyshyn Y, Guimond S, Kuhlenbeck H, Kaya S, Blum RP, Niehus H, Shaikhutdinov S, Simic-Milosevic M, Nilius N, Freund HJ, Ganduglia-Pirovano MV, Fortrie R, Döbler J, Sauer J (2008) Top Catal 50:106–115CrossRef
37.
go back to reference Göbke D, Romanyshyn Y, Guimond S, Sturm JM, Kuhlenbeck H, Döbler J, Reinhardt U, Ganduglia-Pirovano MV, Sauer J, Freund HJ (2009) Angew Chem Int Ed 48:3695–3698CrossRef Göbke D, Romanyshyn Y, Guimond S, Sturm JM, Kuhlenbeck H, Döbler J, Reinhardt U, Ganduglia-Pirovano MV, Sauer J, Freund HJ (2009) Angew Chem Int Ed 48:3695–3698CrossRef
38.
go back to reference Sturm JM, Göbke D, Kuhlenbeck H, Döbler J, Reinhardt U, Ganduglia-Pirovano MV, Sauer J, Freund HJ (2009) Phys Chem Chem Phys 11:3290–3299CrossRef Sturm JM, Göbke D, Kuhlenbeck H, Döbler J, Reinhardt U, Ganduglia-Pirovano MV, Sauer J, Freund HJ (2009) Phys Chem Chem Phys 11:3290–3299CrossRef
39.
go back to reference Baron M, Bondarchuk O, Stacchiola D, Shaikhutdinov S, Freund HJ (2009) J Phys Chem C 113:6042–6049CrossRef Baron M, Bondarchuk O, Stacchiola D, Shaikhutdinov S, Freund HJ (2009) J Phys Chem C 113:6042–6049CrossRef
40.
go back to reference Abbott HL, Uhl A, Baron M, Lei Y, Meyer RJ, Stacchiola DJ, Bondarchuk O, Shaikhutdinov S, Freund HJ, Catal J (2010) (in Press) Corrected Proof Abbott HL, Uhl A, Baron M, Lei Y, Meyer RJ, Stacchiola DJ, Bondarchuk O, Shaikhutdinov S, Freund HJ, Catal J (2010) (in Press) Corrected Proof
41.
go back to reference Ganduglia-Pirovano MV, Popa C, Sauer J, Abbott H, Uhl A, Baron M, Stacchiola D, Bondarchuk O, Shaikhutdinov S, Freund H-J (2010) J Am Chem Soc 132:2345–2349CrossRef Ganduglia-Pirovano MV, Popa C, Sauer J, Abbott H, Uhl A, Baron M, Stacchiola D, Bondarchuk O, Shaikhutdinov S, Freund H-J (2010) J Am Chem Soc 132:2345–2349CrossRef
42.
43.
44.
go back to reference Giordano L, Martinez U, Sicolo S, Pacchioni G (2007) J Chem Phys 127:144713–144719CrossRef Giordano L, Martinez U, Sicolo S, Pacchioni G (2007) J Chem Phys 127:144713–144719CrossRef
46.
go back to reference Risse T, Shaikhutdinov S, Nilius N, Sterrer M, Freund H-J (2008) Acc Chem Res 41:949–956CrossRef Risse T, Shaikhutdinov S, Nilius N, Sterrer M, Freund H-J (2008) Acc Chem Res 41:949–956CrossRef
47.
48.
go back to reference Meyer R, Lemire C, Shaikhutdinov S, Freund H-J (2004) Gold Bulletin 37:72–124 Meyer R, Lemire C, Shaikhutdinov S, Freund H-J (2004) Gold Bulletin 37:72–124
49.
go back to reference Sterrer M, Risse T, Giordano L, Heyde M, Nilius N, Rust HP, Pacchioni G, Freund H-J (2007) Angew Chem Int Ed 46:8703–8706CrossRef Sterrer M, Risse T, Giordano L, Heyde M, Nilius N, Rust HP, Pacchioni G, Freund H-J (2007) Angew Chem Int Ed 46:8703–8706CrossRef
50.
go back to reference Sterrer M, Risse T, Martinez Pozzoni U, Giordano L, Heyde M, Rust H-P, Pacchioni G, Freund H-J (2007) Phys Rev Lett 98:096107CrossRef Sterrer M, Risse T, Martinez Pozzoni U, Giordano L, Heyde M, Rust H-P, Pacchioni G, Freund H-J (2007) Phys Rev Lett 98:096107CrossRef
51.
go back to reference Sterrer M, Risse T, Heyde M, Rust H-P, Freund H-J (2007) Phys Rev Lett 98:206103–206104CrossRef Sterrer M, Risse T, Heyde M, Rust H-P, Freund H-J (2007) Phys Rev Lett 98:206103–206104CrossRef
