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Surface Engineering and Applied Electrochemistry

Published in:

01-04-2023

Modification of Cellulose Acetate Membranes with Unipolar Corona Discharge to Separate Oil–Water Emulsion

Authors: R. R. Nabiev, V. O. Dryakhlov, I. G. Shaikhiev, M. F. Galikhanov, I. R. Nizameev

Published in: Surface Engineering and Applied Electrochemistry | Issue 2/2023

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Abstract

The separation of oil–water emulsion with cellulose acetate membranes modified with a unipolar corona discharge at a voltage of 5–25 kV and time of 1–5 min was investigated. Decrease in the filter roughness after the impact of the corona discharge was determined using atomic-force microscopy. The results of X-ray diffraction analysis and of electrostatic field parameters’ measurements showed a decrease in crystallinity from 0.29 to 0.27 and the formation of positive charges on the surface of the sample, while the formation of a double electric layer according to dielectric spectrometry data was not detected. During the separation of the model oil–water emulsion, an increase in efficiency was revealed as 80 to 98% and the separation productivity from 15 to 35 dm³/(m² h) after treatment in the field of a unipolar corona discharge of cellulose acetate membranes, which is explained by a change in the supramolecular and chemical structure of the latter.

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Title: Modification of Cellulose Acetate Membranes with Unipolar Corona Discharge to Separate Oil–Water Emulsion
Authors: R. R. Nabiev
V. O. Dryakhlov
I. G. Shaikhiev
M. F. Galikhanov
I. R. Nizameev
Publication date: 01-04-2023
Publisher: Pleiades Publishing
Published in: Surface Engineering and Applied Electrochemistry / Issue 2/2023
Print ISSN: 1068-3755
Electronic ISSN: 1934-8002
DOI: https://doi.org/10.3103/S1068375523020138

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