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Journal of Polymer Research

Published in:

01-07-2009

Monoacrylated cyclodextrin via “click” reaction and copolymerization with N-isopropylacrylamide: guest controlled solution properties

Authors: SooWhan Choi, Maricica Munteanu, Helmut Ritter

Published in: Journal of Polymer Research | Issue 4/2009

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Abstract

Mono-(1 H-1, 2, 3-triazol-4-yl) (methyl) 2-methylacryl-β-cyclodextrin (CD) 3 is synthesized by microwave assisted `click´ reaction of propargyl (meth) acrylate and mono-(6-azido-6-deoxy)-β-CD using Cu (I) catalysis. Free radical copolymerizations of monomer 3 with N-isopropylacrylamide 5 (NIPAAM) of different portions are carried out. The properties of polymers are characterized by use of gel permeation chromatography (GPC), dynamic light scattering (DLS) and turbidity measurements. The Lower Critical Solution Temperatures (LCSTs) of the copolymers with different portions of NIPAAM and influence of guest molecules addition by adamantly carboxylate and adamantly methyl methacrylate are evaluated.

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Title: Monoacrylated cyclodextrin via “click” reaction and copolymerization with N-isopropylacrylamide: guest controlled solution properties
Authors: SooWhan Choi
Maricica Munteanu
Helmut Ritter
Publication date: 01-07-2009
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 4/2009
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-008-9240-0

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