52.
go back to reference Simic-Milosevic V, Heyde M, Nilius N, Koenig T, Rust HP, Sterrer M, Risse T, Freund HJ, Giordano L, Pacchioni G (2008) J Am Chem Soc 130:7814–7815CrossRef Simic-Milosevic V, Heyde M, Nilius N, Koenig T, Rust HP, Sterrer M, Risse T, Freund HJ, Giordano L, Pacchioni G (2008) J Am Chem Soc 130:7814–7815CrossRef
53.
go back to reference Simic-Milosevic V, Heyde M, Lin X, König T, Rust H-P, Sterrer M, Risse T, Nilius N, Freund H-J, Giordano L, Pacchioni G (2008) Phys Rev B 78:235429CrossRef Simic-Milosevic V, Heyde M, Lin X, König T, Rust H-P, Sterrer M, Risse T, Nilius N, Freund H-J, Giordano L, Pacchioni G (2008) Phys Rev B 78:235429CrossRef
54.
go back to reference Lin X, Yang B, Benia H-M, Myrach P, Yulikov M, Aumer A, Brown M, Sterrer M, Bondarchuk O, Kieseritzky E, Rocker J, Risse T, Gao H, Nilius N, Freund HJ (2010) J Am Chem Soc (in press) Lin X, Yang B, Benia H-M, Myrach P, Yulikov M, Aumer A, Brown M, Sterrer M, Bondarchuk O, Kieseritzky E, Rocker J, Risse T, Gao H, Nilius N, Freund HJ (2010) J Am Chem Soc (in press)
55.
go back to reference Lin X, Nilius N, Sterrer M, Koskinen P, Häkkinen H, Freund H-J (2010) Phys Rev B 81:153406CrossRef Lin X, Nilius N, Sterrer M, Koskinen P, Häkkinen H, Freund H-J (2010) Phys Rev B 81:153406CrossRef
56.
57.
go back to reference Qin ZH, Lewandowski M, Sun YN, Shaikhutdinov S, Freund HJ (2008) J Phys Chem C 112:10209–10213CrossRef Qin ZH, Lewandowski M, Sun YN, Shaikhutdinov S, Freund HJ (2008) J Phys Chem C 112:10209–10213CrossRef
58.
go back to reference Qin ZH, Lewandowski M, Sun YN, Shaikhutdinov S, Freund HJ (2009) J Phys Condens Matter 21:134019CrossRef Qin ZH, Lewandowski M, Sun YN, Shaikhutdinov S, Freund HJ (2009) J Phys Condens Matter 21:134019CrossRef
59.
go back to reference Lewandowski M (2011) Thesis, Technical University, Berlin Lewandowski M (2011) Thesis, Technical University, Berlin
60.
go back to reference Sun YN, Giordano L, Goniakowski J, Lewandowski M, Qin ZH, Noguera C, Shaikhutdinov S, Pacchioni G, Freund HJ (2010) Angew Chem Int Ed 49:4418–4421CrossRef Sun YN, Giordano L, Goniakowski J, Lewandowski M, Qin ZH, Noguera C, Shaikhutdinov S, Pacchioni G, Freund HJ (2010) Angew Chem Int Ed 49:4418–4421CrossRef
61.
62.
64.
65.
go back to reference Sun YN, Qin ZH, Lewandowski M, Carrasco E, Sterrer M, Shaikhutdinov S, Freund HJ (2009) J Catal 266:359–368CrossRef Sun YN, Qin ZH, Lewandowski M, Carrasco E, Sterrer M, Shaikhutdinov S, Freund HJ (2009) J Catal 266:359–368CrossRef
66.
go back to reference Sun YN, Qin ZH, Lewandowski M, Kaya S, Shaikhutdinov S, Freund HJ (2008) Catal Lett 126:31–35CrossRef Sun YN, Qin ZH, Lewandowski M, Kaya S, Shaikhutdinov S, Freund HJ (2008) Catal Lett 126:31–35CrossRef
Metadata
Title
Model Studies in Catalysis
Authors
N. Nilius
T. Risse
S. Schauermann
S. Shaikhutdinov
M. Sterrer
H.-J. Freund
Publication date
01-03-2011
Publisher
Springer US
Published in
Topics in Catalysis / Issue 1-4/2011
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-011-9626-9

Other articles of this Issue 1-4/2011

Topics in Catalysis 1-4/2011 Go to the issue

Premium Partners